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The escalating demand for renewable energy solutions and the imperative for efficient energy storage mechanisms have catalyzed the evolution of Power-to-X (PtX) technologies. Germany has the most PtX projects, accounting for 44% of all projects that have been reported. PtX encompasses a spectrum of processes engineered to convert surplus renewable energy into versatile energy carriers or chemical commodities, such as hydrogen, methane, or synthetic fuels. The Paramount to this domain is to synergistically harness renewable energy sources and hydrogen carriers to curtail waste and bolster sustainability. Central to achieving this synergy is the effective control of PtX processes, ensuring optimal performance, cost efficiency, and seamless integration within existing energy frameworks. This paper delves into the control processes and environmental prerequisites within the PtX landscape, elucidating key challenges, and strategies within this dynamic realm. While providing an initial overview of fundamental PtX process chains, this paper accentuates the critical role of geographical considerations. Subsequently, it conducts a thorough analysis of equipment modeling challenges, addressing performance metrics, operational requisites, and capital investments, particularly focusing on methanol and hydrogen production and storage. Through holistic examination, this paper endeavors to delineate the evolving landscape of PtX control processes and conditions, advancing our understanding of this expanding field. [Display omitted] • Comprehensive overview of PtX control process, challenges, strategies, and advancements. • Overview of PtX process chains and geographical conditions. • Analysis of equipment modeling challenges for methanol and hydrogen. • Addressing crucial storage challenges in PtX system. • Exploration of diverse influences on PtX control processes. [ABSTRACT FROM AUTHOR]

This paper examines the potential of solar and hydrogen (H 2) energy-based hybrid energy systems for residential applications. The growing need for energy and the demand for sustainable energy sources have led to the development of integrated energy systems that combine renewable energy resources to meet energy needs. This paper overviews recent studies on hybrid energy systems for on-grid and off-grid residential utilizations. It discusses the system configuration and components of hybrid energy systems, including solar panels, electrolyzers, fuel cells (FC), and batteries. It also covers the technical optimization of integrated energy systems, including sizing, control strategies, and economic analysis. The key findings of this review paper indicate that hybrid energy systems can offer dependable and sustainable energy for residential applications. Through numerical analyses, the optimal dimensioning of the system elements and control strategies can significantly enhance the system's performance and lower the cost of energy. This study also highlights the challenges and opportunities for integrating hybrid energy systems within residential applications. Overall, it provides in-depth perspectives on the possibilities inherent in solar and hydrogen energy-based hybrid energy systems for residential applications. The findings can guide future research and the advancement of hybrid energy systems for sustainable energy solutions. • Comprehensive review on solar and hydrogen-based residential applications. • Holistic approach to system configuration, optimization, and economics. • Detailed analysis of interconnected components enhancing system efficiency. • Unique focus on real-world residential applications and scenarios. • Broad applicability across diverse geographical regions. [ABSTRACT FROM AUTHOR]

Transitioning to a sustainable energy future necessitates innovative storage solutions for renewable energies, where hydrogen (H₂) emerges as a pivotal energy carrier for its low emission potential. This paper explores unlined rock caverns (URCs) as a promising alternative for underground hydrogen storage (UHS), overcoming the geographical and technical limitations of UHS methods like salt rock caverns and porous media. Drawing from the experiences of natural gas (NG) and compressed air energy storage (CAES) in URCs, we explore the viability of URCs for storing hydrogen at gigawatt-hour scales (>100 GWh). Despite challenges such as potential uplift failures (at a depth of approximately less than 1000 m) and hydrogen reactivity with storage materials at typical conditions (below temperatures of 100°C and pressures of 15 MPa), URCs present a flexible, scalable option closely allied with green hydrogen production from renewable sources. Our comprehensive review identifies critical design considerations, including hydraulic containment and the integrity of fracture sealing materials under UHS conditions. Addressing identified knowledge gaps, particularly around the design of hydraulic containment systems and the interaction of hydrogen with cavern materials, will be crucial for advancing URC technology. The paper underscores the need for further experimental and numerical studies to refine URC suitability for hydrogen storage, highlighting the role of URCs in enhancing the compatibility of renewable energy sources with the grid. • Detailed exploration of unlined rock cavern (URC) technology. • Analysis of URCs' potential for large-scale hydrogen storage. • Insights from historical use of URCs in compressed gas storage. • Examination of the opportunities and challenges in using URCs for hydrogen storage. [ABSTRACT FROM AUTHOR]

Hydrogen is a relatively new source of sustainable energy resources; presently, its usage ranges from direct energy generation in mixed-cycle thermal power plants to its usage in the internal combustion engine. If the generation of hydrogen is coupled with renewable energy resources, the use of hydrocarbons can be substantially reduced in both energy generation and transportation. In this paper, we conducted a national-level assessment to identify the hydrogen generation capacity of Pakistan. The methodology used in this study is a combination of spatial multi-criteria analysis and density-based clustering in a geographical information systems environment. Based on the analysis, the national clusters capable of producing green hydrogen were identified. The results shows that the hydrogen generation capacity for Pakistan is approximately 7 million tons per year using solar photovoltaic energy. The Surab-Gwadar alignment, N-25 national highway, and Quetta-to-D-I-Khan alignment offer potential hydrogen generation sites with water resources. Most of the identified sites for the production of hydrogen in the country were found to be near the national electricity transmission networks. The Best-Worst Method was further employed to provide policymakers with a road map for prioritizing the development of these capacities based on their proximity to the national networks, their terrain suitability, and their generation capacities. • This paper assesses the suitable sites for solar-based green hydrogen production in Pakistan. • The methodology used involves a combination of spatial multicriteria analysis, clustering, and the best-worst method. • Pakistan's theoretical annual hydrogen generation capacity is around 7 million tons annually. • The Surab-Gwadar alignment presents promising hydrogen generation opportunities. [ABSTRACT FROM AUTHOR]

The paper is devoted to the development of a device for protecting facilities with turn-to-turn insulation, namely transformers and wind generators in order to increase the reliability of operation of electrical power systems, renewable energy installations and energy storage systems. The paper presents the results of experimental studies of the parameters of a prototype frequency-dependent device, as well as an assessment of the effectiveness of suppression of high-frequency surge voltages by the proposed device. The results of four groups of measurements are shown, which were compared with each other and with the results of previously showed computer simulations. The high efficiency of the proposed device when influencing the slope and amplitude of short high-frequency transients is shown. It is indicated that the parameters proposed earlier in the simulation allow the device to be used effectively. A brief analysis of alternative methods and means of protection is provided, and the prospects for using the device as protective equipment for wind power plants are also considered. [ABSTRACT FROM AUTHOR]

Green hydrogen is crucial for society's access to peaceful, secure, and stable energy sources to flourish sustainably and get universal government support. To protect the environment and provide energy security, it is essential to use hydrogen as a sustainable fuel and energy source to cover the energy baseload. This paper investigates the developments of renewable energy (RE) and the potential for green hydrogen in the Middle East and North Africa (MENA) region. There is a considerable chance to use RE because of the MENA region's excellent solar radiation. On the other hand, many countries in the MENA region are classified as one of the poorest in water resources and are known to have water-energy challenges. This paper focuses on the water needed to produce hydrogen in countries with water scarcity. A strengths, weaknesses, opportunities, and threats (SWOT) analysis was performed for green hydrogen generation in the MENA, where recommendations for countries with a water-energy nexus can be made. Additionally, this paper offers suggestions for creating a sustainable hydrogen economy, such as cutting back on the domestic use of fossil fuels, subsidizing the renewable production industry, and supporting hydrogen manufacturing. • Green hydrogen production is highly affected by water scarcity. • SWOT analysis was performed on green hydrogen generation in the MENA. • Recommendations were provided on a country-by-country basis. [ABSTRACT FROM AUTHOR]

This study presents a bibliometric review focusing on the utilization of water electrolysis as a means of generating hydrogen as an energy carrier. The analysis includes research conducted over the past decade, covering from 2014 to 2023 (till August). Several key aspects are highlighted, including publication trends, the leading country in research output, journal rankings, and a citation analysis of papers related to water electrolysis. The findings reveal a notable increase in publication trends, with China emerging as the leading contributor in this research area. Furthermore, the International Journal of Hydrogen Energy is identified as the highest-ranked journal in terms of both publication number and citation impact. Additionally, the top ten most cited research articles and review papers are investigated to determine their influence within the field. To gain a deeper understanding of water electrolysis methods, the three primary approaches: alkaline water electrolysis (AWE), proton exchange membrane (PEM) electrolysis, and solid oxide electrolysis (SOE) is examined. The analysis emphasizes that PEM electrolysis is the most prevalent method for hydrogen generation, particularly when integrated with renewable energy sources such as solar and wind power due to its rapid response to electrical input fluctuation. Finally, the challenges and future directions of water electrolysis in hydrogen production are highlighted, including an exploration of economic and environmental considerations at large scale, offering insights into the path forward for advancing this technology sustainably. • A comprehensive bibliometric analysis of water electrolysis for hydrogen production. • Publication trends, journal rankings, and citation analysis are highlighted. • China is identified as the leading contributor in water electrolysis publications. • International Journal of Hydrogen Energy: the highest-ranked journal in this field. • Specific electrolysis methods, including AWE, PEM, and SOE are examined. [ABSTRACT FROM AUTHOR]

Clean energy devices have a great ability to change the world because they strengthen the economy and preserve society. The continuous improvement and progress in nanomaterials and nanotechnology have a great role in human life. The increasing prevalence of PEM fuel cells makes them one of the most viable sustainable energy sources. Nanostructured materials synthesis methodologies have introduced a breakthrough and found to overcome the obstacles for PEMFC commercialization. Amongst them, wet chemical approaches are rapidly expanding and beneficial for the fabrication of nanoparticles since they contribute toward the attainment of a range of essential nanoparticle characteristics like sizes, morphologies, structures, and phases. Wet chemical manufacturing enables fine-tuning of reaction parameters to generate the desired nanomaterials. This review article focuses on the latest improvements in wet chemical methods to better regulate the quality of nanomaterials. This paper examines how wet chemical approaches (hydrothermal synthesis, spray pyrolysis, sol-gel processing, and co-precipitate synthesis, among others) can contribute to the scalable manufacturing of nanoparticles to uphold rising industrial requirements. And how wet chemical methods have a significant influence on power generation systems (Fuel cells) along with their pros and cons. This review carefully analyzes and summarizes synthetic methods and optimized factors in order to prepare nanoparticles and carefully analyzes the reported data. In this paper, the electrochemical analysis, morphological evaluation, compositional analysis, and performance testing of materials produced using wet chemical techniques have been investigated. Recent signs of progress and innovative techniques used to overcome the complexities of synthetic nanoparticle processing. This article is a holistic approach including social, economic, and ecological aspects in the wet chemical process and will certainly help in the fabrication, and application of nanoparticles for PEM Fuel cells. [Display omitted] • Introduction to the status of materials synthesis in energy generating devices. • Overview of wet chemistry Approaches for PEMFC. • Impact of synthesis parameters on properties of materials. • Pros and Cons of wet chemistry techniques for material synthesis. [ABSTRACT FROM AUTHOR]

In pursuit of energy transition objectives, Algeria is increasingly focusing on the production and utilization of low-carbon and renewable hydrogen. While hydrogen has predominantly been used in the chemical and refining industries, it holds promise for decarbonizing specific industrial sectors, enabling electricity storage, and powering the transport sector. However, several barriers must be overcome before hydrogen technologies can be widely deployed. Numerous countries, with Japan at the forefront, are heavily investing in this burgeoning market, anticipating the creation of thousands of new jobs. Hydrogen offers Algeria significant potential for greenhouse gas (GHG) reduction and substantial economic benefits. In response, the Algerian government has prioritized energy transition to new and renewable sources as part of its economic recovery plan, aiming for "green" growth through innovative and digital energy technologies. This paper's primary objective is to provide a techno-economic foundation for guiding public policy development, identifying promising opportunities for green hydrogen within Algeria's energy transition context, and outlining sustainable pathways for pilot projects that promote hydrogen adoption within the Algerian society. Additionally, this paper will explore the latest advancements in hydrogen research, technology, and applications relevant to the Algeria's energy transition. The Algerian energy minister, has reaffirmed his desire to "invest in hydrogen", an energy source presented as one of the solutions to the climate crisis. In October 2021, Algeria launched a hydrogen plan worth several billion dinars, including 100 million for research, to enable the country to develop "green" hydrogen, i.e. produced without fossil fuels. • Algeria's energy transition mission focuses on promoting energy transition, innovation, and efficiency. • The Algerian Strategy on Green Hydrogen 2050 intends to establish a supportive framework for hydrogen sector development. • Algeria has set ambitious targets: reducing its GHG emissions by 2030 and lowering its consumption of petroleum products. • Algeria export between 30 and 40 TWh by 2040 of gaseous green hydrogen, liquefied, and derived. [ABSTRACT FROM AUTHOR]

Green H 2 (GH) has emerged as a highly promising medium for the transportation of eco-friendly energy. The utilization of H 2 as the primary operational medium in H 2 -based energy storage systems and fuel cells has facilitated the integration of these systems with various other renewable energy sources, rendering such integration highly viable. This review presents an overview of the current advancements in the field of GH production techniques using water electrolyzers powered by renewable energy sources. The present paper starts with a concise overview of several production techniques and a detailed analysis of various types of water electrolyzer. It also offers a thorough examination of H 2 production methods utilizing solar, wind, and hybrid systems. An economic evaluation of GH production was analyzed by comparing the costs associated with different renewable sources. This study focuses on investigating the challenges and advantages of GH and the implementation of large-scale commercial operations. The proton exchange membrane water electrolyzer (PEMWE) technologies boast higher current densities (1-2Acm−2) than alkaline water electrolyzer (AWE); the PEMWE technologies also produce a higher purity of H 2 up to 99.9999 %. The wind energy-associated PEM LCOH ranges from 5.3 to 9.29 $/kg. AWE had levelized cost of H 2 (LCOH) of 7.49–7.59 $/kg. Other studies show that SOE-based LCOH ranges from 6 to 9.34 $/kg and should drop to 1.9 $/kg by 2050. The cost of GH was found to be significantly influenced by the rated wind speed compared to other wind turbine parameters, and it ranged from $1.7/kg to $40.00/kg. [Display omitted] • GH could help reduce global warming and transition to a more sustainable energy system. • Discussion on grand challenges, prospects, and key recommendations to the commercialization of water electrolysis systems. • The lack of global hydrogen standards hinders the growth of the global hydrogen market. [ABSTRACT FROM AUTHOR]

To tackle the carbon emission problem, the exploitation of renewable energy resources (RESs) with zero emissions has gained much importance. In this context, hydrogen has become an important resource to involve itself in distributed energy resources (DERs) to generate electricity, energize vehicles, and heat our living areas. The utilization of hydrogen technologies is indispensable due to their procurement, environmental friendliness, and high efficiency for DERs. A challenging area in the field of hydrogen energy technologies is extracting efficient power and integration to DERs. This paper investigates how to model and operate a proton exchange membrane fuel cell (PEMFC) stack in a DER application to establish a living lab facility for educational and research purposes by covering Power-to-X (P2X). The PEMFC model of the studied system is designed in a MATLAB/Simulink environment and implemented in an experimental testbed. Thus, a fuel cell (FC) unit as a complementary source is preferred to be used near a photovoltaic (PV) array, a small-scale wind turbine (WT), and a lead acid battery energy storage system (BESS) by creating a P2X concept to form a living lab platform. Beyond the model, regarding the experimental part, a PV array, a WT, and a BESS are combined with a PEMFC module that is rated output of 1200 W. Expect for all systems, the FC part is emphasized in this study. Also, a dynamic model of the mentioned PEMFC is proposed and verified. • Importance of hydrogen energy is focused on its advantages, future role, potential, and challenges. • FC unit as a complementary source is evaluated by creating a P2X concept. • This platform is designed to meet the energy needs of research-education, diversify the supply, increase energy independence. • Energy procurement is supplied via green energy during a lesson, which is noteworthy and instructive. • Feasibility of combined PV/WT/BESS/PEMFC system is investigated. [ABSTRACT FROM AUTHOR]

Due to the widespread use of multi-generation systems utilizing renewable energy sources and the growing global demand for such systems from both economic and environmental considerations, numerous researchers have focused on the design and evaluation of their performance. To this end, this research presents a biomass-based multi-generation system with an innovative and practical design that can generate electricity, heat, and hydrogen. This system includes a modified gas turbine cycle, a supercritical CO 2 (SCO 2) cycle, a transcritical CO 2 (TCO 2) cycle, a proton exchange membrane (PEM) electrolyzer, and a PEM fuel cell unit. This study aims to evaluate the impact of various biomass sources (paper, wood, paddy husk, and municipal solid waste) on the system performance. The proposed system has been analyzed using the first and second laws of thermodynamics. This system uses the maximum capacity to produce power, heat and hydrogen. A fuel cell unit has been used to consume hydrogen and generate more electricity. In the basic mode, the system has energy and exergy efficiencies of 47.89% and 32.26%, respectively, and can produce 2.74 kg/h of hydrogen. The biomass fuel consumption rate within the system is 0.055 kg/s. The overall exergy destruction of the system amounts to 1240 kW, with the biomass boiler and the condenser being the components that experience the greatest exergy destruction, registering values of 535.5 kW and 432.3 kW, respectively. Notably, employing municipal waste as biomass increases the system's exergy efficiency to 33.16%. • To investigate a biomass-driven system for producing power, hydrogen, and heating. • To evaluate the impact of various biomass sources on the system performance. • To use PEME for hydrogen and PEMFC for power and heat production. [ABSTRACT FROM AUTHOR]

The presented paper focuses on renewable energy-assisted electricity, hydrogen, and cold energy production. Solar energy is used as the energy source in the study. The organic Rankine cycle (ORC) is used for electricity generation, a proton exchange membrane electrolyzer (PEMe) for hydrogen production, and an ejector refrigeration system for cold energy production. The study is based on the exergy concept and examines thermo-economic and thermo-environmental analyses. The exergy efficiency of each equipment in the system is calculated from a holistic perspective. Considering the energy consumption values of the equipment in the whole system, the cost required for hydrogen production is calculated as 1.086 $/kg. Additionally, the exergy efficiency of the whole system is found to be 2.082 %. • Thermodynamic analysis of the solar-based hydrogen production system. • The exergy efficiency of the whole system is found as 2.082 %. • The cost of green hydrogen production is found as 1086 $/kg. [ABSTRACT FROM AUTHOR]

The necessity of employing renewable energy sources within microgrid-based Power-to-X (P2X) systems has been emphasized by the imperatives of reducing global warming and fossil fuel consumption. Due to their numerous advantages, solar and wind energy have acquired prominence in contemporary power systems. However, their intermittent nature presents challenges. To overcome these challenges, energy storage devices are utilized. Batteries, however, are plagued by issues such as high maintenance needs, self-discharge, and diminishing storage capacity with age. Consequently, investigating alternatives such as hydrogen storage has become a financially viable option, especially for high-power applications. However, the intrinsically slow dynamics of hydrogen production from electricity contrast with the rapid responses of contemporary power electronic devices. This paper presents a versatile technique for optimizing hydrogen production in the presence of stochastic fluctuations in solar irradiance and wind speed. The proposed method combines a modified version of the Symbiotic Differential Whale Optimization Algorithm (m-SDWOA) with power converters to maximize production from renewable sources and electrolyzers. Using extensive simulations to demonstrate the efficacy of the proposed method by comparing its performance to that of the Whale Optimization Algorithm (WOA) and Particle Swarm Optimization (PSO). The results demonstrate the superior performance of the m-SDWOA-integrated method and pave the way for improved hydrogen generation in microgrid-based P2X systems. • Innovative control framework coordinates WT, PV, BESS, and HESS. • Maximizes hydrogen production while maintaining power quality. • Efficient controllers stabilize DC-bus voltage amidst WT/PV variability. • Ensures consistent, reliable power supply in microgrid. • Efficient energy management via m-SDWOA for resource optimization. [ABSTRACT FROM AUTHOR]

In response to climate change and the imperative for sustainable energy solutions, this study investigates the feasibility of producing green hydrogen and associated e-fuels (methane, methanol, and ammonia) using a renewable energy hybrid system in Dakhla, Morocco. Utilizing the System Advisor Model (SAM) software for simulation-based analysis, the research evaluates a hybrid system combining concentrated solar power (CSP) and photovoltaic (PV) plants against standalone counterparts. Various simulations comparing standalone PV and CSP plants with a novel CSP/PV hybrid concept were carried out. The hybrid system demonstrates significant promise, exhibiting increased annual energy yield and capacity factors up to 90%, leading to enhanced efficiency, performance, and cost savings with a Levelized Cost of Electricity (LCOE) approximating 17 cents/kWh. Furthermore, this paper conducts an in-depth exploration into the feasible production of hydrogen and its derived synthetic fuels utilizing hybrid renewable systems. The study provides a thorough examination of the production processes, yields, and efficiencies of hydrogen and its derivative e-fuels, with a focus on green hydrogen production through water electrolysis, CO2 hydrogenation, the Sabatier process, and the Haber-Bosch process. It sheds light on the potential applications of these fuels in the transportation sector, including in electric and hydrogen vehicles and aviation. The insights garnered are indispensable for crafting future strategies and policies in sustainable energy planning. These findings not only provide valuable direction for forthcoming initiatives in renewable energy but also underscore the pivotal role of hybridization in enhancing the efficient production and utilization of hydrogen within both renewable energy and transportation sectors. • PV and CSP systems to generate electricity for the Dakhla city was investigated. • A Hybrid system optimization has been proposed. • The Electricity surplus was used to produce hydrogen and hydrogen-based products. • Various scenarios for the heavy-duty application of e-fuel were presented and discussed. [ABSTRACT FROM AUTHOR]

Green hydrogen is central to the global energy transition. This paper introduces a renewable hydrogen production system model that optimizes hydrogen production on a worldwide 50 km × 50 km grid, considering country-specific investment risks. Besides the renewable energy's impact on the hydrogen production system (HPS) design, we analyze the effect of country-specific interest rates on the levelized cost of hydrogen (LCOH) production. Over one-third (40.0%) of all cells have an installed solar PV capacity share between 50% and 70%, 76.4% have a hybrid (onshore wind and solar PV) configuration. Hydrogen storage is deployed rather than battery storage to balance hydrogen production via electrolysis and hydrogen demand. Hybrid HPSs can significantly reduce the LCOH production compared to non-hybrid designs, whereas country-specific interest rates can lead to significant increases, diminishing the relative competitiveness of countries with abundant renewable energy resources compared to countries with fewer resources but fewer investment risks. [Display omitted] • Worldwide levelized cost of hydrogen production on a 50 km × 50 km grid resolution. • Impact of country risk premiums on the levelized cost of hydrogen production. • Cost-optimal hybrid hydrogen production system design per grid cell. • All results are available on an open-data license. [ABSTRACT FROM AUTHOR]

There is a great desire to integrate multiple energy systems by forming low-carbon energy hubs. Among various energy platforms, the integration of power and gas networks via Power-to-Gas (PtG) technologies is introduced as a promising solution to enhance the flexibility of power grids and facilitate seamless adoption for high penetration levels of renewable energy resources. In addition, the production of green hydrogen from waste/inexpensive clean electricity has recently been identified as a potential means for large-scale energy storage, deployment of hydrogen mobility, and decarbonization of several processes that utilize hydrogen. As integrated hydrogen-based energy hubs (H 2 Hubs) attract more attention for widespread deployment, the security of such new platforms against various cyberattacks is also becoming a critical topic for investigation. This paper proposes a new data estimation technique, developed and integrated with H 2 Hubs scheduling models, for real-time optimal adaptive collection and organization of the system operating parameters for cybersecurity assessment. A new formulation is presented for the adaptive formation of a newly proposed concept, referred to as the system feasibility area , via real-time acquisition of the system operating information. The created feasibility areas are utilized for real-time post-occurrence detection of the bad scheduling data that is invisible to the existing cybersecurity layers. Numerical studies are conducted to demonstrate the efficacy and feasibility of the proposed model. The results demonstrate that the historical data can be adaptively collected in real time and successfully utilized to create feasibility areas to categorize the system operating points. • An optimal scheduling model is proposed for hydrogen-based energy hubs (H 2 Hubs). • A new data estimation method is developed and integrated with the scheduling model. • A new formulation is given for the adaptive creation of the feasibility area. • Simulation case studies are presented and discussed. [ABSTRACT FROM AUTHOR]

Due to the increase in electric energy consumption and the significant growth in the number of electric vehicles (EV) at the level of the distribution network, new networks have started using new fuels such as hydrogen to improve environmental indicators and at the same time better efficiency from the excess capacity of renewable resources. In this article, the services that can be provided by hydrogen refueling stations and charging electric vehicles in the optimal performance of microgrids have been investigated. The model proposed in this paper includes a two-stage stochastic framework for scheduling resources in microgrids, especially hydrogen refueling stations and electric vehicle charging. In this model, two main goals of cost minimization and greenhouse gas emissions are considered. In the proposed framework and in the first stage, the service range of microgrids is determined precisely according to the electrical limitations of distribution systems in emergency situations. Then, in the second stage, the problem of energy management in each microgrid will be solved centrally. In this situation, various indicators including the output energy of renewable sources, smart charging of hydrogen and electric vehicle charging stations (EV/FCV) and flexible loads (FL) are evaluated. The final mathematical model is implemented as a multivariate integer multiple linear problem (MILP) using the GUROBI solver in GAMS software. The simulation results on the modified IEEE 118-Bus network show the positive effect of the presence of flexible loads and smart charging strategies by charging stations. Also, the numerical derivation shows that the operating costs of the entire system can be reduced by 4.77% and the use of smart charging strategies can reduce greenhouse gas emissions by 49.13%. • Embedding network security constraints to ensure that each microgrid operates within safe voltage levels and avoids line capacity. • Examining the impacts of flexible loads and the charging patterns of EVs and FCVs on operational costs. • Incorporating hydrogen storage systems and refueling stations in the model to mitigate the adverse effects of renewable energy fluctuations. • Establishing a multi-objective model to consider both economic and environmental aspects of energy management in the proposed model. [ABSTRACT FROM AUTHOR]

Hydrogen energy is one of promising non-polluting and renewable energy sources. In this paper, we present a first principal study of hydrogen storage in pure C 60 fullerene cage and Stone-Wales (SW) defective C 60 cages using density functional theory (DFT) with applying both the exchange functional B3LYP and the dispersion correction wb97xd at 6–31+g(d,2p) basis set. In addition, the counterpoise correction is applied, and the basis set superposition error is calculated. The calculations underscore that the hydrogenation binding energy of C 60 cages occurs through an endothermal process for C 60 H in with a hydrogen binding energy of 0.09 eV and through an exothermal process for C 60 H out , C 60 SW 66 H out , and C 60 SW 65 H out , cages with hydrogen binding energies of −2.17 eV, −2.96 eV, and −2.20 eV, respectively. Remarkably, for the first time, the intermediate hydrogen binding energy is found inside C 60 SW 66 H in fullerene, and C 60 SW 65 H in fullerene cages with energies of −0.26 eV and −0.81 eV, respectively. The hydrogen adsorption inside the cavity of C 60 SW 66 fullerene cage is thermodynamically possible below 289.8 K and entire pressure range considered. Our results highlight, for the first time, that the endohedral cavity of C 60 SW 66 is a promising new medium for hydrogen storage due to its binding energies (−0.26 eV) and its hydrogen storage weight percentage (5.3%) that are close to the optimal conditions specified by DOE for commercial use. In addition, this study opens up a new discovery of Stone-Wales defective C 60 fullerene for further endohedral cavity applications. • New insight into endohedral cavity of Stone Wales C 60 SW 66 is reported. • For the first time, a new promising medium for hydrogen storage inside cavity of C 60 SW 66 is proved. • Binding energies of −0.26 eV and hydrogen storage weight percentage up to 5.3% are achieved inside the cavity of C 60 SW 66. • This study opens a new discovery of the SW defective C 60 fullerene for further endohedral cavity applications. [ABSTRACT FROM AUTHOR]

By offering promising solutions to two critical issues – the integration of renewable energies into energy systems and the decarbonization of existing hydrogen applications – green hydrogen production through water electrolysis is set to play a crucial role in addressing the major challenges of the energy transition. However, the successful integration of renewable energy sources relies on gaining accurate insights into the impacts that intermittent electrical supply conditions induce on electrolyzers. Despite the rising importance of addressing intermittency issues to accelerate the widespread adoption of renewable energy sources, the state-of-the-art lacks research providing an in-depth understanding of these concerns. This paper endeavors to offer a comprehensive review of existing research, focusing on proton exchange membrane (PEM) and alkaline electrolysis technologies operating under intermittent operation. Despite growing interest over the last ten years, the review underscores the scarcity of industrial-scale databases for quantifying these impacts. [Display omitted] • Dynamic features, e.g. event frequency and amplitude, affect efficiency and durability of alkaline and PEM electrolyzers. • Intermittent operation promotes electrolyzer decay, but literature lacks consensus and studies on alkaline technology. • Industrial-scale assessments of intermittency impacts are significantly lacking for both alkaline and PEM technologies. • Developing standardized methods is crucial to understand how intermittency affects electrolyzer efficiency and durability. [ABSTRACT FROM AUTHOR]

This paper addresses the urgent need for efficient hydrogen storage methods in the context of combating climate change and transitioning to sustainable energy sources. Among various storage options, LiBH 4 is highlighted for its high volumetric and gravimetric energy densities, critical factors in determining its suitability for energy applications. However, challenges arise due to its high thermolysis temperature, which poses difficulties, especially in applications like automotive use where high temperatures are required. The commercial viability of LiBH 4 remains a significant obstacle due to the nascent stage of chemical hydride technology and the absence of large-scale production facilities. Environmental concerns also loom large, as the production of LiBH 4 relies on extensive mining of lithium and boron, known for their environmental impact. Furthermore, the economic feasibility of LiBH 4 as a hydrogen storage medium is questioned, given the substantial portion of total expenses attributed to hydrogen costs, affecting all methods except those based on fossil fuels or electricity. Nevertheless, there is optimism that with technological advancements and improved infrastructure, the costs associated with LiBH 4 and hydrogen storage overall may decrease over time. In conclusion, while LiBH 4 presents promising energy density characteristics, its practical implementation faces challenges such as high production costs, environmental concerns, and technological limitations. Overcoming these obstacles is crucial for realizing a sustainable and carbon-free energy landscape driven by hydrogen. • LiBH 4 shows promise for high energy density storage but faces obstacles high production costs and environmental concerns. • A comprehensive decision matrix analysis showcases the strengths and weaknesses of various hydrogen storage options. • LiBH 4 may find applications in small-scale personal storage due to its safety and energy density. [ABSTRACT FROM AUTHOR]

The shared energy storage system is recognized as a promising business model for the coordinated operation of integrated energy systems (IES) to improve the utilization of energy storage and the consumption of renewable energy. As the hydrogen energy gradually receives more attention, this paper constructs the structure of a hybrid hydrogen energy storage system shared by an IES alliance in a dynamic pricing mode. A bi-level optimization model for the shared hybrid hydrogen energy storage system (SHHESS) is proposed to optimize the capacity configuration decisions and the pricing strategy jointly. The upper level determines the capacity and dynamic price of SHHESS with maximum profits and the lower level obtains the optimal operation of the IES alliance minimizing the total operation costs. The proposed model is solved by an improved PSO-GA algorithm and CPLEX solver. Finally, numerical tests are conducted in different scenarios. The results show that the hybrid energy storage system improves the daily profits of SHHESS by 70.3% and 5.44%, and reduces the renewable energy curtailment by 80.93% and 48.92% respectively compared to the battery-only and hydrogen-only systems. Additionally, the daily operation cost of the IES alliance is 35.2% lower than the individual operation scenario. The proposed model confirms the feasibility and superiority of the hybrid hydrogen energy storage system in a sharing business mode. • Design an interactive structure of a shared hybrid hydrogen energy storage system. • Propose a bi-level planning optimization framework for shared hybrid hydrogen energy storage. • The dynamic price of energy storage sharing service is optimized. • Determine the optimal operation strategy of the integrated energy system alliance. • Propose a hybrid method combining an improved PSO-GA and CPLEX optimizer. [ABSTRACT FROM AUTHOR]

World is presently facing major challenges in energy industry to reduce or replace greenhouse gases (CO 2 , CH 4 , NO x etc.) emissions to net zero in the coming decades while decreasing the reliance on traditional fossil fuels. In the current scenario, hydrogen (H 2) appears to be an excellent alternative energy source to meet the criteria. Storage of H 2 over a long period of time in large quantities poses a significant challenge for its widespread uses. In order to overcome this issue, the idea of using large-scale depleted underground hydrocarbon reservoirs, salt caverns, underground aquifers, etc. is considered to be a suitable option for underground hydrogen storage. However, underground storage of H 2 for a longer time period comes up with a potentially high microbial activity where H 2 can be utilized in the microbial metabolism and converted into undesirable gases like CH 4 and H 2 S which in turn, damage the porous medium due to clogging, acid formation, and corrosion activity. This review paper explores the various scientific challenges during large-scale H 2 storage in porous medium to facilitate the global H 2 economy. Moreover, a detailed description of the effect of subsurface environment conditions such as pressure, temperature, pH, and salinity on microbes is included in this study. In addition to this, steps to counter microbial activity in stored H 2 monitoring and mitigation approaches are also discussed in this article. • Underground hydrogen storage and its mechanism are discussed. • Effect of microorganisms on stored hydrogen and porous media properties comprehensively reviewed. • The impact of microbial activity on subsurface storage environment conditions. • Monitoring and mitigation strategies to counter microbial activities comprehensively reviewed. • Latest treatment proposition of microbial activities and role of biocides in underground hydrogen storage discussed. [ABSTRACT FROM AUTHOR]

The measures needed to limit global warming pose a particular challenge to current fossil fuel exporters, who must not only decarbonise their local energy systems, but also compensate for the expected decline in fossil fuel revenues. One possibility is seen in the export of green hydrogen. Using Algeria as a case study, this paper analyses how different levels of ambition in hydrogen exports, energy efficiency and fuel switching affect the cost-optimal expansion of the power sector for a given overall emissions reduction path. Despite falling costs for photovoltaics and wind turbines, the results indicate that in countries with very low natural gas prices, such as Algeria, a fully renewable electricity system by 2050 is unlikely without appropriate policy measures. The expansion of renewable energy should therefore start early, given the high annual growth rates required, which will be reinforced by additional green hydrogen exports. In parallel, energy efficiency is a key factor as it directly mitigates CO2 emissions from fossil fuels and reduces domestic electricity demand, which could instead be used for hydrogen production. Integrating electrolysers into the power system could potentially help to reduce specific costs through load shifting. Overall, it seems advisable to analyse hydrogen exports together with local decarbonisation in order to better understand their interactions and to reduce emissions as efficiently as possible. These results and the methodology could be transferred to other countries that want to become green hydrogen exporters in the future and are therefore a useful addition for researchers and policy makers. • The required strong capacity expansion for PV and wind is challenging, but feasible. • "Energy efficiency first" benefits both the local energy transition and H2 exports. • Fully renewable power systems require a suitable political framework. • Higher hydrogen exports might help to reduce the specific power system cost. • Fossil capacity expansion must be stopped to avoid lock-ins and higher future costs. [ABSTRACT FROM AUTHOR]

Renewable energy production through electrolysis of water to obtain "green hydrogen" has gained interest as a clean energy storage option. However, integrating variable renewable energy resources into the grid poses challenges to maintaining energy balance and stability. In this paper, a hybrid energy storage system combining short-term battery energy storage system and long-term hydrogen-based energy storage system is proposed for an isolated DC microgrid with a structure similar to a hydrogen refueling station. Passivity-Based Control (IDA-PBC) is utilized for power converters regulation, ensuring global stability based on Lyapunov theory while accounting for the nonlinear characteristics of the physical system. The control strategy is designed to ensure a reliable supply of electrical energy to the loads, preserve the quality of electrical variables in the network, and secure the safe operation of system components. Additionally, to safeguard devices from overvoltage, a Sliding Mode Reference Conditioning loop (SMRC) is proposed. It intervenes only when there is a potential risk of exceeding predefined boundaries. Simulations results under demanding conditions demonstrate the effectiveness of incorporating hydrogen energy storage systems with IDA-PBC and SMRC for this class of problems. • An isolated MG with H2 storage, typical structure of a refueling station, was modeled. • The IDA-PBC ensures the stability of the nonlinear and complex MG. • SMRC ensures overvoltage protection in the bus. • The control confirms that H2 storage integrated with RES contributes to MG stability. [ABSTRACT FROM AUTHOR]

The extensive use of coal and oil for heating, electricity generation and cooling of buildings contributes to various environmental problems, both locally and globally. One of the feasible solutions to the climatic issues currently in this region is using sustainable energy sources. Hydrogen is an alternative option to fossil resources generated from sustainable energy sources. It is a form of energy that is both ecologically safe and sustainable. Hydrogen may now be produced in several different ways, including by reforming hydrocarbons, the Electrolysis of water, and Steam reforming of fossil fuels. However, because there is a finite supply of fossil fuels and a change in climate conditions due to the emission of CO 2 & other contaminants, there has been a focus on producing hydrogen using renewable resources. This study reviews an H 2 production system that combines geothermal & solar energy, the two primary renewable energy sources and a hybrid solar-geothermal system. This study looked into different aspects, like the working fluid for water electrolysis, the geothermal fluid temperature, and the type of power cycle. Comparative analysis was also performed on numerous GPPs, including flash, ORC cycles, binary, flash-binary, and solar collectors; this covers investigations on the rates and costs of producing hydrogen. • This paper looks at three different approaches of producing hydrogen using renewable energy sources. • An innovative renewable energy system that depends on solar and geothermal power. • An integrated system consists of geothermal and solar energy, an electrolyzer, and a fuel cell unit. • Hydrogen production as a function of design factors including working fluid, electrolysis temperature, and cycle type. • Producing hydrogen from geothermal and solar energy is a cost-effective and potentially profitable solution. [ABSTRACT FROM AUTHOR]

Transportation is an economic sector that contributes significantly to global warming due to its high consumption of fossil fuels, and sustainably produced hydrogen is a major contender for an alternative clean energy source. Public transit is vital for environmental sustainability via reducing individual vehicle usage and traffic congestion, and the prospect of powering buses using hydrogen fuel has been extensively studied lately. This paper seeks to comprehensively review the current status of research on hydrogen-powered buses considering triple bottom line sustainability perspectives. A brief technical overview of prospective environmentally benign hydrogen production processes has been presented. Technological, economic, and environmental findings and research trends seen in recent analyses on hydrogen-powered buses have been summarized, along with the status quo of global hydrogen refuelling stations. Identified focal points for future studies include performance enhancements, refuelling infrastructure propagation, and policy formulation. The conclusions derived from this review will benefit the accelerated deployment of hydrogen-fuelled public transit fleets. • Environmentally benign hydrogen production is reviewed techno-economically. • The prospects of using hydrogen for public bus transport are discussed thoroughly. • Blue and green hydrogen production are likely to coexist in the hydrogen economy. • Costs and energy consumption of hydrogen-powered buses need improvement. • Refuelling facility deployment and public awareness of safety should be enhanced. [ABSTRACT FROM AUTHOR]

The development of efficient, stable and low-cost catalysts for hydrogen evolution reaction (HER) is one of the major difficulties in water electrolysis. It is also the key to realizing the large-scale production of hydrogen energy, a renewable and clean energy source. In recent years, metal-organic frameworks (MOFs) have attracted much attention as novel precursors for preparing water electrolysis catalysts due to their high porosity and large specific surface area. In this paper, we use ZIF-67 as a precursor and modify it by doping transition metal elements Fe and Ni. Afterwards, Fe–Ni–CoSe 2 @NC is synthesized by a thermal selenization process. The results show that the HER overpotential of the catalyst after modification is reduced by 50%, and the efficiency of water electrolysis is significantly improved. Moreover, the catalyst has good stability under alkaline condition and is more economical than the expensive Pt-based catalysts, which provides more possibilities for industrial applications. [Display omitted] • The catalysts prepared by ZIF-67 as a precursor have large specific surface area. • Co-doping of Fe and Ni greatly improves the electrochemical activity of CoSe 2 @NC. • Fe–Ni–CoSe 2 @NC has relatively good stability and obvious economic advantage. [ABSTRACT FROM AUTHOR]

The development of large energy systems based on renewable energy sources is accompanied by an increase in the input capacities of large grid storages. Taking into account the vector for decarbonization and maneuverability, the use of hydrogen as a fuel in the cycle of a diabatic compressed air energy storage (CAES) is a promising scientific and technical direction. This paper analyzes the key performance indicators of a compressed air energy storage in the presence and absence of thermal energy recovery within the cycle. In addition, an assessment was made of the prospects for the use of a methane-hydrogen mixture in gas turbines. At the end of the paper, a calculation of the process of plasma pyrolysis of methane is given as one of the possible methods for the production of hydrogen for use in energy purposes. [ABSTRACT FROM AUTHOR]

Hydrogen production from renewable energy sources is one of the important means to solve the world energy crisis. In the past decades, many experts and scholars have made different reviews on electrolyser and hydrogen production power supply. However, few articles have reviewed the actual industrial products of electrolyser and hydrogen production power supply from the perspective of industry. Therefore, this paper reviews the hydrogen production power supply and electrolyser used in practical engineering projects. It is helpful for experts and scholars to understand the development status of hydrogen production power and electrolyser in the industry and to further develop industrial products more suitable for practical applications. • This paper reviews the products of electrolyzers and hydrogen power sources. • This paper expounds the development situation of hydrogen production key products. • This paper summarizes the future development direction of water electrolysis. • This paper helps scholars to propose methods with practical significance. • This paper has guiding value for industrial equipment selection. [ABSTRACT FROM AUTHOR]

The integration of water electrolysis with renewable energy sources (RESs) constitutes a milestone in the transition to neutral and sustainable energy systems. The attractive features of the Proton Exchange Membrane (PEM) electrolyzer such as high purity of hydrogen, operation with high pressure, and high current densities have made it a critical technology to produce green hydrogen from RESs. Accurate models are required for proper design, analysis, and control of the electrolyzer when connected to the grid or renewable energy systems. Amongst the various types of models proposed for modeling the PEM electrolyzer, electrical circuit models are the easiest, most appealing, and straightforward to use for the investigation of electrolyzer operation and control. This paper presents an exhaustive review of the electrical circuit modeling reported in the literature on PEM electrolyzers. The reviewed models are classified analogously to the classifications of physical modeling in terms of voltage components (reversible, ohmic, activation, and concentration voltage drop), model behavior (static/dynamic), and modeling scale (cell/stack). Furthermore, MATLAB simulations of the reviewed models are implemented and the results are compared to pinpoint their similarities and deviations. Moreover, the applications, challenges, benefits, and drawbacks of the electrolyzer's electrical equivalent circuit modeling are discussed and overarching recommendations are set out for further research on the PEM electrolyzer modeling. The paper can be used as a comprehensive reference for choosing the appropriate electrical model of the electrolyzer for beginners as well as for research and industry experts who rely on PEM electrolyzer models in their work. • A comprehensive review of the electrical circuit models of the PEM electrolyzer is presented. • The models are classified in terms of voltage components, model behavior, and scale. • Simulations of the models are implemented to show their similarities and deviations. • Applications, benefits, and drawbacks of electrical circuit modeling are discussed. • Overarching technical recommendations are drawn for further research on electrical circuit modeling. [ABSTRACT FROM AUTHOR]

Hydrogen energy storage systems (HESS) play an essential role in Microgrid (MG) systems to address the inherent generation characteristics of renewable energy sources. Also, the integration of Demand Response (DR) into the Energy Management System (EMS) of a renewable-based Multi-Microgrid (MMG) can lead to substantial technical and economic benefits. This paper proposes a modified optimization algorithm for optimizing MMG Energy Management (EM). The proposed algorithm is a modified version of the Student Psychology-Based Optimization (SPBO) technique called Modified Student Psychology-Based Optimization (MSPBO). This modification aims to improve issues such as slow convergence, low solution accuracy, lack of diversity, and getting stuck in local optima. The proposed MSPBO method incorporates a local escape operator and a collaborative student class to achieve a better balance between exploiting known solutions and exploring new possibilities. The MSPBO algorithm is applied to address the EM challenge within a MMG context. Considering the integration of renewable sources as Wind turbines and solar photovoltaic and the HESS, the EM problem is formulated as a two-stage multi-objective optimization: minimizing the operating cost of conventional generators and power transactions cost in addition to the cost of HESS, while maximizing operator benefits and peak load reduction. This multi-objective problem is tackled using a hybrid ε-lexicography–weighted-sum approach that avoids the need for normalization. The performance of the proposed MSPBO is evaluated using CEC 2017 benchmark test functions, utilizing various statistical measures such as best, average, worst, rank, and standard deviation (SD) of fitness values, along with Wilcoxon's rank-sum test. The MSPBO technique is compared with other optimization algorithms for these test functions, highlighting its efficiency and adeptness in achieving a harmonious trade-off between exploiting known solutions and exploring new ones. Furthermore, the MSPBO method is applied to solve two case studies. In Case 1, which involves a single stage with conventional demand response optimization, the results achieved using MSPBO are benchmarked against other optimization techniques, revealing its superior efficacy in addressing the EM challenge. In Case 2, a more complex two-stage multi-objective problem is tackled using MSPBO, and the assessment of the integration of HESS in the MMG is evaluated. In the second stage, there is a notable enhancement in peak load reduction percentage (PRP), from 13.9% to 16.13% without the HESS and from 12.68% to 16.46% with the integration of HESS. [ABSTRACT FROM AUTHOR]

Distribution feeder reconfiguration (DFR) in distribution systems can enhance operating conditions by reducing losses and improving voltage indices. This paper introduces a dual-stage risk-based framework that concurrently tackles day-ahead reconfiguration and microgrid scheduling within the distribution network. To control the negative aspects of uncertainties, the proposed framework integrates energy storage systems (ESS/HSS) and demand response programs (DRPs) at the network level, enhancing adaptability. The initial stage of the proposed model employs the AC power flow model, utilizing loss and voltage deviation functions as objective benchmarks for network reconfiguration. The scheduling is meticulously executed per interval, deriving optimized structures under diverse scenarios with the aid of a case reduction technique (CRT) to streamline solutions. The ultimate solution employs the grey wolf optimization (GWO) algorithm and CPLEX solver in the first and second stages respectively. Outcomes from applying this approach to the adjusted 118-bus network manifest improved operational conditions and voltage quality through reconfiguration. Impressively, the integration of ESS/HSS and DRPs yields a substantial 22.34% reduction in total operating costs, a conclusion substantiated by the numerical findings. Furthermore, by leveraging the CRT, a remarkable 56.17% reduction in problem-solution time is achieved. [Display omitted] • Investigating the impact of losses and voltage deviations on network performance. • Introducing a two-stage risk-based framework to determine the optimal topology. • Finding solutions to the micro-grids planning problem with the distribution network reconfiguration. • Adopting a case reduction method to lessen time demand required for solving the day-ahead planning problem. • Investigating the effect of demand response programs on the voltage characteristics and losses of the system. [ABSTRACT FROM AUTHOR]

Hydrogen as a sustainable and clean energy source has been widely noticed, but it is urgent to find an efficient and stable electrocatalyst to increase its hydrogen production. For the catalytic performance of electrocatalysts, defects, doping, and stress are usually selected to enhance the catalytic performance, on the basis of which in this paper, MSi 2 N 4 (M = Mo, W) system containing vacancies and bimetallic doping was constructed and analyzed for its HER performance. The results show that the formation energy of all structures is stable and Ni doping can significantly improve the stability according to formation energy of the structures with vacancy. Both ipsilateral doping and contralateral doping can significantly improve the Gibbs free energy of MA 2 Z 4 materials, especially the MoSi 2 N 4 doped with double Co. In particular, the values of Gibbs free energy of C-Ni-V N @MoSi 2 N 4 -N in and C-Co-V N @WSi 2 N 4 -N in are −0.027 eV and 0.041 eV, significantly better than the performance of the recognized electrocatalyst Pt, which has a free energy of only 0.09 eV. After doped with transition metallic atoms, the energy bands of all materials present semiconductor property. Our work provides a novel method for the regulation of MA 2 Z 4 family materials and a theoretical strategy for designing efficient HER electrocatalysts. • Screening of bimetal-doped MA 2 Z 4 with defective structures for HER catalytic activity. • The HER performance of the ipsilateral doping is better than that of the contralateral doping. • The vacancies can significantly improve the formation energy of Ni doped materials. • The MoSi 2 N 4 defect structure doped with double Co has a near-zero ΔG H. [ABSTRACT FROM AUTHOR]

Increasing greenhouse gas emissions and the increase in renewable energy sources in electricity generation have led to an increasing interest in hydrogen in recent years. As an energy storage solution for renewable energy, hydrogen can contribute to decarbonizing industries and transportation sectors as well as balancing energy systems. In this paper, the primary objective is to examine different methods for producing hydrogen depending on the primary energy source. In addition, it evaluates the economic and environmental performance of three types of hydrogen, known as hydrogen colors, and the significant obstacles to widespread fuel cell adoption. The key finding is that hydrogen's environmental benefits depend heavily on how hydrogen is produced and what fuel is used to produce it. Green hydrogen can only be produced using wind, solar photovoltaic (PV), and hydroelectric power. The emissions from other sources, such as blue hydrogen that uses carbon capture, utilization, and storage (CCUS) or electrolysis using electricity from the grid, are significantly higher than those from grey hydrogen. Furthermore, establishing an international hydrogen market will reduce costs and allow hydrogen to be produced in optimal locations. Lastly, a key unresolved question is whether hydrogen, whatever its color, is economically competitive in any sector of the energy system, despite all external costs associated with it. A policy framework that supports technological advancements, cost reductions, and future priorities will determine hydrogen's success in the future. The transition from grey hydrogen to green hydrogen should be facilitated by this framework. [ABSTRACT FROM AUTHOR]

Nowadays, renewable energy sources are integral to programs for the development of electric power systems. It is established that modern renewable generation units and energy storage systems utilize power electronic-based interfaces, such as voltage source converters, to convert power. On the one hand, the utilization of a voltage source converter provides certain advantages, such as the absence of a direct link to the network, the ability to operate on all quadrants of the PQ diagram, and the possibility of connecting renewable generation units to a weak network. On the other hand, the widespread use of renewable generation units utilizing voltage source converters reduces the overall inertia of the electric power system. However, excessive use of power electronic converters in the network leads to a significant increase in harmonic pollution, thereby introducing fresh challenges to ensuring safe and stable operation of the electric power system. To ensure the dependable operation of an electric power system with renewable energy sources units and energy storage systems based on the voltage source converter, it is essential to update the control system of the voltage source converter to meet the requirements for traditional generation as part of the electric power system. This paper presents the outcome of the power oscillation damping controller application implemented in the voltage source converter, which enhances the electric power system's stability. [ABSTRACT FROM AUTHOR]

The ongoing transition from fossil fuel-based electricity generation toward green energy relying on the intermittent renewable energy sources indispensably requires development of novel energy conversion and storage methods. Depending on a particular location and local resources, pumped storage, lithium- or sodium-ion batteries, compressed air energy storage, as well as the so called power-to-gas (P2G) technologies may be applied. Taking into account the abundant solar energy resources available in the northwestern China, such as Ningxia hui autonomous region, and local water resources coming from the Yellow River, a power-to-hydrogen (P2H2) distributed energy conversion system is proposed in this paper, which is based on a high-efficiency reversible Solid Oxide Cell (rSOC). The conducted studies comprise tests with simulated current based on the actual photovoltaic power station data, and with usage of the as-obtained Yellow River water for the electrolysis mode without any pretreatment. It is documented that the reversible operation is beneficial, and the tested cell can operate for a prolonged time. Of importance, Na, Ca, Mg, and Si elements remain in an evaporator, and do not contaminate the cell, while higher than the initial boron concentration can be found in the condensed exhaust gases. The respective operational parameters of the system correspond to an electrolysis current density loading up 433.3 mA cm−2 for 4 h, as well as fuel cell operation mode with a current density of 8.3 mA cm−2 for 12 h. It is found that the average voltage losses in the electrolysis cell and fuel cell mode are 0.27 %/cycle and 0.886 %/cycle, respectively, indicating that the lifetime of the cells can be more than 800 h. The reported studies demonstrate validity of applying rSOC-based P2H2 system, especially if abundant photovoltaic power and water resources are available. [Display omitted] • The Yellow River water was utilized by rSOC for the first time. • The designed test current was modeled with local photovoltaics. • The P2H2 nearby consumption system can reversibly operate for over 800 h. • The degradation rates in SOFC mode are lower than those in SOEC mode. • The Yellow River water has no significant effect on the degradation rate. [ABSTRACT FROM AUTHOR]

The global energy issue is undergoing transformation owing to various factors, such as climate change and geopolitics. In the long term, the primary pathways to achieve sustainable energy development remain the clean energy and global cooperation. As the largest energy consumption centers, the Asia Pacific and North America possess complementary energy profiles and developmental needs for cooperation. This paper analyses various electricity or hydrogen transmission technologies suitable for the Pacific Rim energy system. The liquid hydrogen superconducting energy pipelines possess the potential to fulfill the demands of long-distance and large-scale energy transmission. Building upon this technology, a super energy pipeline project connecting East Asia and North America across 12 time zones was proposed. It is composed of pipelines and relay energy stations, which can realize large-scale storage and transportation of renewable energy as well as the diversified energy supply at terminals. The techno-economic evaluation of the project has been comprehensively conducted, and the investment can be recovered within 10 years. The project is expected to boost the progress of renewable energy, ensure regional energy security and promote the sustainable development of global energy. [Display omitted] • Proposes cross-continental energy transmission scheme for Pacific Rim. • Highlights the potential of liquid hydrogen superconducting energy pipelines. • Identifies the future requirements for the energy storage and transmission. • Presents a review of the existing global energy mix. [ABSTRACT FROM AUTHOR]

Hydrogen is currently recognized as being able to mitigate the overuse of fossil fuels and as a clean energy source in future development. In addition, water electrolysis can work with renewable energy sources to make the hydrogen cycle sustainable. However, hydrogen production efficiency from water electrolysis relies on efficient catalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). At present, in order to further develop overall water splitting (OWS) catalysts, non-metal doping has attracted increasing attention. Non-metals can modulate the electronic structure, lattice structure, and surface properties of transition metal-based catalysts, which can be a new strategy to regulate the catalytic activity. Herein, the recent research progresses of non-metallic doping in transition metal-based catalysts are reviewed in this paper. This article summarizes the inherent correlation between the electronic structure and local environmental changes of water electrolysis catalytic materials with different non-metallic elements in the transition metal-based materials. Then, the reasons and related mechanisms for the improved performance of catalysts by nonmetal doping are discussed. The aim of this review is to offer some insights in favour of the role that non-metallic doping owns special advantages in electrocatalytic water splitting. • Non-metals doping is a new strategy to regulate the catalytic activity. • Non-metals can modulate the structure and surface properties of transition metal-based catalysts. • Non-metals doping can regulate inherent correlation between the electronic structure and local environmental. • The effects of non-metal doping on HER, OER and water splitting are discussed. [ABSTRACT FROM AUTHOR]

This paper examines the complex relationship between the role of H 2 , carbon emissions and their impact on global warming and the economy. Despite improvements in energy efficiency, fossil fuel consumption continues to increase. CO 2 from industrial activities at high temperatures, such as cement, iron, steel and glass production, have increased rapidly, resulting in an increase in the concentration of greenhouse gases in the atmosphere. These emissions accelerate climate change, leading to dangerous consequences such as increasing average atmospheric temperature and decreasing agricultural productivity. To combat this, it is advocated to reduce CO 2 emissions by using renewable energy sources such as hydroelectricity, biomass, wind solar energy. Current study also discusses carbon reduction methods, including oxy-fuel combustion capture, pre-combustion capture, and post-combustion capture. Despite their unique advantages and disadvantages, these methods play an important role in reducing CO 2 emissions from power plants. Additionally, the article highlights the importance of H 2 as a cornerstone in the development of synthetic fuels and future energy systems. H 2 from renewable sources holds the potential to use carbon-neutral synthetic liquid fuels and revolutionize transportation. Although traditional H 2 production methods are associated with emissions, sustainable H 2 production techniques can facilitate low-carbon fuel production. The article concludes by highlighting the importance of sustainable energy practices and the role of H 2 in reducing carbon emissions, highlighting research efforts to improve production methods, integrate renewable energy, and develop carbon capture technologies for a sustainable future. • Methods used in synthetic fuel production and sources of hydrogen production. • Carbon capture methods and their comparative discussion. • The importance of hydrogen production in synthetic fuel production and future plan. [ABSTRACT FROM AUTHOR]

Hydrogen is expected to be a game changer in the fight against climate change, being able to support the clean energy transition through a variety of roles: decarbonizing different hard-to-abate industrial sectors (such as steel, cement production) and transport (in long haul vehicles, maritime transport, and aviation), direct use as a fuel, chemical feedstock or in the form of synthetic fuels, and providing the ability to integrate with hybrid energy systems and renewables, enhancing energy storage and tapping the full potential of renewable energy sources. As a consequence, a substantial expansion in hydrogen production, due to rise in the demand, is expected by 2050, with all the generation coming from zero-carbon processes (electrolysis/thermochemical cycles using clean electricity and heat) or from a low-carbon production process using steam methane reforming with carbon capture and storage. Nuclear energy can be capitalized on both electricity and heat to provide a clean and reliable source of hydrogen through various processes. There are currently various demonstration projects undergoing in several countries to showcase the use of nuclear energy to produce clean hydrogen, considering both the current reactor fleet and advanced reactors. This paper provides an overview of these projects, giving an insight on the potential use of nuclear energy for hydrogen production and the current status of existing projects. It also highlights the activities of the International Atomic Energy Agency on technical and economic assessment of hydrogen production using nuclear energy for near term deployment. • Hydrogen is anticipated to be a game-changer in the fight against climate change. • Nuclear energy is positioned favourably to serve the developing hydrogen economy. • A single 1000 MW nuclear reactor could produce more than 200,000 t of H2 per year. • Several countries are considering nuclear hydrogen demonstration projects. • The IAEA has multiple resources available for nuclear hydrogen production. [ABSTRACT FROM AUTHOR]

Alkaline water electrolysis has become the most promising solution for hydrogen production considering certain factors such as cost, lifetime and maturity of technology. By developing the large-scale hydrogen production by alkaline water electrolysis as the energy buffering, the consuming pressure of the power system caused by the growing penetration of renewable energy sources such as wind and solar energy can be relieved effectively. However, when the alkaline water electrolysis is integrated with renewable energy sources, the unclear underlying mechanism and interaction characteristics limit large-scale application for hydrogen production. Aiming at this problem, from the aspects of efficiency and consistency, power regulation flexibility and gas purity, this paper studies safety and efficiency problems about the wide-range operation of alkaline water electrolyzers driven by renewable energy sources. The corresponding mechanism analyses are carried out and possible solutions for the future research are given, which are expected to provide a comprehensive review and useful guide for this research topic. • The mechanism of the inefficiency of alkaline water electrolyzers in low load is revealed. • Power regulation flexibility of alkaline water electrolyzers is improved by the advanced energy management. • Possible solutions to solve the poor gas purity of alkaline water electrolyzers are provided. [ABSTRACT FROM AUTHOR]

This paper aims at the development and validation of a computational fluid dynamic (CFD) model for simulations of the refuelling process through the entire equipment of the hydrogen refuelling station (HRS). The absence of such models hinders the design of inherently safer refuelling protocols for an arbitrary combination of HRS equipment, hydrogen storage parameters, and environmental conditions. The CFD model is validated against the complete process of refuelling lasting 195s in Test No.1 performed by the National Renewable Energy Laboratory (NREL). The test equipment includes high-pressure tanks of HRS, pressure control valve (PCV), valves, pipes, breakaway, hose, and nozzle all the way up to three onboard tanks. The model accurately reproduced hydrogen temperature and pressure through the entire line of HRS equipment. A standout feature of the CFD model, distinguishing it from simplified models, is the capability to predict temperature non-uniformity in onboard tanks, a crucial factor with significant safety implications. • CFD model of refuelling through the entire HRS equipment reproduced NREL Test No.1. • Complete hydrogen refuelling process of 195 s simulated in 2 days on 32-core CPU. • The model can be used to design fuelling protocols for HRS with any equipment. [ABSTRACT FROM AUTHOR]

This paper focuses on the design and use of a control system for a renewable energy production plant based on hydrogen. The proposed control system aims at ensuring the stability and smooth functionality of the plant, which consists of a (i) photovoltaic system connected to an electrolyzer through a battery, (ii) a DC/DC step down transformer, and (iii) an electrolyzer heat exchange system. In this study, solar irradiance is the main system input, and hydrogen production the main output. Since the system utilizes solar energy as input, it depends on the random input of solar irradiance, ambient temperature, and wind flow. Furthermore, the electrolyzer's functionality is subject to several operational variables including cell voltage, current, temperature, and pressure. The electrolyzer heat exchange system operates at specified water temperatures and flow rates. The DC/DC output voltage, and therefore the voltage supplied to the electrolyzer, is regulated by changing its duty cycle. To regulate hydrogen production in the renewable energy production plant, an efficient control system is required. Accordingly, in this work, a control system is designed accounting for three different electrolyzer technologies, alkaline, PEM (proton exchange membrane), and E-TAC (electrochemical - thermally activated chemical water splitting). Subsequently, the effectiveness of the control system is analyzed using Matlab and Simulink models. The main results indicate that the battery is a crucial element in the whole system as it supplies the necessary energy to the electrolyzer. By regulating the appropriate components, the proposed control system proved capable of minimizing power fluctuations and increasing system efficiency up to 20% depending on ambient conditions. Additionally, the results indicate E-TAC and PEM efficiencies 13% and 7% higher than alkaline, respectively. [Display omitted] • Design of a control system for three different electrolyzer technologies. • Use of control systems for electrolyzer voltage and heat exchange. • Photovoltaic system connected to an electrolytic one through a battery. • Proposed control system increases system efficiency up to 20%. [ABSTRACT FROM AUTHOR]

Designing self-sufficient renewable energy systems is becoming a key issue in the energy sector due to modern energy goals. Due to the variability of renewable energy sources, very often it is necessary to adopt hybrid configurations of renewable energy systems and advanced energy storage to achieve self-sufficiency. However, the adoption of complex and novel systems, including technologies as photovoltaic, wind turbines, biomass gasifiers, hydrogen energy storage, must to be founded on a comprehensive analysis of the system operation under different conditions and its energy and economic performance in the investigated case study. Therefore, the aim of the present paper is carry out a comprehensive feasibility analysis of a novel hybrid renewable energy system achieving a high self-sufficiency level. The system integrates a wind turbine and photovoltaic panels to match the energy load of a tourist resort in Agkistro, Greece. Energy exceeding the load is directed to the energy storage system based on the battery and hydrogen tank. As backup energy source, a wood gasifier is used. The investigation is performed by means of a numerical model developed in TRNSYS software allowing one to simulate dynamically the system and to assess its energy and economic performance. The goal achieved during the simulation of the system was to ensure at least 97% of energy demand from renewable sources. Moreover, a parametric analysis of the storage system is presented. It is found that payback period of the installation varies in the range between 11 and 15 years, for systems configurations allowing to satisfy 90–98% of the users energy yearly demand from renewables. The achieved results allows one to evaluate the feasibility of the proposed system from both an energy and economic point of view. • Island energy systems in Greece. • Hybrid energy system with both battery and hydrogen energy storage. • 97% reduction of energy produced from fossil fuels with 30% of energy curtailed. • Parametric study concerning sizes of the energy storage. [ABSTRACT FROM AUTHOR]

This paper explores the use of Solar Chimney Power Plants (SCPPs) for the production of green hydrogen as a means to store excess electrical energy generated from renewable energy resources (RESs). The proposed structure produces electrical energy and distilled water by heating the air under the SCPP. The electrolyzer is integrated into the seawater pool and installed at the solar chimney's base. The weather conditions at the proposed location of the SCPP including solar radiation, temperature, humidity, and wind speed, are analyzed to assess their impact on the performance of the SCPP. The potential applications and economic feasibility of the SCPP are discussed, considering its contribution to renewable energy generation and the benefits of hydrogen as a clean energy carrier. The results show that solar radiation levels and favorable temperature profiles play an important role in the performance of the SCPP. The SCPP could produce 380,263 kW h of electrical energy and 139,443 tons of distilled water annually. The results also showed that the SCPP could produce 13,000 kg of green hydrogen and 173,224 kg of oxygen annually. The revenue generated from the production of H 2 and O 2 has improved the levelized cost of energy (LCOE) for the SCPP to 0.51 $/kWh and made it compete with other energy production facilities. Monthly variations in electrical energy, H 2 , O 2 , and distilled water production, highlight the dependence of hydrogen production on solar intensity and temperature. Overall, the research demonstrates the potential of SCPPs and hydrogen production as a sustainable and efficient solution for storing and utilizing excess renewable energy. [Display omitted] • Solar-electrolysis system combing solar chimney & electrolysis station is proposed. • The system produces green hydrogen, oxygen, desalinated water, and electricity. • The solar-electrolysis system was modeled using MATLAB mathematical modeling. • The system produced 380 MW h, 13 ton H 2 , 173.3 ton O 2 , and 139,443 ton water per year. [ABSTRACT FROM AUTHOR]

Variable Renewable Energy Sources are crucial for decarbonizing industries and efficient energy storage. Hydrogen storage technologies are limited in their large-scale capabilities. PtL technology can synthesize alternative fuels like methanol, which can be used in existing energy infrastructures to produce liquid fuel. The paper presents an innovative approach for utilizing in-situ thermal energy, using a hot reservoir rock (HRR) system for methanol synthesis at high temperature and pressure in an underground large-scale natural reservoir reactor. This approach aims to integrate renewable energy technologies into a single energy generation and fuel production system, including the direct utilization of renewable sources. Solutions from the oil and gas industry can be adapted to this action, such as continuous injection, alternate injection, separate injection, or chemical flooding. Conventional geothermal reservoirs, HDR systems, and depleted hydrocarbon reservoirs can be used as "underground reactors". However, it was also noted that there are challenges, such as catalyst distribution and the complexity of reservoir pore space. • Reservoir rock as a geochemical reactor for underground in-situ e-methanol synthesis. • Synergy between energy storage, CCUS, e-methanol production, and geothermal energy. • Effective use of surplus renewable energy with hydrogen technologies. • Risk reduction related to chemical processing and high environmental neutrality. • Use of resources related to the oil and gas industry for the energy transition. [ABSTRACT FROM AUTHOR]

In a 100% renewable energy scenario, power generation fluctuates, requiring management and control of this generation. Storage is presented as a solution to regulate production discontinuity. In particular, seasonal storage can compensate for long-term fluctuations and serve as a necessary complement to short-term storage management. Due to the potential role of hydrogen in the decarbonization of energy production systems, this research attempts to analyse the levelized cost of storage (LCOS) of this energy carrier as a solution to long-term electricity requirements. The research focuses on the analysis of the total Power-to-Power (P2P) process cost, all factors affecting the input of electricity up to the output of electricity after the conversion of the hydrogen are considered. A transformation of the surplus electricity to hydrogen through a PEM electrolyzer is proposed in this paper. This hydrogen would be stored seasonally in salt caverns. Finally, a gas-to-energy transformation using gas turbines or fuel cells is contemplated. The analysis presents highly competitive results in terms of cost, demonstrating the system's competitiveness and potential: the turbine powered by 100% hydrogen solution appears to be more cost effective than the fuel cell solution: 0.207€/kWh and 0.284€/kWh respectively. Hydrogen storage presents itself as the most cost-effective long-term alternative in the near future, even better than pumped hydro, compressed air or batteries. • LCOS: Levelized Costs of Storage for a large-scale and long-term system. • The use of hydrogen as an energy carrier to store electrical energy from renewable sources at large scale. • Long-term storage of hydrogen in salt caverns. • Transformation of stored hydrogen into electricity through turbine and fuel cells. [ABSTRACT FROM AUTHOR]

The transition to a low-carbon energy system can be depicted as a "great reconfiguration" from a socio-technical perspective that carries the risk of impact shifts. Electrification with the objective of achieving rapidly deep decarbonisation must be accompanied by effective efficiency and flexibility measures. Hydrogen can be a preferred option in the decarbonisation process where electrification of end-uses is difficult or impractical as well as for long-term storage in energy infrastructure characterised by a large penetration of renewable energy sources. Notwithstanding the current uncertainties regarding costs, environmental impact and the inherent difficulties of increasing rapidly supply capacity, hydrogen can represent a solution to be used in multi-energy systems with combined heat and power (CHP), in particular in urban energy districts. In fact, while achieving carbon savings with natural gas fuelled CHP is not possible when low grid carbon intensity factors are present, it may still be possible to use it to provide flexibility services and to reduce emissions further with switch from natural gas to hydrogen. In this paper, a commercially established urban district energy scheme located in Southampton (United Kingdom) is analysed with the goal of exploring potential variations in its energy demand. The study proposes the use of scalable data-driven methods and probabilistic simulation to generate seasonal energy demand patterns representing the potential short-term and long-term evolution of the energy district. • Hydrogen role in the transition to low carbon energy systems for urban energy district. • Data-driven urban energy modelling using regression-based approaches. • Probabilistic modelling of energy demand in terms of electricity and fuels. • Climate change impact and energy efficiency measures accounting. • Seasonal variations of energy demand patterns from short-term to long-term scenarios. [ABSTRACT FROM AUTHOR]

The paper emphasizes the significance of sustainable energy solutions centered around electric vehicles (EVs). This involves Electric Intelligent Parking Lots (IPLs) that are interconnected with Renewable Energy Sources (RES) and Hydrogen Storage Systems (HSS) to achieve both technical and environmental goals. The study introduces a probabilistic approach to managing HSS-based energy in IPLs, employing the Probabilistic Two-Point Estimate Method (TPEM) to consider variables like sun radiation, temperature, wind speed, and IPL load. The Honey Badger Algorithm (HBA) is employed for optimization, striving to minimize operational costs related to energy distribution while maximizing profits by exploring revenue opportunities within the IPL system. This strategy enhances energy management and intelligent EV charging in IPLs, improving efficiency and economic viability. The approach is tested in a standard IPL environment integrated with RES and load demand, showcasing its successful technical and financial outcomes. Results reveal a 7.8 % profit increase from renewable resources and an additional 4.89 % when uncertainties are factored in. Ultimately, the proposed energy management framework utilizing HSS and RES integration proves effective in achieving objectives, with the potential for greater profitability through renewable resource incorporation and uncertainty consideration. • Optimal energy management framework proposed for electric vehicle integration in intelligent parking lots. • Simulation of efficient charging and discharging strategy in an IPL for electric vehicles. • Impact of renewable sources integration (wind and solar) on IPL efficiency and revenue generation. • Uncertainty analysis of renewable sources and load demands in IPL using two-point estimation method. • Smart integration of renewable sources, hydrogen storage, and electric vehicle charging for optimal operation of IPL. [ABSTRACT FROM AUTHOR]