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This article addresses a novel finite control-set model predictive control solution for nested neutral point-clamped converter. More specifically, it is formed by incorporating a finite-time extended state observer design into a cascade-free finite control-set model predictive control architecture. In this architecture, a finite-time extended state observer is developed to estimate the total disturbances, and an integral error term and a dynamic reference design point of view are embedded into the proposed design so as to improve the performance. The main features of this proposal are: first of all, the detailed knowledge of the physical structure of the controlled plant is not required; second, a cascade-free structure is achieved in finite control-set model predictive control solution without weighting factors and steady-state error; and third, the proposed methodology can operate with different systems not just power converters, while keeping the fast transient response. In contrast to existing finite control-set model predictive control approaches, it can be found that our modification not only can track fast to their references but also can have superior robustness performance. Finally, the proposed solution is verified by comprehensive results that prove the theoretical researches for nested neutral point-clamped converter, while meeting the harmonic standards. [ABSTRACT FROM AUTHOR]