1. Efficient quantum cutting of lanthanum and ytterbium ions co-doped perovskite quantum dots towards improving the ultraviolet response of silicon-based photodetectors.
- Author
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Yang, Gang, Zheng, Changbo, Zhu, Yongsheng, Li, Xueguo, Huang, Jinshu, Xu, Xiumei, Liu, Wei, Cui, Shaobo, and Pan, Gencai
- Subjects
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YTTERBIUM ions , *YTTERBIUM , *QUANTUM dots , *PHOTODETECTORS , *PHOTOELECTRIC devices , *QUANTUM efficiency , *SILICON solar cells - Abstract
High-efficiency quantum cutting materials have great application prospects in improving the photoelectric conversion efficiency of silicon-based photoelectric devices. Herein, La3+ and Yb3+ ions co-doped CsPbCl 3 perovskite quantum dots (PQDs) were prepared successfully via the modified hot-injection method. La3+ and Yb3+ ions codoping makes the PLQY of CsPbCl 3 PQDs increase from 5% to 168%. This is because Yb3+ ions doping makes the effective quantum cutting process happen, as well as La3+ ions doping effectively reduces non-radiative transition in CsPbCl 3 PQDs and further improves the quantum cutting efficiency. Finally, La3+ and Yb3+ ions co-doped CsPbCl 3 PQDs film were integrated on silicon-based photodetectors. The spectral range of silicon-based photodetectors is extended to the ultraviolet (UV) region (200–400 nm) besides the visible spectral region. The external quantum efficiency (EQE) is around 67%, and the responsivity is 0.14 A/W, which is comparable to the highest value previously reported. This work provides a new strategy to improve the quantum cutting efficiency and the performance of silicon-based photodetectors. • The PLQY of CsPbCl 3 PQDs increase from 5% to 168% via La3+ and Yb3+ codoping. • La3+/Yb3+ co-doped CsPbCl 3 PQDs were integrated on silicon photodetectors. • The response spanning of silicon photodetectors is extended to the ultraviolet. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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