1. Enhanced of Tb3+ emission in KSr4(BO3)3:Dy3+, Tb3+ phosphors via energy transfer from Dy3+.
- Author
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Leng, Zhihua, Yu, Guihong, Li, Linlin, Liu, Yali, zhang, Nannan, and Gan, Shucai
- Subjects
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ENERGY transfer , *ENERGY storage , *ENERGY density , *DIPOLE-dipole interactions , *OPTICAL materials - Abstract
With K + as charge compensator, a series of KSr 4 (BO 3 ) 3 :Dy 3+ , Tb 3+ phosphors were successfully synthesized by solid–state reaction process. Under near-ultraviolet excitation (389 nm), the green emission of Tb 3+ is observed in Dy 3+ /Tb 3+ codoped samples due to the efficient energy transfer from Dy 3+ to Tb 3+ . The energy transfer efficiency, average donor-acceptor distance, as well as transfer mechanism were also studied. The energy transfer efficiency of KSr 4 (BO 3 ) 3 :Dy 3+ , xTb 3+ increased gradually and reached about 60% when the concentration of Tb 3+ was 0.030. And the critical distance R Dy-Tb was calculated to be 15.36 Å. Moreover, the energy transfer mechanism from Dy 3+ to Tb 3+ in KSr 4 (BO 3 ) 3 host was demonstrated to be dipole–dipole interaction. In addition, the emitting colors of Dy 3+ /Tb 3+ codoped samples can be adjusted from the edge of white area to green via tuning the Tb 3+ doped concentration. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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