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• Ni(Co)MoO 4 hybrid electrode with a mixed structure was synthesized on nickel foam. • The hybrid electrode exhibits a remarkable cycling performance due to the mixed morphology. • The asymmetric supercapacitor shows a high energy density of 55.71 Wh kg−1 at the power density of 375 W kg−1. [Display omitted] In this work, the Ni(Co)MoO 4 (NMO-Co) hybrid materials with nanoneedle and nanosheet structure were prepared on nickel foam (NF) by the hydrothermal method for high-stability supercapacitors. The effect of Co presence on the structure and electrochemical properties of NMO-Co was investigated. As the molar of Cobalt increased, more nanoneedles grew on the surface of NiMoO 4 /NF. The combination of the Ni-doped CoMoO 4 nanoneedles and Co-doped NiMoO 4 nanosheets was irregularly arranged on the surface of NF, which emerged an improvement of the cycling performance. When the molar ratio of Co: Ni: Mo was 0.5: 1: 1, the capacitance retention of the hybrid electrode was 80.1% after 10,000 cycles at 10 A g−1, while the pure NiMoO 4 electrode was 53.1%. Moreover, an asymmetric supercapacitor device displayed high energy density and power density. The maximum energy density and power density could reach 55.71 Wh kg−1 and 14,999 W kg−1, respectively. The hybrid electrode's good electrochemical performance is due to the combination of mutual doping of Ni and Co with a mixed morphology. [ABSTRACT FROM AUTHOR]