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FeSe 2 shows superior advantages as anode of lithium-ion batteries (LIBs) with abundant resources, high theoretical specific capacity, and environmentally friendly. However, the FeSe 2 anode still faces great challenges balancing specific capacity, capability, and stability. In this work, we employ a self-sacrifice template of Fe-PBA coated with polydopamine to prepare FeSe 2 @Void@NC cubic nanostructures by one-step pyrolysis and selenization. The experimental results well elucidate the unique hollow cubic architectures with high surface area and abundant pore structure induce rapid adsorption storage, thus improving electrochemical kinetics. Benefiting from the enhanced ion diffusion kinetics and high conductivity through N-doped carbon coating, the FeSe 2 @Void@NC electrode demonstrates a considerable capability with a high specific capacity of 493.93 mAh g−1 (3 A g−1), and a stable cyclability with a reversible capacity of 498.5 mAh g−1 (1 A g−1) after 750 cycles. The full cells with FeSe 2 @Void@NC anode and LiFePO 4 cathode also exhibit remarkable rate capability and stable cyclability. Our research provides profound insights into the structure engineering of alternative transition metal sulfide anode for LIBs with excellent electrochemical performance. [Display omitted] • The prepared FeSe 2 @Void@NC anode demonstrates a brilliant performance as LIB anode materials. • The synergistic effect of the interface coupling and dual carbon protection greatly facilitates electron and mass transfer. • The FeSe 2 @Void@NC electrode behaves fast lithium-ion diffusion rate and favorable electrochemical kinetics. [ABSTRACT FROM AUTHOR]