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• Heat and mass transfer model of pyrolysis gases in a confined space was developed. • Growth rates of pyrolysis product concentrations were determined. • Synergistic effects were identified for different fire hazard sources. • Role of ventilation in the growth of pyrolysis gases concentrations was defined. • Correlation of room sizes with concentrations of pyrolysis gases was established. Numerical research findings are presented on the patterns of spread of thermal decomposition products of wood-based materials in confined spaces isolated from the external environment. Based on the experimental data, a physical problem statement was formulated and a mathematical model of heat and mass transfer was developed for rooms with the most typical sources of fire hazard. The experimental and numerical research findings were obtained for the conditions corresponding to compartments isolated from the external environment (e.g., rooms at dedicated facilities, like ships, small and medium-sized rooms) and to underventilated rooms. The performed experiments and calculations revealed satisfactory agreement in the findings and demonstrated the validity of the proposed model of heat and mass transfer. Wood was used as the main material in fires. A comparative analysis was also carried out for paper of different quality. The modeling was performed for the most frequent causes of fires: careless handling of fire, unsafe operation of heating equipment and electrical short circuits. The rates of growth of thermal decomposition product concentrations were determined for different distances from the material. The impact of a number of factors on the characteristics under study was determined. These are the fire and room sizes, fire cause, supply and exhaust ventilation. The data were extrapolated to the conditions corresponding to business, warehouse and residential premises. [Display omitted] [ABSTRACT FROM AUTHOR]