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A p-n-type Bi 5 O 7 I-modified porous g-C 3 N 4 nano-heterojunction is synthesized via a simple preparation technique using the template method and annealing-hydrothermal co-deposition method. The results of SEM, EDS, elemental mapping, XRD, TEM, XPS and FT-IR imply that the Bi 5 O 7 I nanoparticles were successfully deposited on the surface of the g-C 3 N 4 nanosheets. The photocatalytic activity of the as-prepared p-n-type nano-heterojunction remarkably exhibits an enhancement of 30 times that of the unmodified samples. Furthermore, the photocatalytic degradation enhancement mechanism has been studied, which could be ascribed to the p-n-type nano-heterojunction and lamellar-porous structure of the g-C 3 N 4 . [ABSTRACT FROM AUTHOR]

In the present work, a series of layered BiOBr/g-C 3 N 4 heterojunction photocatalysts were prepared via a simple reflux process, and their photocatalytic performance was investigated by the degradation of rhodamine B (RhB) and bisphenol A (BPA) under visible light irradiation. It was found that BiOBr nanoplates were deposited on the external surface of g-C 3 N 4 nanosheets (CNNS) and the tightly contacted interface was formed between two components, giving rise to a 2D porous layered heterojunction structure with a high specific area. It was found that BiOBr nanoplates coupled with the proper amount of CNNS exhibited an excellent photocatalytic performance due to the combined effects of layered heterojunction, high specific surface area and porous structure, which lead to the high efficiency of light harvesting and charge separation. The active species of OH is the most crucial one while h + and O 2 − contributed to a lesser extent in RhB and BPA photocatalytic degradation. Based on the direct evidence of the formed OH, O 2 − and h + active species detected by active species capture experiment and ESR spectra, a Z-scheme photocatalytic mechanism was proposed for the charge separation. The present work may provide an insight for designing novel layered Z-scheme heterojunction photocatalysts with a high performance. [ABSTRACT FROM AUTHOR]