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Green hydrogen can be the transitional solution required to reduce anthropogenic emissions and enhance energy independency from fossil fuel. To improve green hydrogen adoption, a cluster-based infrastructure, called a hydrogen hub, is devised taking into account the demand-supply interplay coupled with transport ease. In this paper, we have identified sites across states that are conducive for hydrogen hubs. It involves a multicriteria decision-making (MCDM) framework deployed to assign priorities within competing set of criteria. A comprehensive analytical hierarchy process (AHP) is used to rank criteria that are connected to establish a functioning hydrogen hub. These criteria include, but not limited to, proximity to refineries, fertilizer plants, substations, chlor-alkali units, steel manufacturing plants, water availability, access to gas pipelines, railway line access, and finally distance to highways. Our analyses indicate that proximity to refineries and fertilizers scored higher (scores directly proportional to importance) while railway line access scored the least. These prioritised scores are used to spatially locate sites using geographical information system. In a total of thirteen states identified, Gujarat had the largest parcel of most suitable land for setting up hydrogen hub followed by Maharashtra and Andhra Pradesh. For India to set up a functioning hydrogen economy and achieve green hydrogen goals, it is important to identify states that can drive the agenda forward. This paper illustrates a way (amongst many available ways) to identify states based on their strength and capability to fulfil the national goal of 5 million tons of green hydrogen by 2030. • The paper addresses setting up of green hydrogen hubs in India based on a multi-criteria site selection framework. • Nine selection criteria covering aspects of hydrogen ecosystem proposed to identify site(s) suitable for hydrogen hubs. • Integration of AHP and GIS is used to ascertain land parcels where hydrogen economy can sustain across states in India. • Zones in 13 states were identified as potential hydrogen hubs. [ABSTRACT FROM AUTHOR]

Abstract: This paper deals with how the Hydrogen Energy may play a crucial role in taking care of the environmental scenario/climate change. The R&D efforts, at the Hydrogen Energy Center, Banaras Hindu University have been described and discussed to elucidate that hydrogen is the best option for taking care of the environmental/climate changes. All three important ingredients for hydrogen economy, i.e., production, storage and application of hydrogen have been dealt with. As regards hydrogen production, solar routes consisting of photoelectrochemical electrolysis of water have been described and discussed. Nanostructured TiO2 films used as photoanodes have been synthesized through hydrolysis of Ti[OCH(CH3)2]4. Modular designs of TiO2 photoelectrode-based PEC cells have been fabricated to get high hydrogen production rate (∼10.35lh−1 m−2). However, hydrogen storage is a key issue in the success and realization of hydrogen technology and economy. Metal hydrides are the promising candidates due to their safety advantage with high volume efficient storage capacity for on-board applications. As regards storage, we have discussed the storage of hydrogen in intermetallics as well as lightweight complex hydride systems. For intermetallic systems, we have dealt with material tailoring of LaNi5 through Fe substitution. The La(Nil − x Fe x )5 (x =0.16) has been found to yield a high storage capacity of ∼2.40wt%. We have also discussed how CNT admixing helps to improve the hydrogen desorption rate of NaAlH4. CNT (8mol%) admixed NaAlH4 is found to be optimum for faster desorption (∼3.3wt% H2 within 2h). From an applications point of view, we have focused on the use of hydrogen (stored in intermetallic La–Ni–Fe system) as fuel for Internal Combustion (IC) engine-based vehicular transport, particularly two and three-wheelers. It is shown that hydrogen used as a fuel is the most effective alternative fuel for circumventing climate change. [Copyright &y& Elsevier]