1. Desorption experiments and modeling of micropollutants on activated carbon in water phase: application to transient concentrations mitigation
- Author
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Marie-Hélène Manero, Matthieu Jacob, Romain Richard, Sabine Sochard, Séda Bourneuf, Claire Albasi, Laboratoire de génie chimique [ancien site de Basso-Cambo] (LGC), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées, Total SA Pôle d'études et de recherche de Lacq (PERL), TOTAL FINA ELF, LABORATOIRE DE THERMIQUE ENERGETIQUE ET PROCEDES (EA1932) (LATEP), Université de Pau et des Pays de l'Adour (UPPA), Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - INPT (FRANCE), Total (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Université de Pau et des Pays de l'Adour - UPPA (FRANCE), Laboratoire de Thermique, energétique et procédés - LATEP (Pau, France), and Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
- Subjects
Pollution ,LDF ,Environmental Engineering ,Activated carbon ,media_common.quotation_subject ,Analytical chemistry ,Ingénierie de l'environnement ,02 engineering and technology ,010501 environmental sciences ,01 natural sciences ,Adsorption ,Organics ,Desorption ,Phase (matter) ,medicine ,Environmental Chemistry ,Water treatment ,0105 earth and related environmental sciences ,media_common ,Pollutant ,Chromatography ,[SDE.IE]Environmental Sciences/Environmental Engineering ,Chemistry ,Attenuation ,Modeling ,021001 nanoscience & nanotechnology ,6. Clean water ,13. Climate action ,0210 nano-technology ,General Agricultural and Biological Sciences ,medicine.drug - Abstract
International audience; Experimental studies and numerical modeling were conducted to assess the feasibility of a granular activated carbon column to buffer load variations of contaminants before wastewater treatment devices. Studies of cycles of adsorption, and more especially desorption, of methyldiethanolamine (MDEA) and 2,4-dimethylphenol (2,4-DMP) have been carried out on granular activated carbon (GAC). Dynamic variations of contaminants concentrations were run at several conditions of duration (peaks). GAC fixed-bed exhibited a stable adsorption/desorption capacity after undergoing two conditioning cycles. The study of pollution peaks revealed that attenuation is largely dependent on the targeted pollutant: 2.4 ± 0.5 % attenuation/cm of bed for MDEA and 6.0 ± 1.2 % attenuation/cm of bed for 2,4-DMP. Mass balances calculated from both injected and recovered pollutant during peaks were respected. Finally, a coupling of the linear driving force model and isotherms models was used to fit experimental data for both adsorption breakthrough curves and desorption curves. The model was used to predict adsorption and desorption behaviors of following cycles. Good agreement with experimental values was obtained.
- Published
- 2015
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