Search

Your search keyword '"T. P. Smith"' showing total 2 results
Start Over Author "T. P. Smith" Journal inorganic chemistry
2 results on '"T. P. Smith"'

1. Photochemistry of dithiocarbamato complexes. 1. Photolysis in chlorine-containing solvents

Author

K. W. Given, T. P. Smith, G. L. Miessler, M. C. Palazzotto, Louis H. Pignolet, and G. Stuk

Subjects
Inorganic Chemistry, Chemistry, Photodissociation, Chlorine, chemistry.chemical_element, Physical and Theoretical Chemistry, Photochemistry
Abstract

Die Photolyse des Dithiocarbamatokomplexes (I) in Chloroform oder Chlorbenzol fuhrte zur Bildung der Verbindung (II).

Published
1976
Full Text
View/download PDF

2. Halogen-mediated electron transfer between metallocenes of ruthenium and osmium in the oxidation states 4+ and 2+

Author

K. S. Kwan, Henry Taube, D. J. Iverson, M. W. Droege, and T. P. Smith

Subjects
Inorganic chemistry, chemistry.chemical_element, Ruthenium, Inorganic Chemistry, Metal, NMR spectra database, chemistry.chemical_compound, Electron transfer, Crystallography, chemistry, visual_art, Halogen, visual_art.visual_art_medium, Ruthenocene, Osmium, Physical and Theoretical Chemistry, Metallocene
Abstract

The rates of self-exchange for several systems of the class MCp/sub 2/X/sup +//Cp/sub 2/, where M is Ru or Os and X is Cl, Br, or I, have been measured by the NMR line-broadening method. For each metal, the rates increase along the halogen series as given above and are more rapid for M = Ru than for the osmium analogues. In consideration of these data, the possibility is raised that these 2e self-exchange reactions and those of other metal ions take place by 1e steps.

Published
1987
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results