1. Ti3C2Tx MXenes bonded MoS2 nanosheets for superior sodium-ion batteries.
- Author
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Han, Jiachen, Xu, Wenbin, Liu, Zhimin, Gao, Zhaoyang, Tao, Song, Min, Huihua, Yang, Hao, and Wang, Jin
- Subjects
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CHARGE transfer kinetics , *NANOSTRUCTURED materials , *DIFFUSION kinetics , *CHEMICAL stability , *ENERGY storage , *CHARGE transfer , *SODIUM ions - Abstract
Sodium-ion batteries (SIBs) have evolved into the most potential alternatives to lithium-ion batteries (LIBs) especially for large-scale energy storage applications. However, the large radius of sodium ion inevitably causes large volume change and sluggish ion diffusion kinetics. Molybdenum disulfide (MoS 2) as a rising star of anode for SIBs has raised concern because of its high theoretical capacity. Nevertheless, MoS 2 suffers from low electronic conductivity and serious re-stacking, resulting in declined cycling stability and poor rate capability. Herein, we reported an electrostatic self-assembly process to synthesize three-dimensional (3D) crumpled MXene-bonded MoS 2 nanosheets. The MoS 2 /MXene heterostructure not only avoids the serious self-aggregation of MoS 2 nanoparticles but only maintains the chemical and mechanical stability of MoS 2 /MXene hybrids during sodiation and desodiation. Strong chemical interactions were validated on the interface of MXene and MoS 2 , favoring fast charge transfer kinetics and durable structural stability. The developed MoS 2 /MXene electrode exhibits a high specific capacity (509 mAh g−1 at 0.05 A g−1) and considerable cyclability (326 mAh g−1 at 1 A g−1 after 900 cycles), manifesting a promising application prospect for SIBs. Our work can provide a rational strategy for the electrode design strategy for SIBs. [Display omitted] • Crumpled MXene bonded MoS 2 nanosheets demonstrate a brilliant performance as SIB anode materials. • The synergistic effect of crumpled MXene and MoS 2 nanosheets, greatly facilitates electron and mass transfer. • The MoS 2 /MXene electrode behaves fast sodium diffusion rate and favorable electrochemical kinetics. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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