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Start Over Author "Luis Garzón-Tovar" Journal inorganic chemistry communications
1 results on '"Luis Garzón-Tovar"'

1. Non-classical hydrogen bond (CH∙∙∙I) directed self-assembly formation of a novel 1D supramolecular polymer, based on a copper complex [Cu{(CH3)2SO}6]I4

Author

Álvaro Duarte-Ruiz, Luis Garzón-Tovar, and Klaus Wurst

Subjects
chemistry.chemical_classification, Chemistry, Hydrogen bond, Iodide, Photochemistry, Ion, Inorganic Chemistry, Supramolecular polymers, Crystallography, Polyiodide, chemistry.chemical_compound, Chain (algebraic topology), Materials Chemistry, Molecule, Self-assembly, Physical and Theoretical Chemistry
Abstract

The structure of the new complex with molecular formula [Cu{(CH3)2SO}6]I4, has been determined. The compound comprises discrete [Cu{(CH3)2SO}6]2 + units connected through a self-assembly process with a linear arrangement of polyiodide I2n + 22 −, driven by non-classical hydrogen bonds C H∙∙∙I. The polyiodide chain presents a neutral I2 molecule weakly coordinated with two iodide anions. The linear, uncoordinated, centrosymmetric polyiodide anion represents a rare example of a tetraiodide.

Published
2013
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