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Hydrogen is considered a truly clean energy source with great potential for replacing fossil fuels. However, the special physical and chemical properties of this source make large-scale, safe, and efficient storage challenging, thus limiting its widespread use. Consequently, an underground hydrogen storage system inspired by underground methane storage and CO 2 geological sequestration has been proposed, and it is increasingly becoming a focus of research. Depleted oil reservoirs are ideal sites for such systems. Nevertheless, research on these types of underground hydrogen storage systems is limited to a few feasibility assessments, and the hydrogen seepage laws in reservoirs with residual oil are not well understood. In this paper, a study was conducted involving mathematical modeling and numerical simulation of underground hydrogen storage, which was converted from the SSZ low-permeability depleted oil reservoir in Bohaiwan Basin, eastern China, to reveal the seepage patterns between hydrogen and complicated in situ fluids (oil, gas, and water). First, a comprehensive analysis was conducted using numerous rock samples and experimental data to identify the composition, genesis, and distribution patterns of the sandstone reservoir, detailing its internal pore structure and fluid distribution postdepletion characteristics. Then, the hydrogen seepage properties in the presence of oil films in the three main throat types of low-permeability sandstone were analyzed, and corresponding mathematical models of the different throats were established. Finally, a numerical simulation of underground hydrogen storage was conducted to assess the impacts of various parameters, such as injection speed, reservoir heterogeneity, and residual oil saturation, on hydrogen seepage. The planar and vertical diffusion patterns of hydrogen were clarified, and the key factors affecting the efficiency of underground hydrogen storage were analyzed, offering suggestions for the establishment of stable and efficient underground hydrogen storage systems. • Selection and description of typical low-permeability reservoirs for UHS. • Mathematical model establishment for hydrogen percolation in porous rock. • Numerical simulation of the storage process of hydrogen. • Percolation laws of hydrogen in rock porous. [ABSTRACT FROM AUTHOR]

In this paper, the numerical calculation model of salt cavern hydrogen storage was established based on the proposed salt cavern hydrogen storage in a bedded salt mine in Jiangsu Province of China. The effects of the minimum internal pressure, maximum internal pressure, average internal pressure and injection-production rate on the stability and tightness of the storage were explored respectively. The results revealed that: (1) The volume shrinkage rate and the plastic zone distribution of the surrounding rock decreased with the increase of the minimum internal pressure, and increased with the decrease of the maximum internal pressure. (2) When the depth of salt cavern is around 1700 m , its long-term stability cannot meet the requirements according to the traditional standard of 0.3–0.8 times of the vertical stress at the cavern roof. It is therefore suggested that the minimum internal pressure of the storage should be increased to 0.4 times of the vertical stress at the cavern roof. (3) The tightness evaluation indexes, including leak range, pore pressure distribution of hydrogen, and cumulative leakage of hydrogen in surrounding rock, all increased with the increase of average pressure and amplitude of internal pressure. (4) Under the same average internal pressure and injection-production frequency, the greater the injection-production rate (the amplitude of internal pressure), the smaller the cumulative leakage rate is. Therefore, increasing the injection-production rate is beneficial to the storability of the hydrogen storage. • Different internal pressures are set to study the stability and tightness of the salt cavern for hydrogen storage. • Raising the minimum internal pressure can enhance the stability of the salt cavern. • The amplitude of internal pressure is the key factor affecting the tightness of the salt cavern. • The selection of internal pressure for hydrogen storage should take into account the effects of multiple factors. [ABSTRACT FROM AUTHOR]

Regional integrated energy systems (RIES) can economically and efficiently use regional renewable energy resources, of which energy storage is an important means to solve the uncertainty of renewable energy output, but traditional electrochemical energy storage is only single electrical energy storage, and the energy efficiency level is low. Hydrogen energy storage has the advantages of large energy storage capacity, long storage time, clean and pollution-free, and can realize the synergistic and efficient utilization of electricity and thermal power. Based on this, this paper proposes a synergistic planning method for an integrated energy system with hydrogen storage taking into account the coupled use of electric-thermal energy, which effectively reduces the system carbon emission and improves the comprehensive energy efficiency level. Firstly, this paper constructs an electric-thermal coupling model of the hydrogen energy storage unit and proposes an optimization strategy for the integrated energy system containing hydrogen storage taking into account the utilization of electricity and thermal power. Secondly, a planning optimization model with the lowest economy and carbon emission and the highest comprehensive energy efficiency was constructed. Third, the CSPO-GE optimization algorithm is proposed for solving the problem, which significantly improves the solution efficiency. Finally, a planning optimization simulation of RIES for a residential community W in northern China verifies the effectiveness of the model and method proposed in this paper. The comparative analysis of the three schemes shows that compared with the integrated energy system with conventional electrochemical energy storage and heat storage tank as the main form of energy storage and the integrated energy system with only hydrogen storage, the integrated energy system with hydrogen storage and heat storage tank can reduce carbon emissions by 43.8% and 7.61%, respectively, and improve the integrated energy efficiency level by 337.14% and 14.44%. • An electrothermal coupled production strategy based on dynamic equilibrium feedback regulation is proposed. • A hydrogen-containing RIES planning and optimization model considering economy-environment-efficiency is constructed. • A multi-objective chaotic particle swarm algorithm (CPSO-GE) based on greedy and elite retention strategies is proposed • The impact of cost variation of hydrogen storage devices on the economics of integrated energy systems is considered. [ABSTRACT FROM AUTHOR]

Environmentally friendly and pollution-free hydrogen cell, battery and supercapacitor hybrid power system has taken the attention of scientists in recent years. Several notable advancements in energy storage mechanisms with hybrid power systems have been made during the last decade, influencing innovation, research, and the possible direction for improving energy storage technologies. This paper represents a quantitative analysis of all knowledge carriers with mathematical and statistical methods of hydrogen energy storage to establish a hybrid power system. For selecting the top cited papers in this topic, related articles on energy storage mechanisms for hybrid power systems were searched in the Scopus database under specified predetermined parameters. The selection technique of the most cited paper was based on filtered keywords in the hybrid hydrogen energy storage-based hybrid power system and related research during 2008–2021. About 48% of all articles have been published between 2016 and 2019; 21% will have originated from China; and 29% of the papers have used batteries as a form of energy storage in the application of electric vehicles. Most of the articles contain experimental work (25.11%) followed by simulation analysis (25%) and systematic and nonsystematic review (18.75%). Related publications with the most citations were published in 35 different impactful journals from different publishers and nations. This research found that integrating hydrogen energy storage with battery and supercapacitor to establish a hybrid power system has provided valuable insights into the field's progress and development. Moreover, it is a thriving and expanding subject of study. Bibliometric analysis was used to identify the most significant research publications on the subject of hybrid energy storage, mapping the multidisciplinary character, illustrating nature and trends, and outlining areas for further research. The process of collecting, selecting, and analyzing the most cited articles is expected to contribute to a methodical foundation for future developments of hydrogen energy storage systems and provide viable research paths toward attaining a hybrid power system. • Hydrogen-battery-supercapacitor hybrid power system made notable advancements. • A statistical analysis of hydrogen storage integrated hybrid system is demonstrated. • Top cited papers were searched in Scopus database under predetermined parameters. • Challenges and recommendations are highlighted for future energy applications. • Bibliometric analysis was used to identify potentials for future research directions. [ABSTRACT FROM AUTHOR]

The international hydrogen supply chain has been commercialized and promoted hydrogen trade. With the global energy transition, the two are expected to play a more important role and make hydrogen become a major international energy trade category similar to natural gas and LNG. This paper considers importing two hydrogen sources to Huizhou of China through MCH-TOL hydrogen storage technology from Saudi Arabia, which are produced from Natural gas + CCS and from renewable energy sources. It is estimated that the costs of dehydrogenation and purification after landing are 27.6 CNY/kgH 2 and 32.7 CNY/kgH 2 respectively, which are difficult to be competitive. Therefore, the strategy and goal of cost reduction are proposed. It is expected to control the costs of dehydrogenation and purification to less than 25 CNY/kgH 2 , and explore the feasibility of developing large-scale and economically competitive hydrogen import business in China. • Composition, development status and prospect of international hydrogen supply chain and global hydrogen export. • Select suitable liquid organic hydrogen carrier for hydrogen trans -ocean transportation. • Introduce the hydrogenation and dehydrogenation processes of Methylcyclohexane - Toluene hydrogen storage technology. • Cost estimation and competitiveness analysis of importing hydrogen from Saudi Arabia to Huizhou, Guangdong, China. • Provide strategic suggestions for China to reduce the cost of importing hydrogen from overseas. [ABSTRACT FROM AUTHOR]

Hydrogen is a promising sustainable energy carrier for the future due to its high energetic content and no emissions, other than water vapor. However, its full deployment still requires technological advances in the renewable and cost-effective production of hydrogen, cost reduction of fuel cells and especially in the storage of hydrogen in a lightweight, compact and safe manner. One way to achieve this is by using materials in which hydrogen bonds chemically, or by adsorption. Different kinds of Hydrogen Storage Materials have been investigated, such as Metal-Organic Frameworks (MOFs), Simple Hydrides (including Magnesium Hydride, MgH 2), AB 5 Alloys, AB 2 Alloys, Carbon Nanotubes, Graphene, Borohydrides, Alanates and Ammonia Borane. Billions have been invested in Storage Materials research, resulting in tens of thousands of papers. Thus, it is challenging to track how much effort has been devoted to each materials class, by which countries, and how the field has evolved over the years. Quantitative Science and Technology Indicators, produced by applying Bibliometrics and Text Mining to scientific papers, can aid in achieving this task. In this work, we evaluated the evolution and distribution of Hydrogen Storage Materials research using this methodology. Papers in the 2000–2015 period were collected from Web of Science and processed in VantagePoint® bibliometric software. A thesaurus was elaborated relating keywords and short phrases to specific Hydrogen Storage Materials classes. The number of publications in Hydrogen Storage Materials grew markedly from 2003 to 2010, reducing the pace of growth afterwards until a plateau was reached in 2015. The most researched materials were MOFs, Simple Hydrides and Carbon-based materials. There were three typical trends in materials classes: emerging materials, developed after 2003, such as MOFs and Borohydrides; classical materials with continuous growth during the entire period, such as Simple Hydrides; and stagnant or declining materials, such as Carbon Nanotubes and AB 5 Alloys. The main publishing countries were China, countries from the European Union (EU) and the USA, followed by Japan. There is a division between countries with continued growth in recent years, such as China, and those with stagnant production after 2010, such as the EU, the USA and Japan. The results of this work, compared to a previous study in storage materials patenting by our group, and the recent launch of commercial hydrogen cars and trains and stationary hydrogen production and fuel cell solutions, indicates that although the Hydrogen Energy field as a whole is transitioning from lab and prototype stages to commercial deployment, materials-based hydrogen storage still has base technological challenges to be overcome, and therefore still needs more scientific research before large scale commercialization can be realized. The developed thesaurus is made available for refinement and future works. • H 2 storage materials papers grew exponentially between 2000 and 2009, and maxed in 2015. • Most researched classes: MOFs, Simple Hydrides and Carbon-based materials. • US, EU and JP topped in 2009, while CN, KR and AU continued growing. [ABSTRACT FROM AUTHOR]

The number of hydrogen refuelling stations (HRSs) is steadily growing worldwide. In China, the first renewable hydrogen refuelling station has been built in Dalian for nearly 3 years. FLACS software based on computational fluid dynamics approach is used in this paper for simulation and analysis on the leakage and explosion of hydrogen storage system in this renewable hydrogen refuelling station. The effects of wind speed, leakage direction and wind direction on the consequences of the accident are analyzed. The harmful area, lethal area, the farthest harmful distance and the longest lethal distance in explosion accident of different accident scenarios are calculated. Harmful areas after explosion of different equipments in hydrogen storage system are compared. The results show that leakage accident of the 90 MPa hydrogen storage tank cause the greatest harm in hydrogen explosion. The farthest harmful distance caused by explosion is 35.7 m and the farthest lethal distance is 18.8 m in case of the same direction of wind and leakage. Moreover, it is recommended that the hydrogen tube trailer should not be parked in the hydrogen refuelling station when the amount of hydrogen is sufficient. • The effects of wind speed and direction on hydrogen accidents are analyzed. • The farthest harmful distance and lethal distance are calculated. • The lethal area is larger when the wind speed is low. [ABSTRACT FROM AUTHOR]

In the face of growing environmental pollution, developing a PEMFC driving shunting locomotive is a great challenge in China for environmental protection and energy saving, it combines the environmental advantages of an electric locomotive with the lower infrastructure costs of a diesel electric locomotive. In this paper, through innovation of the power system using PEMFC, an experiment prototype of a PEMFC shunting locomotive has been developed which will reduce the effects on the environment. The performance of the fuel cell power plant and the integrated locomotive are experimentally investigated. It is the first locomotive to use a PEMFC power plant in China. Staring from October 2012, we started to test the PEMFC locomotive on the test rail-line in Chengdu, Sichuan. The achieved encouraging results can provide fundamental data for further modification of the locomotive powered by individual PEMFC stack or even development of hybrid ones powered by PEMFC and other power sources in China. [ABSTRACT FROM AUTHOR]