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Start Over Author "Zhang, Li-Yi" Journal inorganic chemistry communications
8 results on '"Zhang, Li-Yi"'

8. <f>μ3</f>-SH dicapped triangular copper(I) complex of bis(diphenylphosphino)amine

Author

Han, Lei, Shi, Lin-Xi, Zhang, Li-Yi, Chen, Zhong-Ning, and Hong, Mao-Chun

Subjects
*COPPER compounds, *PHOTOLUMINESCENCE
Abstract

The reaction between [Cu2(Ph2PNHPPh2)2(MeCN)2](BF4)2 and sodium salt of mercaptoacetic acid (HSCH2COONa) at room temperature for 12 h produced a doubly μ3-SH-bridged tricopper complex [Cu3(μ-Ph2PNHPPh2)3(μ3-SH)2](BF4)·2MeOH·Et2O which affords a trigonal bipyramidal core of Cu3(μ3-SH)2 with copper ⋯ copper separations around 3.0 A˚. The complex is photoluminescent and it displays an emissive maximum at 523 nm in the solid state at 293 K. [Copyright &y& Elsevier]

Published
2003
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