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This paper precisely estimates the looming demand for hydrogen within the transportation sector, spanning 14 pivotal G20 nations from 2022 to 2050, anchored in the global vehicle hydrogen market penetration rate. Employing a robust techno-economic modeling methodology and leveraging Geographic Information System (GIS) for enriched visualization, it unveils distinct environmental dividends across three thoughtfully devised scenarios: Business- as -Usual, Moderate, and Aggressive. Findings herald India and China as pinnacles of hydrogen demand, with South Korea and Japan tailing closely. The study forecasts the energy consumption for solar hydrogen production in G20 countries to oscillate between 3.02 and 2.89 million GWh in 2022, while production costs are anticipated to range from $8.47/kg to $10.01/kg. In an assertive scenario, the paper illuminates a pathway towards achieving a significant CO 2 reduction, unmasking environmental savings of up to a staggering 48%, equivalent to 1.5 million mtCO 2 , by 2050. [Display omitted] • Hydrogen demand of G20 countries is analyzed using GIS and techno-economic models. • The projected adoption rates of hydrogen vary among the G20 countries. • Solar energy is crucial in determining each region's annual energy demand. • China, US, and India have the highest solar potential throughout the year. • The environmental analysis shows 850–1.5 million mtCO2 total emissions by 2050. [ABSTRACT FROM AUTHOR]

Increasing penetration of renewable electricity in the power systems coupled with reduction in its cost has resulted in increased interest in green hydrogen globally. Industry has been using fossil fuel-based hydrogen as an input for several decades. This paper makes an assessment of existing hydrogen production capacities in petroleum refineries and ammonia synthesis units in India along with estimating the potential for installing solar photovoltaic (SPV) powered alkaline electrolysers for producing green hydrogen and SPV capacity required for this purpose. Levelised cost of hydrogen production in these industries in India has been analysed and found to be competitive. The paper also discusses about water requirement, land requirement for SPV power plants, CO 2 emissions avoided and likely investment to be made for establishing infrastructure for green hydrogen production. With launching of national hydrogen mission in India, a transition to green hydrogen by the industry appears to be a near term possibility. • Hydrogen production capacities assessed for petroleum refineries and ammonia synthesis units in India. • Capacities of electrolysers and solar photovoltaic system to be installed for replacing existing hydrogen systems estimated. • Values for levelised cost of hydrogen estimated for such a combination of technologies. • Estimation made for water and land requirement for green hydrogen production, CO 2 emission avoided and investment needed. [ABSTRACT FROM AUTHOR]

Abstract: This paper deals with how the Hydrogen Energy may play a crucial role in taking care of the environmental scenario/climate change. The R&D efforts, at the Hydrogen Energy Center, Banaras Hindu University have been described and discussed to elucidate that hydrogen is the best option for taking care of the environmental/climate changes. All three important ingredients for hydrogen economy, i.e., production, storage and application of hydrogen have been dealt with. As regards hydrogen production, solar routes consisting of photoelectrochemical electrolysis of water have been described and discussed. Nanostructured TiO2 films used as photoanodes have been synthesized through hydrolysis of Ti[OCH(CH3)2]4. Modular designs of TiO2 photoelectrode-based PEC cells have been fabricated to get high hydrogen production rate (∼10.35lh−1 m−2). However, hydrogen storage is a key issue in the success and realization of hydrogen technology and economy. Metal hydrides are the promising candidates due to their safety advantage with high volume efficient storage capacity for on-board applications. As regards storage, we have discussed the storage of hydrogen in intermetallics as well as lightweight complex hydride systems. For intermetallic systems, we have dealt with material tailoring of LaNi5 through Fe substitution. The La(Nil − x Fe x )5 (x =0.16) has been found to yield a high storage capacity of ∼2.40wt%. We have also discussed how CNT admixing helps to improve the hydrogen desorption rate of NaAlH4. CNT (8mol%) admixed NaAlH4 is found to be optimum for faster desorption (∼3.3wt% H2 within 2h). From an applications point of view, we have focused on the use of hydrogen (stored in intermetallic La–Ni–Fe system) as fuel for Internal Combustion (IC) engine-based vehicular transport, particularly two and three-wheelers. It is shown that hydrogen used as a fuel is the most effective alternative fuel for circumventing climate change. [Copyright &y& Elsevier]