This study deals with the design and fabrication of parabolic trough solar collectors (PTCs) used to increase the yield of a single slope solar still. The designed parabolic trough solar collector is investigated numerically using Ansys Fluent 18.2. The proposed solar still is coupled with a parabolic trough solar collector with an evacuated tube receiver in its focal axis using different working fluids. The working fluids are water (case 1), oil (case 2), and nano‐oil (CuO/mineral oil 3% vol; case 3). In the case when the working fluid is not water, then a heat exchanger serpentine should be used in the solar still basin. The PTC has a rim angle of 82° and an aperture width of 0.9 m and length of 2.8 m. An assessment of the performance for the studied systems was accomplished under the weather conditions of Ismailia, Egypt, during summer months, June, July, and August 2019. The outcomes of closed‐loop working fluids different flow rates are investigated. The experimental results of the accumulated freshwater productivities record 2.955, 3.475, 4.29, and 5.04 L m−2 d−1 for the traditional solar still and the modified cases 1 to 3 solar stills, respectively. The modified solar still in case 3 has the highest daily accumulated freshwater productivity with a percentage increase of 71.2% than the traditional solar still. The maximum daily efficiency is 46% and 26.9% for the traditional and modified (case 3) solar stills, respectively. The cost of 1 L of fresh water is 0.057 and 0.062 $/L for the traditional and the modified (case 3) solar stills, respectively. [ABSTRACT FROM AUTHOR]