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International audience; The classical Kuiper Belt Object (KBO) Arrokoth was surveyed by the New Horizons spacecraft on 1st January 2019, revealing a small bilobed object with a red surface, whose spectral slope lies in the average of the whole KBOs population. This red color has been assigned to reddish organic materials, either inherited from the protosolar disk during accretion, or formed through radiolytic processes in the surface due to exposure to solar or interstellar photons, Solar Wind, Solar Energetic Particles or Galactic Cosmic Rays. We report here a study investigating the radiolytic scenario, based on numerical calculations and experimental simulations run with swift heavy ions (74.8 MeV136Xe19+ and 33.06 MeV58Ni9+), and low-energy 105 keV18O6+ions on CH3OH ice, the only molecule identified at Arrokoth’s surface.

The detection of crystalline H2O-ice on multiple surfaces of Kuiper Belt Objects (KBOs) seems to contrast with what scientists understand about the surface environment of these objects, as previous estimates suggest that radiolysis should have easily amorphized these objects' surface over their lifetimes. Here, we use a detailed laboratory approach to show that crystalline H2O-ice can be amorphized by energetic electrons at temperatures as high as 70 K. However, the estimated time needed to completely amorphize the H2O-ice present on the surface of a KBO to the depth probed by near-infrared spectroscopy is only slightly less than the age of the solar system. Given the uncertainties involved in these types of extrapolations and the possibility of a resurfacing event occurring in these objects lifetime, the detection of crystalline or at least partially crystalline H2O-ice on KBOs should be expected.

We discuss the formation of aerosols within Titan's thermosphere-ionosphere and the different chemical pathways. Negative ion measurements by the Cassini Plasma Spectrometer (CAPS) Electron Spectrometer (ELS) give evidence for formation of unsaturated anion carbon chains, while positive ion measurements of the Cassini Ion Neutral Mass Spectrometer (INMS) indicate formation of more aromatic cation hydrocarbons. There is presently no direct observational evidence for large neutral molecule growth in Titan's thermosphere-ionosphere. The hydrocarbon cations are expected to form Polycyclic Aromatic Hydrocarbons (PAH), those with the addition of nitrogen being called PAHNs. We theorize anion carbon chains can eventually become long enough to fold into fullerene C60,70 carbon shells, of various charge states. Based on laboratory data the fullerenes can trap incoming O+ magnetospheric ions that have relatively high energy collisions with the fullerenes and, once trapped, protect the oxygen atom from Titan's reducing thermosphere-ionosphere. The fullerenes can form into larger onion fullerenes and condense into larger embryo aerosols (i.e., m/q > 10,000 amu/q anions as observed by CAPS/ELS) eventually falling onto Titan's surface and precipitating to the bottom of its hydrocarbon lakes. Molecule production composed of H, C, N is known to occur in Titan's atmosphere with energy input from the magnetosphere, solar UV, and deep-penetrating irradiation from galactic cosmic rays (GCR). Space radiation effects by GCR irradiation of Titan's surface and lakes can lead to the manufacture of exobiological molecules with oxygen as the new ingredient. We have developed a model of galactic cosmic ray irradiation of Titan's atmosphere, surface, subsurface and bottoms of Titan lakes. GCR would provide further energy for processing of the aerosols into more complex organic forms such as tholins and precursor molecules for amino acids. A second process called hydrolysis then converts the precursor molecules into amino acids. Hydrolysis is provided via meteor impacts with size >10 km and cryovolcanism both which can produce liquid water on Titan's surface for episodic periods > several 100 to 1000 years. Our model shows that GCR secondary particles can penetrate ~ 100 m below the ice surface (including the bottom of Titan's less dense hydrocarbon lakes ~ 150 m depths) and produce chemically significant dosages over very long timescales ~ 450 Myrs. The GCR model is combined with laboratory data from experiments in which dry methyl ices were irradiated to doses producing prebiotic amino acids such as glycine. The model calculations show glycine can form to ~ 2.5 ppb levels near the surface after ~ 450 Myrs of GCR proton irradiation and potentially to 5 ppb if heavy-ion GCRs up through Fe are included. If such molecules were detected, this would not only confirm this model but indicate that life forms different from ours may not be required.

We present Cassini data revealing that protons between a few keV and about 100 keV energy are not stably trapped in Saturn's inner magnetosphere. Instead these ions are present only for relatively short times following injections. Injected protons are lost principally because the neutral gas cloud converts these particles to energetic neutral atoms via charge exchange. At higher energies, in the MeV to GeV range, protons are stably trapped between the orbits of the principal moons because the proton cross-section for charge exchange is very small at such energies. These protons likely result from cosmic ray albedo neutron decay (CRAND) and are lost principally to interactions with satellite surfaces and ring particles during magnetospheric radial diffusion. A main result of this work is to show that the dominant energetic proton loss and source processes are a function of proton energy. Surface sputtering by keV ions is revisited based on the reduced ion intensities observed. Relatively speaking, MeV ion and electron weathering is most important closer to Saturn, e.g. at Janus and Mimas, whereas keV ion weathering is most important farther out, at Dione and Rhea.

Results from a three-dimensional ballistic model of Europa’s O2 atmosphere are presented. Hubble Space Telescope (HST) ultraviolet observations show spatially non-uniform O2 airglow from Europa. One explanation for this is that the O2 atmosphere is spatially non-uniform. We show that non-uniform ejection of O2 alone cannot reproduce the required morphology, but that a non-uniform distribution of reactive species in Europa’s porous regolith can result in a non-uniform O2 atmosphere. By allowing O2 molecules to react with Europa’s visibly dark surface material, we produced a spatially non-uniform atmosphere which, assuming uniform electron excitation of O2 over the trailing hemisphere, compares favorably with the morphology suggested by the HST observations. This model, which requires a larger source of O2 than has previously been estimated, can in principal be tested by the New Horizons observations of Europa’s O2 atmosphere.

Molecular oxygen produced by the decomposition of icy surfaces is ubiquitous in Saturn's magnetosphere. A model is described for the toroidal O2 atmosphere indicated by the detection of O 2 + and O+ over the main rings. The O2 ring atmosphere is produced primarily by UV photon-induced decomposition of ice on the sunlit side of the ring. Because O2 has a long lifetime and interacts frequently with the ring particles, equivalent columns of O2 exist above and below the ring plane with the scale height determined by the local ring temperature. Energetic particles also decompose ice, but estimates of their contribution over the main rings appear to be very low. In steady state, the O2 column density over the rings also depends on the relative efficiency of hydrogen to oxygen loss from the ring/atmosphere system with oxygen being recycled on the grain surfaces. Unlike the neutral density, the ion densities can differ on the sunlit and shaded sides due to differences in the ionization rate, the quenching of ions by the interaction with the ring particles, and the northward shift of the magnetic equator relative to the ring plane. Although O+ is produced with a significant excess energy, O 2 + is not. Therefore, O 2 + should mirror well below those altitudes at which ions were detected. However, scattering by ion–molecule collisions results in much larger mirror altitudes, in ion temperatures that go through a minimum over the B-ring, and in the redistribution of both molecular hydrogen and oxygen throughout the magnetosphere. The proposed model is used to describe the measured oxygen ion densities in Saturn's toroidal ring atmosphere and its hydrogen content. The oxygen ion densities over the B-ring appear to require either significant levels of UV light scattering or ion transmission through the ring plane.

Remote observations with the Chandra X-ray Observatory and the XMM-Newton Observatory have shown that the Jovian system is a source of x-rays with a rich and complicated structure. The planet's polar auroral zones and its disk are powerful sources of x-ray emission. Chandra observations revealed x-ray emission from the Io Plasma Torus and from the Galilean moons Io, Europa, and possibly Ganymede. The emission from these moons is certainly due to bombardment of their surfaces of highly energetic protons, oxygen and sulfur ions from the region near the Torus exciting atoms in their surfaces and leading to fluorescent x-ray emission lines. Although the x-ray emission from the Galilean moons is faint when observed fiom Earth orbit, an imaging x-ray spectrometer in orbit around these moons, operating at 200 eV and above with 150 eV energy resolution, would provide a detailed mapping (down to 40 m spatial resolution) of the elemental composition in their surfaces. Here we describe the physical processes leading to x-ray emission fiom the surfaces of Jupiter's moons and the instrumental properties, as well as energetic ion flux models or measurements, required to map the elemental composition of their surfaces. We discuss the proposed scenarios leading to possible surface compositions. For Europa, the two most extreme are (1) a patina produced by exogenic processes such as meteoroid bombardment and ion implantation, and (2) upwelling of material fiom the subsurface ocean. We also describe the characteristics of X - m , an imaging x-ray spectrometer under going a feasibility study for the JIM0 mission, with the ultimate goal of providing unprecedented x-ray studies of the elemental composition of the surfaces of Jupiter's icy moons and Io, as well as of Jupiter's auroral x-ray emission.

A 1-D collisional Monte Carlo model of Europa’s atmosphere is described in which the sublimation and sputtering sources of H2O molecules and their molecular fragments are accounted for as well as the radiolytically produced O2. Dissociation and ionization of H2 Oa nd O2 by magnetospheric electron, solar UV-photon and photo-electron impact, and collisional ejection from the atmosphere by the low-energy plasma are taken into account. Reactions with the surface are discussed, but only adsorption and atomic oxygen recombination are included in this model. The size of the surface-bounded oxygen atmosphere of Europa is primarily determined by a balance between atmospheric sources from irradiation of the satellite’s icy surface by the high-energy magnetospheric charged particles and atmospheric losses from collisional ejection by the low-energy plasma, photo- and electron-impact dissociation, and ionization and pick-up from the surface-bounded atmosphere. A range of sources rates for O2 to H2O are used with a larger oxygen-to-water ratio than suggested by laboratory measurements in order to account for differences in adsorption onto grains in the regolith. These calculations show that the atmospheric composition is determined by both the water and oxygen photochemistry in the near-surface region, escape of suprathermal oxygen and water into the jovian system, and the exchange of radiolytic water products with the porous regolith. For the electron impact ionization rates used, pick-up ionization is the dominant oxygen loss process, whereas photo-dissociation and atmospheric sputtering are the dominant sources of neutral oxygen for Europa’s neutral torus. Including desorption and loss of water enhances the supply of oxygen species to the neutral torus, but hydrogen produced by radiolysis is the dominant source of neutrals for Europa’s torus in these models.

Galileo Orbiter measurements of energetic ions (20 keV to 100 MeV) and electrons (20-700 keV) in Jupiter's magnetosphere are used, in conjunction with the JPL electron model (less than 40 MeV), to compute irradiation effects in the surface layers of Europa, Ganymede, and Callisto. Significant elemental modifications are produced on unshielded surfaces to approximately centimeter depths in times of less than or equal to 10(exp 6) years, whereas micrometer depths on Europa are fully processed in approximately 10 years. Most observations of surface composition are limited to optical depths of approximately 1 mm, which are indirect contact with the space environment. Incident flux modeling includes Stormer deflection by the Ganymede dipole magnetic field, likely variable over that satellite's irradiation history. Delivered energy flux of approximately 8 x 10(exp 10) keV/square cm-s at Europa is comparable to total internal heat flux in the same units from tidal and radiogenic sources, while exceeding that for solar UV energies (greater than 6 eV) relevant to ice chemistry. Particle energy fluxes to Ganymede's equator and Callisto are similar at approximately 2-3 x 10(exp 8) keV/square cm-s with 5 x 10(exp 9) at Ganymede's polar cap, the latter being comparable to radiogenic energy input. Rates of change in optical reflectance and molecular composition on Europa, and on Ganymede's polar cap, are strongly driven by energy from irradiation, even in relatively young regions. Irradiation of nonice materials can produce SO2 and CO2, detected on Callisto and Europa, and simple to complex hydrocarbons. Iogenic neutral atoms and meteoroids deliver negligible energy approximately 10(exp 4-5) keV/square cm-s but impacts of the latter are important for burial or removal of irradiation products. Downward transport of radiation produced oxidants and hydrocarbons could deliver significant chemical energy into the satellite interiors for astrobiological evolution in putative sub-surface oceans.