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1. Unique 1D → 3D polycatenated architecture constructing from 1D single-armed chains incorporating with two rigid aromatic coligands.

Author

Xia, Wei, Tang, Ping, Wu, Xue-Qian, Cui, Jian, Li, Dong-Sheng, Dong, Wen-Wen, and Lu, J.Y.

Subjects
*AROMATIC compounds, *LIGANDS (Chemistry), *SUPRAMOLECULAR chemistry, *CHEMICAL reactions, *CHEMICAL chains, *MOLECULAR interactions
Abstract

A new supramolecular architecture, {[Zn(FDC)(phen)(H 2 O)]·0.5H 2 O} n ( 1 ), was obtained from mixed rigid ligands [9-fluorenone-2,7-dicarboxylic acid (H 2 FDC), 1,10-phenanthroline (phen)] and zinc(II) nitrate under hydrothermal reactions, which displays a charming 1D → 3D polycatenated motif based on 1D single-armed polymeric chains via powerful π π stacking interactions. In addition, the thermal stability and photoluminescence property of 1 were also investigated. [ABSTRACT FROM AUTHOR]

Published
2015
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