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In this study, a newly synthesized sepiolite-supported nanoscale zero-valent iron (S-nZVI) adsorbent was tested for the efficient removal of As(III) and As(V) in aqueous solution. Compared with ZVI nanoparticles, the As(III) and As(V) adsorption abilities of S-nZVI were substantially enhanced to 165.86 mg/g and 95.76 mg/g, respectively, owing to the good dispersion of nZVI on sepiolite. The results showed that the adsorption kinetics were well fitted with the pseudo-second-order model, and the adsorption isotherms were fitted with the Freundlich model, denoting a multilayer chemical adsorption process. The increase in the initial solution pH of the solution inhibited As(III) and As(V) adsorption, but a weaker influence on As(III) than As(V) adsorption was observed with increasing pH. Additionally, the presence of SO 4 2- and NO 3 - ions had no pronounced effect on As(III) and As(V) removal, while PO 4 3- and humic acid (HA) significantly restrained the As(III) and As(V) adsorption ability, and Mg 2+ /Ca 2+ promoted the As(V) adsorption efficiency. Spectral analysis showed that As(III) and As(V) formed inner-sphere complexes on S-nZVI. As(III) oxidation and As(V) reduction occurred with the adsorption process on S-nZVI. Overall, the study demonstrated a potential adsorbent, S-nZVI, for the efficient removal of As(III) and As(V) from contaminated water.

The novel coronavirus (COVID-19) pandemic has provided a distinct opportunity to explore the mechanisms by which human activities affect air quality and pollution emissions. We conduct a quasi-difference-in-differences (DID) analysis of the impacts of lockdown measures on air pollution during the first wave of the COVID-19 pandemic in China. Our study covers 367 cities from the beginning of the lockdown on 23 January 2020 until April 22, two weeks after the lockdown in the epicenter was lifted. Static and dynamic analysis of the average treatment effects on the treated is conducted for the air quality index (AQI) and six criteria pollutants. The results indicate that, first, on average, the AQI decreased by about 7%. However, it was still over the threshold set by the World Health Organization. Second, we detect heterogeneous changes in the level of different pollutants, which suggests heterogeneous impacts of the lockdown on human activities: carbon monoxide (CO) had the biggest drop, about 30%, and nitrogen dioxide (NO 2 ) had the second-biggest drop, 20%. In contrast, ozone (O 3 ) increased by 3.74% due to the changes in the NO x /VOCs caused by the decrease in NO x , the decrease of O 3 titration, and particulate matter concentration. Third, air pollution levels rebounded immediately after the number of infections dropped, which indicates a swift recovery of human activities. This study provides insights into the implementation of environmental policies in China and other developing countries.