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Start Over Author "Lifang LIN" Journal inorganic chemistry
4 results on '"Lifang LIN"'

2. Aggregation of Polybismuthide Anions in a Single Compound Using +Rh-CO Units: Heterometallic Cluster Ions [Rh@Bi10(RhCO)6]3– and [Rh@Bi9(RhCO)5]3–

Author

Zhenyu Li, Shan Chen, Lifang Lin, Li Xu, Binbin Yuan, and Myung-Hwan Whangbo

Subjects
010405 organic chemistry, Chemistry, Ethylenediamine, Sequestering Agent, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Ion, Inorganic Chemistry, Crystallography, chemistry.chemical_compound, Cluster (physics), Physical and Theoretical Chemistry, Pyramid (geometry)
Abstract

In the presence of the roughly flat sequestering agent, [K(18-crown-6)]+, the reaction of Rh2(CO)4Cl2 with K5Bi4 in ethylenediamine (en) solution at room temperature yielded the heterometallic cluster anion [Rh@Bi10(RhCO)6]3- (1), in which two hitherto unknown Binm- building blocks (i.e., Bi6 crown and Bi4 pyramid) were stabilized by six +Rh-CO units. When the reaction was carried out at 60 °C using Rh(acac)(CO)2 (acac = acetylacetonate) as the source of +Rh-CO units, one obtained the anion [Rh@Bi9(RhCO)5]3- (2) in which two different Binn- units (n = 2, 3) and two weakly bonded Bi atoms were stabilized by five +Rh-CO units. The structures and bonding of the novel heterometallic cluster anions 1 and 2 were discussed.

Published
2020
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3. Extended Mo

Author

Lifang, Lin, Lulu, Wang, and Li, Xu

Abstract

The first examples of extended Mo

Published
2022

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