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Herein, we present a mussel-inspired supramolecular polymer coating to improve the an-ti-corrosion and self-healing properties of an AZ31B magnesium alloy. A self-assembled coating of polyethyleneimine (PEI) and polyacrylic acid (PAA) is a supramolecular aggregate that takes advantage of the weak interaction of non-covalent bonds between molecules. The cerium-based conversion layers overcome the corrosion problem between the coating and the substrate. Catechol mimics mussel proteins to form adherent polymer coatings. Chains of PEI and PAA interact electrostatically at high density, forming a dynamic binding that causes strand entanglement, enabling the rapid self-healing properties of a supramolecular polymer. The addition of graphene oxide (GO) as an anti-corrosive filler gives the supramolecular polymer coating a superior barrier and impermeability properties. The results of EIS revealed that a direct coating of PEI and PAA accelerates the corrosion of magnesium alloys; the impedance modulus of a PEI and PAA coating is only 7.4 × 103 Ω·cm2, and the corrosion current of a 72 h immersion in a 3.5 wt% NaCl solution is 1.401 × 10−6 Ω·cm2. The impedance modulus of the addition of a catechol and graphene oxide supramolecular polymer coating is up to 3.4 × 104 Ω·cm2, outperforming the substrate by a factor of two. After soaking in a 3.5 wt% NaCl solution for 72 h, the corrosion current is 0.942 × 10−6 A/cm2, which is superior to other coatings in this work. Furthermore, it was found that 10-micron scratches were completely healed in all coatings within 20 min, in the presence of water. The supramolecular polymer offers a new technique for the prevention of metal corrosion. [ABSTRACT FROM AUTHOR]

Supramolecular polymers are widely utilized and applied in self-assembly or self-healing materials, which can be repaired when damaged. Normally, the healing process is classified into two types, including extrinsic and intrinsic self-healable materials. Therefore, the aim of this work is to review the intrinsic self-healing strategy based on supramolecular interaction or non-covalent interaction and molecular recognition to obtain the improvement of mechanical properties. In this review, we introduce the main background of non-covalent interaction, which consists of the metal–ligand coordination, hydrogen bonding, π–π interaction, electrostatic interaction, dipole–dipole interaction, and host–guest interactions, respectively. From the perspective of mechanical properties, these interactions act as transient crosslinking points to both prevent and repair the broken polymer chains. For material utilization in terms of self-healing products, this knowledge can be applied and developed to increase the lifetime of the products, causing rapid healing and reducing accidents and maintenance costs. Therefore, the self-healing materials using supramolecular polymers or non-covalent interaction provides a novel strategy to enhance the mechanical properties of materials causing the extended cycling lifetime of products before replacement with a new one. [ABSTRACT FROM AUTHOR]

Herein, we present a mussel-inspired supramolecular polymer coating to improve the an-ti-corrosion and self-healing properties of an AZ31B magnesium alloy. A self-assembled coating of polyethyleneimine (PEI) and polyacrylic acid (PAA) is a supramolecular aggregate that takes advantage of the weak interaction of non-covalent bonds between molecules. The cerium-based conversion layers overcome the corrosion problem between the coating and the substrate. Catechol mimics mussel proteins to form adherent polymer coatings. Chains of PEI and PAA interact electrostatically at high density, forming a dynamic binding that causes strand entanglement, enabling the rapid self-healing properties of a supramolecular polymer. The addition of graphene oxide (GO) as an anti-corrosive filler gives the supramolecular polymer coating a superior barrier and impermeability properties. The results of EIS revealed that a direct coating of PEI and PAA accelerates the corrosion of magnesium alloys; the impedance modulus of a PEI and PAA coating is only 7.4 × 103 Ω·cm2, and the corrosion current of a 72 h immersion in a 3.5 wt% NaCl solution is 1.401 × 10−6 Ω·cm2. The impedance modulus of the addition of a catechol and graphene oxide supramolecular polymer coating is up to 3.4 × 104 Ω·cm2, outperforming the substrate by a factor of two. After soaking in a 3.5 wt% NaCl solution for 72 h, the corrosion current is 0.942 × 10−6 A/cm2, which is superior to other coatings in this work. Furthermore, it was found that 10-micron scratches were completely healed in all coatings within 20 min, in the presence of water. The supramolecular polymer offers a new technique for the prevention of metal corrosion.

Supramolecular polymers are widely utilized and applied in self-assembly or self-healing materials, which can be repaired when damaged. Normally, the healing process is classified into two types, including extrinsic and intrinsic self-healable materials. Therefore, the aim of this work is to review the intrinsic self-healing strategy based on supramolecular interaction or non-covalent interaction and molecular recognition to obtain the improvement of mechanical properties. In this review, we introduce the main background of non-covalent interaction, which consists of the metal–ligand coordination, hydrogen bonding, π–π interaction, electrostatic interaction, dipole–dipole interaction, and host–guest interactions, respectively. From the perspective of mechanical properties, these interactions act as transient crosslinking points to both prevent and repair the broken polymer chains. For material utilization in terms of self-healing products, this knowledge can be applied and developed to increase the lifetime of the products, causing rapid healing and reducing accidents and maintenance costs. Therefore, the self-healing materials using supramolecular polymers or non-covalent interaction provides a novel strategy to enhance the mechanical properties of materials causing the extended cycling lifetime of products before replacement with a new one.

Nowadays, finely controlling the mechanical properties of polymeric materials is possible by incorporating supramolecular motifs into their architecture. In this context, the synthesis of a side-chain terpyridine-functionalized poly(2-(dimethylamino)ethyl methacrylate) is reported via reversible addition-fragmentation chain transfer polymerization. By addition of transition metal ions, concentrated aqueous solutions of this polymer turn into metallo-supramolecular hydrogels whose dynamic mechanical properties are investigated by rotational rheometry. Hence, the possibility for the material to relax mechanical constrains via dissociation of transient cross-links is brought into light. In addition, the complex phenomena occurring under large oscillatory shear are interpreted in the context of transient networks.

Nowadays, finely controlling the mechanical properties of polymeric materials is possible by incorporating supramolecular motifs into their architecture. In this context, the synthesis of a side-chain terpyridine-functionalized poly(2-(dimethylamino)ethyl methacrylate) is reported via reversible addition-fragmentation chain transfer polymerization. By addition of transition metal ions, concentrated aqueous solutions of this polymer turn into metallo-supramolecular hydrogels whose dynamic mechanical properties are investigated by rotational rheometry. Hence, the possibility for the material to relax mechanical constrains via dissociation of transient cross-links is brought into light. In addition, the complex phenomena occurring under large oscillatory shear are interpreted in the context of transient networks. [ABSTRACT FROM AUTHOR]