1. Enhanced hydrogen storage capacity and kinetics in AZ61 alloy with nickel and cobalt additives: Insights into reaction mechanisms and activation energy.
- Author
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Mose, Matoke Peter and Huang, Song-Jeng
- Subjects
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COBALT nickel alloys , *HYDROGEN storage , *X-ray photoelectron spectroscopy , *HYDROGEN as fuel , *SCANNING electron microscopy , *ALLOY powders - Abstract
This study explores the synthesis of AZ61 alloy composite powders with Co-Ni additives using high-energy ball milling (HEBM). The powders are extensively characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) to analyze their morphology, composition, structure, and bonding. The hydrogen storage capacity of the powders is measured using a Sievert's-type system revealing diverse capacities. For AZ61 alloy with Ni additive (2 µm), it absorbs 90% of the capacity in 410 s, showing an activation energy of 91.46 kJmol−1 and displays Mg 2 NiH 4 as an intermediate. On the other hand, AZ61 alloy with Co additive requires 576 s to absorb 90% of the capacity, showing an activation energy of 117.23 kJmol−1 and Mg 2 CoH 5 as an intermediate. When a mixture of Ni and Co is added to AZ61 alloy, it achieves 90% capacity absorption in 300 s. In the absence of additives, AZ61 alloy (15 µm) reaches 90% capacity absorption in 1600 s. The incorporation of additives significantly reduces the activation energy. A correlation between longer absorption times and larger activation energies provides valuable insights into the storage kinetics and activation energy associated with the hydrogen absorption/desorption process. [Display omitted] • The addition of Ni, Co, and a mixture of Ni and Co to the AZ61 alloy enhances its hydrogen storage capacity compared to the alloy without additives. • The hydrogen storage capacities of the AZ61 alloy with Ni, Co, and Ni-Co additives were measured to be 4.5 wt%, 5.316 wt%, and 5.14 wt%, respectively. • The presence of specific reaction intermediates, such as Mg 2 NiH 4 and Mg 2 CoH 5 , was confirmed through XRD patterns, indicating their role in the hydrogen absorption process and promoting reversibility and cycle stability. • The activation energy for hydrogen absorption in the AZ61 alloy with Co additive was found to be 117.23 kJ/mol while that of Ni was 91.46 kJ/mol. • Kinetics to achieve 90% capacity: AZ61 alloy with Ni additive requiring 410 s, the alloy with Co additive requiring 576 s, the alloy with Ni and Co mixture requiring 300 s, and the alloy without additives requiring 1600 s. These results highlight the influence of additive composition on the kinetics of hydrogen absorption. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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