1. Developing β-type bulk metallic glass composites from Ti/Zr-based bulk metallic glasses by an iteration method.
- Author
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Zhang, Long, Fu, Huameng, Li, Hong, Zhu, Zhengwang, Zhang, Hongwei, Li, Weirong, Li, Yangde, and Zhang, Haifeng
- Subjects
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METALLIC glasses , *GLASS composites , *SUPERCOOLED liquids , *SOLIDIFICATION , *THERMODYNAMICS - Abstract
Bulk metallic glass composites containing in-situ formed β-Ti/Zr phases (β-type BMGCs), which exhibit a good combination of strength and plasticity, were generally developed by adding β-stabilizers, such as Nb, Ta, V, etc., into Ti/Zr-based bulk metallic glasses (BMGs). In this work, an iteration method is proposed to develop β-type BMGCs from Ti/Zr-based BMGs, and the compositions of BMGCs can be designed by “the composition of in-situ formed β phase (the iterative variable) + the composition of BMG”. Due to the fast elemental diffusions between the β phase and the (supercooled) liquid phase, the iteration method can develop β-type BMGCs in which both phases can maintain a mutual (metastable) equilibrium during solidification. The procedures of the iteration method and its underlying thermodynamic and kinetic principles are discussed, and a Zr 56.9 Ti 18.8 Cu 7.4 Ni 5.7 Be 11.3 BMGC was developed from Vitreloy 1 by using the iterative method. As compared with β-type BMGCs developed by the conventional method, β-type BMGCs developed by the iteration method have two advantages: (i) the good glass-forming ability of the initial BMGs can be largely inherited by the glassy matrices in BMGCs; (ii) without adding β-stabilizers, the in-situ formed β phases are more likely to be metastable. The current iteration method is of scientific significance on improving plasticity of Ti/Zr-based BMGs and developing new β-type BMGCs. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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