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Loosening local equilibrium assumptions in two-phase flow in porous media gives rise to new, unknown variables. More specifically, when loosening the local thermal equilibrium assumption, one has to describe the heat transfer between multiple phases, present at the same mathematical point. In this paper, we calibrate a macro-scale mathematical model which is free of local equilibrium assumptions to experimental observations. We emphasize the correct determination and upscaling of necessary input parameters from the experimental data achieved by image analysis. By choosing an appropriate scaling parameter, we are able to reproduce experimental measurements satisfactorily. This is a first step towards quantifying heat transfer in two-phase flow in porous media. Ultimately, our aim is to find the limits of the applicability of local equilibrium assumptions in two-phase flow in porous media. [ABSTRACT FROM AUTHOR]

Abstract: This paper developed a mathematical model for the coupled heat and mass transfer in porous media based on the fractal characters of the pore size distribution. According to Darcy’s law and Hagen–Poiseuille’s law for liquid flows, the diffusion coefficient of the liquid water, a function of fractal dimension, is obtained theoretically. The liquid flow affected by the surface tension and the gravity, the water vapor sorption/desorption by fibers, the diffusion of the water vapor and the phase changes are all taken into account in this model. With specification of initial and boundary conditions, distributions of water vapor concentration in void spaces, volume fraction of liquid water, distribution of water molecular content in fibers and temperature changes in porous fibrous media are obtained numerically. Effects of porosity of porous fibrous media on heat and mass transfer are analyzed. The theoretical predictions are compared with experimental data and good agreement is observed between the two, indicating that the fractal model is satisfactory. [ABSTRACT FROM AUTHOR]