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[Display omitted] • SHRIMP age of Kamthai carbonatite-hosted REE deposit is 68.4 ± 1.8 Ma. • Unambiguously links it to the Deccan Large Igneous Province. • One of earliest manifestations of the Réunion hotspot in the Indian sub-continent. • CO 2 outgassing, by carbonatitic eruptions, triggered K-Pg boundary mass extinction. The carbonatite plug at Kamthai in the Late Cretaceous polychronous (66–89 Ma) Sarnu- Dandali alkaline complex (SDAC), NW India, is India's only known carbonatite-hosted rare- earth-element deposit. The SDAC intrudes the Neoproterozoic (∼750 Ma) Malani silicic igneous suite in the Aravalli raton. The Kamthai carbonatite is a calcio-carbonatite dominated by calcite along with barite, strontianite, quartz, zircon and REE-bearing minerals. Textural features suggest an open-system exchange of the magma chamber at varying depths of crystallization. REE patterns are smooth and characterized by strong LREE enrichment, as typical of carbonatites. SHRIMP dating of 12 spots on three magmatic zircons from the carbonatite yielded a concordia age of 66.1 ± 1.4 Ma and an indistinguishable average 206Pb/238U mean age of 68.4 ± 1.8 Ma. The obtained U-Pb ages unambiguously link the carbonatite emplacement to the Deccan Large Igneous Province, i.e. the Réunion hotspot near the K-Pg (Cretaceous-Paleogene) boundary in the polychronous set-up of the SDAC. These ages are also indistinguishable from the 68.53 ± 0.16 Ma magmatic pulse recorded from the nearby Mundwara polychronous alkaline complex and the 69.7 ± 0.2 Ma alkaline sills from the Tethyan suture zone in Pakistan, which are regarded to be earliest manifestations of the Réunion hotspot in the Indian sub-continent. Our results in the context of REE mineralization in the Kamthai deposit have also implications with respect to CO 2 outgassing, induced by at least four near-synchronous carbonatitic eruptions in NW India, and to triggering the mass extinction near the K-Pg boundary. [ABSTRACT FROM AUTHOR]