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Renewable hydrogen is considered as one of the key technologies that may be needed to fully decarbonise our economies, providing the high-temperature heat, fuels and feedstock that might not be possible to electrify. Several pilot projects are underway, and some assessments of the economics of green hydrogen have been published. However, most of them have assessed the costs of producing renewable hydrogen in large-scale, grid-connected units. Another option, pointed by many as a robust strategy in the early stages, is to produce hydrogen locally, in "hydrogen valleys", to serve industrial demand. In this paper, the economics of the different technical configurations and strategies that might be used for this decentralised, variable-demand option are analysed, accounting for the impact that a non-constant operation may cause on the operational efficiency of electrolysers, and for the potential benefits of local hydrogen storage. Our results show that when hydrogen demand is variable, production costs are higher compared to the constant demand case, due to the higher electrolyser size required. Electricity price optimization plus hydrogen storage can be a valuable option in some cases, although the cost benefit is negligible (about 1%) unless price volatility in the market increases with higher RES shares, or investment costs decrease significantly. Sourcing electricity exclusively from a dedicated renewable power plant can only become competitive if electricity market prices rise as observed recently or triggered by increasing CO 2 prices. • Different production strategies are compared to minimise H 2 production costs. • Faraday efficiency increases costs for variable electricity generation. • Electricity price optimization is best for H2 valleys, although compression costs may change this. • Direct H 2 production from renewable plants is not competitive with current prices. [ABSTRACT FROM AUTHOR]

This paper will introduce the concept of 100% renewable energy and the role hydrogen and fuel cells can play for storage and transportation sectors. The importance, necessity and possibility of an overall global transition from fossil and nuclear-based fuels to renewable energy fuels using electricity and hydrogen as clean energy carriers will be summarized. Polluted, inefficient and unhealthy societies of today are missing energy self-sufficient, better managed, in harmony with nature ecological communities. The possible role of hydrogen fuel cells in fulfilling this target will be demonstrated and the success stories of the leading countries will be given. Renewable energy investments which have started in 2013 increased steadily and reached to 290 billion dollars towards the end of 2015. Today's increasing investments and cheaper supply of renewable energy will in turn effect the hydrogen production costs and increase the diversion from fossil fuels to cheap renewable energy. This reality confirms that hydrogen energy technologies will play an important role in reaching the 100% renewable energy target. [ABSTRACT FROM AUTHOR]

The demand for clean power source which can be used to run the various types of vehicles on the road is increasing on a daily basis due to the fact that high emissions released from internal combustion engine play a significant role in air pollution and climate change. Fuel cell devices, particularly Proton Exchange Membrane (PEM) type, are strong candidates to replace the internal combustion engines in the transport industry. The PEMFC technology still has many challenges including high cost, low durability and hydrogen storage problems which limit the wide-world commercialization of this technology. In this paper, the fuel cell cost, durability and performances challenges which are associated with using of fuel cell technology for transport applications are detailed and reviewed. Recent developments that deal with the proposed challenges are reported. Furthermore, problems of hydrogen infrastructure and hydrogen storage in the fuel cell vehicle are discussed. [ABSTRACT FROM AUTHOR]

Abstract: Energy production and combating climate change are among some of the most significant challenges we are facing today. Whilst the introduction of a hydrogen economy has its merits, the associated problems with on-board hydrogen storage are still a barrier to implementation. Ammonia and related chemicals may provide an alternative energy vector. Besides ammonia and metal amine salts, some other ammonia related materials such as hydrazine, ammonia borane, ammonia carbonate and urea also have the potential for use as alternative fuels. These materials conform to many of the US DOE targets for hydrogen storage materials. Similar to hydrogen, ammonia itself is carbon-free at the end users, although CO2 emission on production of ammonia is dependent on the source of energy. Both hydrogen and ammonia utilised similar energy sources for production: fossil fuels, biomass, renewable electricity, nuclear and solar energy. While a number of papers have been published on the catalytic decomposition of ammonia or related chemicals to produce hydrogen, the use of fuel cells directly fed by ammonia and related chemicals would have a higher efficiency. In recent years significant progress has been made on direct ammonia, hydrazine and urea fuel cells to generate electricity from these materials for transport applications. With the development and application in these technologies, reduction of CO2 emissions in transportation would be possible. In this review, we propose the use of ammonia and related chemicals as potential indirect hydrogen storage materials. The progress on fuel cells using these fuels is also briefly reviewed. [Copyright &y& Elsevier]