Search

Your search keyword '"Ciara L. Pollock"' showing total 1 results
Start Over Author "Ciara L. Pollock" Journal inorganic chemistry communications
1 results on '"Ciara L. Pollock"'

1. Complexes of η5, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η5-pentamethylcyclopentadienyl in a rhodium complex

Author

Ciara L. Pollock, Mark Nieuwenhuyzen, Graham C. Saunders, and Andrew C. Marr

Subjects
Chemistry, Stereochemistry, chemistry.chemical_element, Coupling (probability), Medicinal chemistry, Methane, Rhodium, Inorganic Chemistry, chemistry.chemical_compound, Cyclopentadienyl complex, Phosphorus atom, Materials Chemistry, Chelation, Physical and Theoretical Chemistry, Benzene, Phosphine
Abstract

The reaction between [{(η5-C5Me5)RhCl(μ-Cl)}2] and (C6F5)2PCH2P(C6F5)2 in refluxing benzene yields the singly linked complex [{(η5,κP-C5Me 4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)}RhCl2] in which only one phosphorus atom is coordinated to the rhodium.

Published
2006
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results