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The performance of oil-impregnated paper significantly affects the safety and reliability of transformers. Previous studies on water reducing the breakdown strength of oil-impregnated paper have been mainly due to increasing charge carriers and conductivity. However, the influence of water on the cellulose crystal structure of oil-impregnated paper is still not clear; in particular, its role on breakdown strength remains ambiguous. In this study, the AC breakdown strength and crystal structure of vegetable and mineral oil-impregnated paper with different moisture contents were investigated. The results show that with increasing moisture content, the cellulose crystallinity and crystal size increases linearly, while the breakdown strength decreases. The breakdown strength of vegetable oil-impregnated paper is higher than that of mineral oil-impregnated paper and is less affected by moisture. Herein, a model is proposed on the effects of water on the crystal structure of oil-impregnated paper and the correlation of breakdown strength with crystal structure is reported. [ABSTRACT FROM AUTHOR]

The applicability of using 2-furfural (2-FAL) and methanol as aging markers for synthetic ester impregnated paper insulation was investigated through laboratory aging experiments at temperatures of 80, 100 and 120 ?C. Methanol in the synthetic ester increased linearly with paper aging until degree of polymerisation (DP) reached 400. During this period concentration of methanol in oil was higher than that of 2-FAL, which proved the concept of using methanol to indicate early paper aging in the synthetic ester. However, the rate of methanol increase against the reduction of DP in the synthetic ester was about three times higher than that seen in mineral oil. This is due to a difference in the partitioning of the marker between oil and paper. Since the synthetic ester is more polar than the mineral oil, it attracted more methanol molecules from the paper, resulting in a higher concentration of methanol in oil for the same reduction of DP. In addition, a reduction in methanol was observed at the later stage of paper aging at 120 ?C. This could be due to either a change in the partitioning between oil and paper, or an esterification reaction which consumes methanol in the system. [ABSTRACT FROM PUBLISHER]

Nowadays, reliability of power system is of great importance. Therefore, the condition of transformers as the expensive and critical components of a power system should be monitored and assessed. The dominant factor that causes limitation in transformers lifetime is the paper insulation. This paper aims to investigate the conspicuous influence of moisture content, especially in low oxygen and temperature on lifetime estimation under constant conditions, based on the results of previous experiments. Degree of polymerization (DP) is employed to quantify the effects of detrimental parameters with respect to their time-varying nature. This paper proposes a novel lifetime estimation-approach considering a yearly moisture growth for transformers. The results indicate different trend of DP profiles, which lead to an accurate lifetime estimation in comparison with DP obtained through ideal conditions. Furthermore, oscillations in the hot-spot temperature of transformers are demonstrated to have a negative effect on the lifetime. [ABSTRACT FROM AUTHOR]

The oil-impregnated paper, as a vital part in the oil-paper insulation system, serves as the main insulation medium in converter transformer suffering various electric fields. However, the accumulated surface charge on the paper would accelerate the degradation of insulation system and may lead to surface flashover. Direct-fluorination is a method to change the chemical components of polymer matrix thus could affect the surface property of the dielectric material without the alternation of bulk property. This paper presents a method to modify the surface structure of the paper applied in transformers. The paper used in the experiment was treated using the F2/N2 mixture with a volume fraction of 10% for the F2 gas at a pressure of 0.05 MPa in a reaction vessel for 2, 5, 10 and 15 min, respectively. The chemical elements, functional group and physical morphology of the paper before and after modification were measured with energy dispersive X-ray spectroscopy (EDAX), attenuated total reflection infrared (ATR-IR) and scanning electron micrographs (SEM), respectively. Surface and volume resistivity of the fluorinated paper were measured. Furthermore, the surface charge property of the oil-impregnated paper was measured under various positive and negative voltages. Obtained results showed that the fluorination had an obvious influence on the chemical property and surface structure of the paper leading to the reduction of surface and volume resistivity. The treatment was shown to reduce the initial potential and cause acceleration in charge decay process. The trap distribution of the paper surface presented alternation as well. [ABSTRACT FROM PUBLISHER]

In this paper, the influence of partial discharges (PD) on the subsequent dielectric properties of oil-impregnated paper (OIP) is investigated. Dielectric frequency response (DFR) of OIP is investigated at varied levels of moisture, thermal aging, temperature, oil conductivity and electrode material, to allow comparison of these influences. It is shown that PD activity inside OIP can significantly change the real and imaginary parts of permittivity of the paper layers, especially in the frequency range below 100 Hz. It is shown that even if the PD activity is concentrated on a few percent of the test sample, the real part of permittivity measured on the entire sample after a few tens of hours of PD activity can increase up to 10 times at very low frequencies (∼ 1 mHz) and the imaginary part of the permittivity can increase up to 100 times at low frequencies (∼ 1 Hz). The change of the real and imaginary parts of permittivity due to PD activity is permanent. It is very similar to the change caused by thermal aging, and somewhat similar to the change caused by moisture and higher oil conductivity. It is also shown that the dissipation factor of OIP in contact with copper and brass increases, even in the absence of PD, but contact with aluminum and stainless steel has no influence on DFR of OIP. The results suggest that the influence of PD can be significant when estimating the moisture content or the level of thermal aging of OIP with DFR method. [ABSTRACT FROM PUBLISHER]

This paper presents an experimental work investigating the failure data of oil-impregnated paper under pulsating DC voltage. The failure data of the oil-impregnated paper specimens were obtained through constant voltage stress tests; the Weibull distribution was used to estimate the statistical distribution of failure data. The exponential function (EF) and the inverse power function (IPF) were used to modify the Weibull distribution of failure data, so as to obtain two dual-variable Weibull failure distributions (WFDs), which were used to analyze failure data of oil-paper specimens obtained under pulsating DC and individual DC and AC voltages. Their adequacies were evaluated by using failure data obtained through the constant stress tests under various voltages. Both EF-modified and IPF-modified WFDs show more adequacy for failure data of oil-paper insulation under DC and pulsating DC voltages than AC voltages. The EF-modified WFD was more adequate than IPF-modified WFD in estimating the statistical distribution of failure data. [ABSTRACT FROM PUBLISHER]

This paper discusses the effect of temperature on polarization and depolarization current measurements on paper oil insulation system. The influence of copper sulphide formed due to corrosive sulphur in mineral oil, on the changes in polarization and depolarization current at different temperatures are considered. A significant increase in the magnitude of polarization and depolarization currents due to deposits of copper sulphide on paper layers is observed. The conductivity of paper insulation increases significantly with increase in temperature. The increase in current is attributed to thermally active conducting particles of copper sulphide. The Debye model parameters of equivalent circuit under copper corrosion have been computed and a model for failure due to copper sulphide is explained using the data on polarization and depolarization currents. [ABSTRACT FROM PUBLISHER]

The oil-paper insulation of valve-side windings in a high voltage direct current (HVDC) converter transformer is subjected to both complicated voltage and severe thermal stresses. Partial discharge (PD) occurring in oil-paper bounded cavities is influenced by voltage stress type as well as temperature. This paper presents PD behaviors in an oil-paper bounded gas cavity under pulsating DC voltages. The voltage across the gas cavity and PD inception voltages at different test conditions are analyzed. Influences of temperature on statistical PD distributions and parameters are also presented. A numerical model is used to interpret PD behaviors under pulsating DC voltages and various temperatures. Experimental results and theoretical statements show that the temperature exhibits a great influence on the behaviors of cavity discharge under pulsating DC voltages. Volume resistivity, gas pressure, charge decay time constant, and electron generation rate are the primary parameters influencing PD behaviors at different temperatures. [ABSTRACT FROM PUBLISHER]

Furfural content in oil is a valuable indicator of cellulose paper degradation and is widely utilized in aging assessment for power transformers. However, with the same aging degree of insulation paper, the actual furfural content in oil is influenced by temperature because furfural partitioning behavior in the oil-paper insulation system of power transformers changes with temperature. Thus, correction of the temperature effect on furfural partitioning is crucial for accurate assessment of the aging of power transformers. In this research, oil-paper samples with different furfural contents were prepared through an accelerated thermal aging test. A furfural equilibrium experiment was conducted at different temperatures to construct a furfural partitioning diagram. The mass fraction of furfural in oil and paper was calculated. Results showed that the mass fraction of furfural in oil increases with temperature rising and aging deepening, which means that furfural tends to migrate from paper to oil at high temperatures and deep aging conditions. The change in furfural partitioning between oil and paper at different temperatures causes a deviation in paper aging assessment. To correct the temperature effect on furfural partitioning, a furfural correction factor was developed to normalize furfural contents in oil at different temperatures to a reference temperature. The furfural correction factor was verified by experimental data and then introduced into the relation between degree of polymerization of paper and furfural content of oil. Verification results showed that the corrected equation can enhance the accuracy of paper aging estimation at different temperatures. The findings of this work indicated temperature effect on furfural partitioning should be considered when determining the furfural thresholds and evaluating the aging condition of power transformers. [ABSTRACT FROM PUBLISHER]

The application of vibration-based condition monitoring methods to power transformers has shown the potential for detecting mechanical transformer failures. The ageing of winding insulation paper, which is a common problem in long-serving power transformers, affects both the electrical and mechanical strength of the windings. This paper is concerned with the vibration features of winding disks with aged insulation paper. The vibration characteristics of single-layer winding disks wrapped with insulation paper are investigated. By examining the vibration frequency responses of winding disks with different degrees of ageing of insulation paper, the effects of aged paper on the vibration behaviors of winding disks are demonstrated. The experimental results show that changes in the vibration responses of winding disks can be related to the ageing of insulation paper, and thus it is possible to detect this failure mode in a power transformer using a vibration-based method. A qualitative explanation for these changes is presented, using the degradation of the mechanical strength of the insulation paper. [ABSTRACT FROM AUTHOR]

The degradation of oil-impregnated paper induced by partial discharge (PD) seriously affects the life of power equipment. In order to investigate the relationship between partial discharge and the degradation of oil-impregnated paper, PD characteristics and trap parameters of the impregnated paper are measured. In this work, a cavity discharge model is adopted and samples with different degrees of polymerization (DP) are fabricated using thermally accelerated aging to simulate transformers with different lifetimes. For each sample, phase resolved partial discharge (PRPD) spectrograms are recorded for various partial discharge times. The characteristics of partial discharge are analyzed, and the trap parameters of specimens are obtained by the thermally stimulated depolarization current (TSDC) method. Following this, the microstructures of the samples are observed using a scanning electron microscope (SEM). It is found that the damaging breakdown process of oil-immersed paper can be divided into three stages: initial stage, developing stage and pre-breakdown stage. There also exist two levels of trap on the surface of oil-impregnated paper: shallow (0.10-0.59 eV) and relatively deep (0.60-0.90 eV) energy. Importantly, the thermal aging makes the trap energy deeper while electrical aging makes the trap energy shallower. [ABSTRACT FROM AUTHOR]

Oil-paper insulation, as a major insulation mode used in power transformers, is continuously and unavoidably subjected to repeated lightning impulses, which may bring potential risk to the insulation system. Therefore, in this work, accumulative effect of repeated lightning impulses and its damage mechanism in oil-impregnated paper (OIP) are investigated. Firstly a repetitive impulse accumulating test platform was set up, and tests were performed to confirm the existence of accumulative effect of repeated lightning impulses. Then atomic force microscope observation and frequency domain spectroscopy were carried out on OIP samples with different times of lightning impulses, based on which the influence of lightning impulses accumulative effect on surface morphology and dielectric properties of OIP was investigated. The results indicate that repeated lightning impulses produce accumulative damage to the OIP and hence lead to the morphology change and generation of translucent gelatinous substance on the sample surface. Both the surface roughness and dielectric parameters increase with the accumulating of repeated lightning impulses, which can be attributed to the effects of polar products, fiber deformation and the translucent gelatinous substance together. At last, the possible mechanism of the accumulative effect was discussed and relevant tests were carried out to verify the speculation. [ABSTRACT FROM PUBLISHER]

The iso-margin method based on the classical analytical equations is widely used in the development of extra high voltage (EHV) bushing. Therefore, its effectiveness and feasibility have been fully validated. However, with the theoretical formula, it is difficult to evaluate the influence of stray capacitance and temperature on the internal electric stress of the ultra high voltage (UHV) bushing. It?s necessary to further improve the traditional iso-margin method. Firstly, the basic principle of iso-margin method has been briefly described. After that, the E-field distribution of condenser bushing was investigated on the Finite Element Method (FEM) computing platform. Then, the mathematical model of the advanced equal margin design method was established. Furthermore, this paper presents the program flow of optimization which combines the simulation of electro-thermal coupling process and the particle swarm optimization (PSO) algorithm. The proposed methodology was applied to the design of the prototype of the UHV resin impregnated paper (RIP) oil-SF6 bushing, which realizes the uniform axial E-field distribution of the bushing condenser. Meanwhile, the partial discharge margin between adjacent foils can be equal. Moreover, the hot-spot temperature is lower than the operation limiting temperature of the RIP material. The bushing condenser was fabricated according to the optimal structure design. The prototype of bushing has passed through all the type tests. In this paper, the FEM electro-thermal coupling simulation and the advanced equal margin design method were applied to the inner insulation structure optimization of the UHV RIP oil-SF6 bushing. Meanwhile, the proposed methodology provides some theoretical guidelines for the future research and development of other types of bushing on the UHV level. [ABSTRACT FROM AUTHOR]

Heretofore, unlike HVAC transformers, there is not much experience in both insulation design guides and test methods for ultra HV converter transformers. This special insulation phenomenon is very prominent due to the complication of voltage applied on valve-side windings of converter transformers. There is a severe lack of empirical research on partial discharge in oil-paper insulation under the combined ACDC voltage. The study in this paper provides a timely research into the issues. Nine possible configurations, which intent to simulate different defects in the transformer, have been investigated. The PD inception voltages varied ratios of combined AC-DC voltages were conducted. The discharge magnitude and its relation with the applied voltage for selected four common configurations were obtained during voltage increasing and decreasing respectively, which presented the PD initiating process and also reflected the insulation behavior of dielectrics. Besides, the Finite Element Analysis Soft was used to propose the effect of morphology of electrode surface (3 dimensional roughness is approximately 0.03 mm) on PD characteristics, which is very lacking in the previous references. The roles of DC and AC component in PD characteristics were discussed in the context of the relevant work in literatures. [ABSTRACT FROM AUTHOR]

Copper sulfide deposition on cellulosic insulating materials in oil-immersed transformers is evaluated by heating tests stipulated by IEC 62535. Although this method is suitable for evaluation of the corrosivity of unused insulating oil, the subject remains in diagnosis of the insulating oil used. It is because dibenzyl disulfide (DBDS), which is the prime compounds that cause copper sulfide deposition, is consumed by the reaction with copper during operating of transformer. Therefore, it is necessary to detect the existence of DBDS in insulating oil diagnosed as non-corrosivity by IEC 62535. The proceeding paper [6] reports that Bibenzyl (BiBz) and Dibenzyl sulfide (DBS) will be formed in the insulating oil as by-products of copper sulfide formation between copper and DBDS in oxygen-poor atmosphere which imitated the closed-type transformers. These by-products are considered to be the indication of copper sulfide formation. However, the influence of oxygen and addition agent (e.g. 2,6-di-tert-butylp- cresol) on the mechanism of the by-product formation is unclear. The purpose of this study is to elucidate the influence of oxygen and DBPC in by-products formation for development of diagnosis. It became apparent that benzyl alcohol, benzaldehyde and benzoic acid generate as by-products of copper sulfide formation in the air atmosphere which imitated the open-breathing transformers. Furthermore, it became apparent that the reaction product of benzyl radical and the radical of DBPC generates as by-product of copper sulfide formation in the insulating oil containing DBPC. These by-products are detectable even if DBDS disappears. Therefore, it is thought that diagnosis of the open-breathing transformer is possible by detecting these by-products. [ABSTRACT FROM AUTHOR]

A post mortem analysis of scrapped transformers provides an opportunity to directly measure the properties of in-service aged paper insulation. Investigations on 10 scrapped 275 kV and 400 kV power transformers were carried out, where Tensile Index (TI) and Low Molecular Weight Acid (LMA) of the paper insulation sampled from various locations were measured. Multiple-layer TI profile demonstrated the effect of oxidized oil on paper ageing which was confirmed by laboratory ageing experiments. It is LMA rather than High Molecular Weight Acid (HMA) that accelerates the paper degradation. LMA acts as the paper ageing accelerator and also as the paper degradation by-product, supporting the view that self-accelerated hydrolysis process is the main paper ageing mechanism. Finally, a generic relationship between LMA in paper and TI of paper was revealed based on both in-service and laboratory ageing data, i.e. the lower the TI of paper, the higher value of LMA in paper is measured. It implies that LMA in oil can be a potential paper ageing indicator pro viding a link between LMA in oil and paper is found. [ABSTRACT FROM AUTHOR]

This paper is aimed at the study of aging behavior of cellulosic materials in different dielectric liquids under air and nitrogen atmospheres. Paper for copper conductor and high density transformer board were aged at 130°C up to 1128 h in sealed vessels in presence of mineral oil (MO), natural ester (VO) and synthetic ester (SE). The influence of thermal aging on cellulose and oil characteristics are investigated and compared. It's observed that the paper degradation is associated with the generation of CO2 and CO gases. Whatever the type of oil, this generation is more important with vessel under air atmosphere than that under nitrogen gap indicating a protective effect of nitrogen. In mineral oil, the degree of polymerization (DPv) reaches the end of life criteria at around 200 whereas it remains around 400 with ester oils. This is mainly due to the higher water solubility of esters compared to mineral oil. The measured degree of polymerization in MO is comparable to that calculated through 2-FAL (Furanic compounds) content using Vuarchex equation whereas for esters oil, there is no agreement between the measured and calculated DPv through 2-FAL content. This can constitute a limitation in the use of 2-FAL for the diagnosis of ester-filled transformers. Overall, the insulation cellulose/oil behavior seems better under nitrogen atmosphere. [ABSTRACT FROM PUBLISHER]

Utility asset managers and engineers are concerned about the life and reliability of their power transformers which depends on the continued life of the paper insulation. The ageing rate of the paper is affected by water, oxygen and acids. Traditionally, the ageing rate of paper has been studied in sealed vessels however this approach does not allow the possibility to assess the affect of oxygen on paper with different water content. The ageing rate of paper has been studied for dry paper in air (excess oxygen). In these experiments we studied the ageing rate of Kraft and thermally upgraded Kraft paper in medium and high oxygen with varying water content. Furthermore, the oxygen content of the oil in sealed vessels is low which represents only sealed transformers. The ageing rate of the paper has not been determined for free breathing transformers with medium or high oxygen content and for different wetness of paper. In these ageing experiments the water and oxygen content was controlled using a special test rig to compare the ageing rate to previous work and to determine the ageing effect of paper by combining temperature, water content of paper and oxygen content of the oil. We found that the ageing rate of paper with the same water content increased with oxygen content in the oil. Hence, new life curves were developed based on the water content of the paper and the oxygen content of the oil. [ABSTRACT FROM PUBLISHER]

Oxidation ageing experiments on paper insulation and transformer oil have been performed using two different techniques. One is a traditional ageing study wherein degree of polymerization (DP) is measured after conditioning in sealed bottles containing paper submerged in oil, where the partial pressure of oxygen over the oil is varied. Paper is sampled at certain intervals during 8 months and DP-values are measured. The other study was carried out by means of a microcalorimeter; continuously measuring the heat flow from the paper-oil sample. We find that the degradation reaction rate is not linear with oxygen concentration and that the activation energy of oxidation is lower than what has earlier been found for hydrolysis. The microcalorimeter appears to mimic ageing characteristics for oxidation and can potentially be a useful tool for quick ageing investigations. [ABSTRACT FROM AUTHOR]

The overall reliability of a power transformer depends to a great extent on the sound operation of the bushings thereof. Oil impregnated paper (OIP) insulated bushings have been in use for a long time now. In many situations, it becomes necessary to avoid OIP insulation in bushings. In the recent past, a new technological breakthrough has been achieved whereby the OIP is replaced by epoxy resin impregnated crepe paper (RIP) insulation. This new system has several advantages over OIP and has now become the insulation of choice. However, its long time thermal and electrical performance need to be carefully assessed. This paper reports the results of a study of temperature distribution in the body of insulation, based on the ac conductivity of RIP insulation. A method of computing the maximum thermal voltage of this system is also given. [ABSTRACT FROM AUTHOR]

Results of Frequency Domain Spectroscopy measurements are known to be largely influenced by environmental conditions, such as the temperature. Because field measurements, last hours after de-energizing the transformer, the ambient temperature may affect the results. Especially in cold regions of the world, extreme care are required to interpret the results when performing tests at relatively low surrounding temperatures. A better understanding and analysis of the dielectric test results are therefore only possible with a clear understanding of the physical behavior of the insulation system in response to the ambient conditions. In this contribution, the dielectric behavior of a composite oil paper insulation system has been explained from the properties of Debye basic model. A series of experiments have been performed under controlled laboratory conditions with preset moisture content inside the insulation. The equivalent circuit parameters of a laboratory made oil paper condenser bushing model were obtained using a non-linear optimization procedure. Since the dielectric parameters values are geometry dependent, poles, calculated from resistances and capacitances, were used as they are independent of the geometry. It was shown that the poles can be regarded as parameters able to be used for insulation condition assessment. [ABSTRACT FROM AUTHOR]

Acid catalyzed ageing of oil impregnated kraft paper has been studied experimentally. Five different carboxylic acids (formic, acetic, laevulinic, stearic and naphtenic acid) have been added to mineral oil to arrive at a neutralization value of 0,4 mg KOH/g. Thereafter, kraft paper of two different humidities has been allowed to equilibrate with the oil. The results show that the lower the molecular weight of the carboxylic acids is the more is absorbed by the paper. Furthermore, a clear synergy for the paper ageing rates between moisture and the lower molecular weight acids is found, while for the higher molecular weight acids almost no effects were found. It is concluded that present techniques for measuring acidity of oils do not reflect these detailed conditions. It is suggested to introduce a new measuring technique for neutralization value where water rinsing is used to identify the content of low molecular weight, water soluble acids. [ABSTRACT FROM AUTHOR]

The use of paper in electrical insulation, especially in power transformers, remains a topical subject. The interest for the insulating paper, despite the emergence of many synthetic materials is ascribed to its low cost price and its ability to an oil impregnation. However its strong hydrophilic character remains the main difficulty for its implementation in electrical insulation. This affinity to water absorption and/or adsorption shows that a good understanding of the moisture effect becomes imperative. Several studies were carried out on the subject but a systematic study of the moisture effect on overall behavior of paper has not been achieved. This work is meant to be a contribution for this systematic investigation. The first step of this study, which is the object of the present article, concerns an examination of time variation of the electrical currents, under dc stress, for different moisture levels. A particular attention is given to the polarization and depolarization currents. These currents are examined during alternate charges and discharges sequences. An increase of the current, during the application of continuous voltage was noticed. This unexpected phenomenon would be related to an electro-dissociation and/or polarization processes. [ABSTRACT FROM AUTHOR]

Dielectric response is a non-invasive diagnostic method with a potential to give information about the status of the solid insulation in a power transformer. To investigate what conditions the method can and cannot reveal, frequency domain spectroscopy has been applied to oil-impregnated paper and pressboard with and without moisture and/or acids added, and to paper at various stages of aging. Water and carboxylic acids are important aging indicators. It is found that moisture is clearly detectable. Also low molecular weight carboxylic acids will affect the dielectric response in a way similar to moisture, but high concentrations are needed for a contribution comparable to that of moisture. It is difficult to tell moisture and acids apart from the responses obtained. High molecular weight carboxylic acids make little or no contribution to the dielectric response of the solid insulation in a paper/pressboard — oil system. It was also observed that keeping paper or pressboard at elevated temperatures had a conditioning effect on the response. [ABSTRACT FROM AUTHOR]

Provides information on an experiment that carried out the air pressure and the dielectric properties of a multilayer stack of dry kraft paper. Information on the experimental procedure; Results of the study; Information on the calculation of dielectric properties.