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In the contemporary global discourse on environmental and developmental issues, the dual challenges of sustainable green energy and water supply stand paramount. These elements are vitally intertwined with the socio-economic vitality of the world. Notably, regions plagued by freshwater scarcity are increasingly turning to desalination which consists of a reliable and unconventional water source. The intersection of renewable energy with desalination and water purification processes presents a compelling synergy. This approach is particularly pertinent in areas where freshwater shortages coexist with abundant solar energy availability. Additionally, these technologies boast the advantage of low operational and maintenance costs. This paper delves into the design, optimization and financial analysis of a novel, standalone hybrid energy system, integrating photovoltaic and fuel cell technologies, for an agriculture farm situated in Kairouan, Tunisia. Unlike conventional systems, this model foregoes battery storage in favour of hydrogen storage, generated through water electrolysis powered by solar energy. This system harnesses solar energy for direct electrical power generation and hydrogen gas production. A segment of the generated electricity is allocated to electrolysis for green hydrogen production. In times of solar unavailability, the stored hydrogen is reconverted to electricity via a fuel cell. An intriguing aspect of this system is the utilization of saline well water, which, due to its high salt content, necessitates purification through desalination to prevent damage to the electrolysis unit and to render it suitable for agricultural irrigation. [Display omitted] • The production of green hydrogen, water and electricity for agriculture farm in Tunisia is analyzed. • The Levelized cost of green hydrogen produced in the PV farm is 2.25 €/kg. • A PV hydrogen Farm station with a capacity of 140 kW produces 1991 kg of green hydrogen and 235 MW h of electricity yearly. [ABSTRACT FROM AUTHOR]