1. Analysis of fading characteristics of a lithium ion battery based on an integration model
- Author
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Giorgio Rizzoni, Pengju Zhao, Mofan Li, and Jianqiang Kang
- Subjects
Fluid Flow and Transfer Processes ,Battery (electricity) ,Materials science ,020209 energy ,Mechanical Engineering ,Multiphysics ,Electrochemical kinetics ,Thermodynamics ,02 engineering and technology ,Condensed Matter Physics ,Lithium-ion battery ,State of charge ,0202 electrical engineering, electronic engineering, information engineering ,Constant current ,Fading ,Voltage - Abstract
We utilize an integration model of capacity degradation in electrochemical kinetics to analyze the fading characteristics of a lithium-ion battery. On the basis of the assumed parameters of the parasitic reaction, the characteristic of the lithium-ion battery are simulated before and after 100 charge–discharge cycles with the Comsol Multiphysics 4.3 software. After 100 cycles, the curves of voltage vs. state of charge under charge or discharge display a descending trend. The charge and discharge capacities decrease 8.0% and 3.85% at 1 C constant current when the cut-off voltages are set at 4.3 V and 2.8 V, respectively. In addition, the decreased capacity is related significantly to the applied current rate. By analysis, the decreased capacity due to the consumed Li + concentration by the solid-electrolyte interphase reaction is only about 0.05%, showing an extremely slight influence. Thus, the elevated film resistance plays a crucial role in decrement of the capacity. The results also display that state of charge should be set at a lower value, at least under 57%, to protect the battery from fading when it is stored for a long time.
- Published
- 2017