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Early Palaeozoic granitoids in the South Qilian Belt, central China, record details of the tectonic evolution and crustal growth of the Qilian orogenic belt. Five representative granitoids from the western South Qilian Belt were sampled for zircon LA-ICPMS U-Pb dating, Lu-Hf isotopes, and whole-rock geochemical analyses. Zircon U-Pb dating of two porphyritic granodiorites and a porphyritic monzogranite yielded ages of 442.7 ± 3.5, 441.8 ± 4.3, and 435.4 ± 3.5 Ma, respectively. These granitoids exhibit a geochemical affinity to I-type granite, are metaluminous with a low aluminium saturation index (A/CNK = 0.75-1.15), have moderate Al2O3 and low MgO contents, high La/Yb and low Sr/Y ratios, and are depleted in Nb, Ta, P, and Ti, which suggests a subduction zone magmatic arc affinity, with mixing between a primary mantle-derived magma with lesser continental crustal material. The syenogranite and monzogranite from the South Qilian Belt, which yield U-Pb zircon ages of 440.4 ± 9.0 and 442.3 ± 1.2 Ma, respectively, have pronounced S-type geochemical affinities, are peraluminous with A/CNK values of 1.07-1.16, have relatively high SiO2, Al2O3, K2O, and Rb contents, low Y and Yb, low Sr/Y and La/Yb ratios, positive Th, U, and light Rare Earth Element (REE) anomalies, and depletions in Nb, Ta, Sr, and Ti. Their geochemical signature suggests derivation from partial melting of continental crust in a syn-collisional setting. The Hf isotopic data of zircons from the granitoids show a significant input of Paleoproterozoic crust in the crustal formation of the western South Qilian Belt in Palaeozoic. Compare the εHf(t) value of S-type granite with that of I-type granite, the former may have a comparatively homogeneous source. Together with regional evidence, it is proposed that a collisional event occurred between the South Qilian Belt and the Central Qilian Belt at ca. 442-435 Ma. [ABSTRACT FROM AUTHOR]