1. Structure-Property Relationship of New Organic Sensitizers Based on Multicarbazole Derivatives for Dye-Sensitized Solar Cells
- Author
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Jin-Kyu Kang, Hyo Jeong Jo, Jung Eun Nam, Dae-Hwan Kim, and Hyojeong J. Kim
- Subjects
Photocurrent ,Materials science ,Article Subject ,Renewable Energy, Sustainability and the Environment ,Open-circuit voltage ,Energy conversion efficiency ,lcsh:TJ807-830 ,lcsh:Renewable energy sources ,General Chemistry ,Molar absorptivity ,Photochemistry ,Atomic and Molecular Physics, and Optics ,law.invention ,Dye-sensitized solar cell ,chemistry.chemical_compound ,chemistry ,law ,Solar cell ,Thiophene ,General Materials Science ,Absorption (electromagnetic radiation) - Abstract
A new multicarbazole based organic dye (C2A1,C2S1A1) with a twisted structure was designed and synthesized, and the corresponding dye (C1A1) without the twisted structure was synthesized for comparison. They were successfully applied in dye-sensitized solar cells (DSSCs). The results showed that the nonplanar structure ofC2A1andC2S1A1can efficiently retard the dye aggregation and charge recombination. The organic dye (C2S1A1) with thiophene units also exhibited a higher molar extinction coefficient and red-shifted absorption, which leads to an improved light harvesting efficiency. TheC2S1A1-sensitized solar cell produced a solar-to-electricity conversion efficiency of 5.1%, high open circuit voltage (Voc) of 0.69 V, and short-circuit photocurrent density of 10.83 mA cm−2under AM 1.5 irradiation (100 mW cm−2) conditions.
- Published
- 2014
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