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With the highly integrated development of electronic components, higher requirements are put forward for heat transfer components, there is an urgent need for high-performance heat transfer components. Oscillating heat pipe (OHP) is novel types of heat pipe with excellent heat transfer capability. However, the heat transfer limit hinders their operation and application. This paper proposes an OHP under trans-critical conditions with the working fluid of R218 and explores its operating characteristics and heat transfer capability. Visualization experiments and pressure monitoring were conducted to analyze the state changes within the OHP under trans-critical conditions. After evaporation section temperature surpassing the critical temperature of R218, the pressure increases with the temperature, once the pressure reached near the critical pressure, OHP can transcend the limitation of the critical temperature and realize efficient oscillating operation under trans-critical conditions. With stable operation, the working fluid velocity can reach up to 1.49 m/s, and the OHP under trans-critical conditions presented excellent heat transfer performance with the thermal resistance of 0.22 °C/W. This paper proves the feasibility of the OHP under trans-critical conditions and provides a basis for further research. [ABSTRACT FROM AUTHOR]