1. Urothermal synthesis of a photoluminescent zinc coordination polymer
- Author
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Liu, Zi-Sheng, Yang, E., Kang, Yao, and Zhang, Jian
- Subjects
- *
COMPLEX compounds synthesis , *PHOTOLUMINESCENCE , *ORGANOZINC compounds , *COORDINATION polymers , *MOLECULAR self-assembly , *ORGANOMETALLIC compounds , *MOLECULAR structure - Abstract
Abstract: Solvent plays an important role in the self-assembly of metal-organic frameworks (MOFs). It has been demonstrated that the urea derivatives are a new kind of useful solvents, and a new synthetic method denoted as “urothermal synthesis” is emerging. Presented here are the urothermal synthesis, structure and photoluminescent property of an interesting coordination polymer {Zn3[(sip)2(tmdpy)2(e-urea)4(H2O)2](e-urea)2}n (1; sip=5-sulfoisophthalate; tmdpy=1.3-di(4-pyridyl)propane; and e-urea=2-imidazolidinone) with ladder-like structure. [Copyright &y& Elsevier]
- Published
- 2011
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