1. Strengthening and toughening mechanisms of P-rich phase in Cu-4Sn-P alloy wire.
- Author
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Duan, Xin-Rong, Chen, Yan, Hong, Zhi-Yuan, Wang, Song-Wei, Chen, Shuai-Feng, and Zhang, Shi-Hong
- Subjects
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TENSILE strength , *ELECTRON scattering , *SCANNING electron microscopes , *ELECTRIC conductivity , *OPTICAL microscopes - Abstract
The Cu-4Sn and Cu-4Sn-0.15P alloys with rod diameter of 12.5 mm were prepared and then cold drawn to 2.6 mm via multi-pass drawing. The microstructure evolutions, mechanical properties, and electrical conductivity of Cu-4Sn and Cu-4Sn-0.15P alloys were comprehensively analyzed using optical microscope, scanning electron microscope, tension test and electrical conductivity tester. As compared with the P-free alloy, the addition of P can form a new kind of P-rich phase in the Cu-4Sn alloy, and thus refine the casting microstructure via pinning the grain boundary. The toughening mechanisms of P-rich phases in Cu-4Sn-P alloy wires during cold drawing were investigated. With accumulative drawing strain, the spherical P-rich phase gradually changes into fibrous phases, which thus introduce obvious fiber reinforced strengthening. In addition, the distribution of P-rich phase also enhances the< 111 > texture, and promotes the growth of fragmentation zone. It contributes to an improved ultimate tensile strength and final elongation from 664.5 MPa and ∼ 0 % in Cu-4Sn alloy to 970.5 MPa and 1.53 % in Cu-4Sn-0.15P alloy. Finally, the conductivity for Cu-4Sn-0.15P decreases slightly owing to the intensified electron scattering with high amount of primary phase after the addition of P element. • Adding P to Cu-Sn alloy results in more uniform grain size, while increasing dendrite segregation. • Cu-4Sn-0.15 P alloy wire present more homogeneous distribution of P-rich phases with P content of 9 wt%. • Spherical P-rich phases evolve into fibrous shapes, contributing to higher strength and better elongation. • The addition of P increases the proportion of grain fragmentation during drawing. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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