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Start Over Author "SEIGO OHTA" Journal inorganic chemistry communications
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1. Synthesis of new self-assembled octahedrons containing group 14 elements dative bonding of pyrimidine derivatives with palladium ions

Author

Kanako Ito, Yoshiyuki Miura, Masato Nanjo, Yoko Usui, Keiko Yano, Seigo Ohta, and Kunio Mochida

Subjects
Carbon group, Dimethylsilane, Pyrimidine, Inorganic chemistry, chemistry.chemical_element, Ethylenediamine, Inorganic Chemistry, chemistry.chemical_compound, Crystallography, Octahedron, chemistry, Germane, X-ray crystallography, Materials Chemistry, Physical and Theoretical Chemistry, Palladium
Abstract

Self-assembly reactions of di{4-(5-pyrimidyl)phenyl}dimethylsilane and -germane with (ethylenediamine)palladium dinitrate in ratio of 1:2 led to the formation of new octahedral supramolecules containing group 14 elements (Si,Ge), respectively. The structure of the silicon-bridged octahedron was fully identified by spectroscopic methods coupled with X-ray diffraction analysis.

Published
2006

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