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Among the techniques that have been developed in spectroscopy, derivative analysis is particularly promising for use with remote sensing data. In the first step of this research we apply the derivative spectrum in a real hyperspectral image and introduce a new target detection approach called “DCEM”. For this purpose, 1st to 5th orders of derivative spectrum were applied to the DCEM. The outcome of this research has shown that the application of derivative spectrum in target detection is perfectly advisable in a specific derivative order for each target. This order can be introduced as an optimized order or the Best DCEM. The spectrum differentiation eliminates low frequency components of the spectrum. Despite the little information included in those low frequency components of a signal or spectrum, their complete elimination cause an information loss problem. Hence, in the second step of this research an ensemble classifier approach was employed for the combined use of both spectra and the best derivative order. This simultaneous use of the derivative and zero order spectra is introduced as “ECEM”. Experiments were conducted via a HyMap hyperspectral airborne image in eastern Iran. The detection results show that both proposed methods significantly outperform CEM in ROC and AUC values. The best performance upgrade in DCEM detection was about 24% for Kaolinite target and about 28% for Alunite target in ECEM. [ABSTRACT FROM AUTHOR]