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Incorporating support structures into solid–liquid phase change materials (SLPCMs) addresses fluid dynamics challenges during phase transitions, albeit at the cost of reduced phase change enthalpy. We propose a novel approach for developing self-sustaining, porous phase change materials. This process begins with the fabrication of self-sustaining poly(acrylic acid) octadecyl ester aerogels through cross-linking polymerization and thermally induced phase separation (TIPS) followed by ambient drying to shape the aerogel. This aerogel demonstrates exceptional energy storage capacity, impressive room-temperature elasticity, and significant load-bearing strength. Leveraging this aerogel as a scaffold, we employ a 'one-step' technique to produce phase change gels (PCGs). This method, in which EI functions both as a solvent and as SLPCMs, yields PCGs with a high latent heat capacity of 192 J g−1, outstanding phase change elasticity, and structural stability, proving highly effective in photoelectric thermal management. Notably, the 'one-step' process for fabricating self-supporting PCGs circumvents conventional steps like solvent extraction and phase change material absorption in traditional porous foam production. This simplification streamlines manufacturing and facilitates the large-scale production of phase change materials that are morphologically stable, possess high latent heat, and exhibit superior mechanical properties. [ABSTRACT FROM AUTHOR]