Search

In this work, anode-supported solid oxide fuel cells (SOFCs) has been successfully prepared by tape casting and co-sintering technique. The structure contains the thin and dense 10% Sc 2 O 3 -stabilized-ZrO 2 (SSZ) electrolyte layer and the anode layers with continuous porosity gradient. The decomposition of organic additives and the shrinkage of green tape were analyzed by thermo-gravimetric and differential thermal analyses (TG-DSC) and thermal dilatometry. The microstructure morphologies and the porosity of anodes were examined by SEM and Archimedes method. The obtained anodes with continuous porosity gradient facilitate diffusion of the fuel gas and enlarge electrochemical active three phase boundaries. The open circuit voltage (OCV) was close to 1.1 V. The maximum power densities of single cell with graded Ni-SSZ anode were higher than non-gradient Ni-SSZ anode at 600, 650, 700, 750 and 800 °C and were 0.15, 0.30, 0.51, 0.70 and 1.00 W cm −2 , respectively. R p of cell with graded Ni-SSZ anode was lower than that of non-gradient Ni-SSZ anode. [ABSTRACT FROM AUTHOR]

Abstract: Understanding the sintering processes extensively is critical in fabricating a flat cell for solid oxide fuel cell stacks, but few have reported the sintering process and stress development during the constrained sintering of the electrolyte layer on anode substrate. In this study, we show that the green tape of half cell fabricated by co-tape casting cracks into several pieces when it is heated directly to 1400 °C of profile I, while it remains flat and complete when the green tape is sintered with additional pre-sintered profile at 1300 °C of profile II. The strain rate characteristics indicate that the difference of 2.43 × 10−6 s−1 between the electrolyte and the anode layer leads to the stress development in the directly sintered cell, while it reduces to 6.7 × 10−8 s−1 for the pre-sintered cell, which is only 3% of that without pre-sintering. The stress based on continuum model calculated results in the sintered cell demonstrates that the stress increases from 0 at about 1000 °C to 2.60 MPa at 1300 °C, and increased from 2.60 MPa to 6.54 MPa in temperature range of 1300–1400 °C. But it was lower than half of the stress for the pre-sintered cell according to profile II. The SEM images, together with a circuit voltage of 2.22 V for two cell stack, indicate that the electrolyte of the unit cell is dense. The power is 41.7 W, with a power density of 0.26 W cm−2 at 1.4 V and 750 °C for a two tells stacks sintered according to profile II. The ASR of the two cells stack is 2.50 Ω cm2. [Copyright &y& Elsevier]