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Abstract: Sm:CaNb2O6 single crystal has been grown by the Czochralski method. Its high-temperature X-ray powder diffraction, optical absorption, emission spectroscopic as well as lifetime have been studied. Thermal expansion coefficients (α), J–O parameters (Ω i ), radiative lifetime (τ rad), branching ratios (β) and stimulated emission cross-sections (σ e) were calculated. The quantum efficiency (η) was calculated to be 97%. The intense peak emission cross section at 610, 658nm were calculated to be 2.40×10−21, 2.42×10−21 cm2. These results indicate that Sm:CaNb2O6 crystal has potential use in visible laser and photonic devices area. [Copyright &y& Elsevier]

Abstract: In this paper, a Yb3+ doped Lu3ScAl4O12 single crystal has been grown by the Czochralski method. The cell parameters were analyzed with X-ray diffraction (XRD). The absorption spectrum, emission spectrum and fluorescence lifetime of Yb:Lu3ScAl4O12 crystal were measured at room temperature. The absorption bandwidth, emission bandwidth, absorption cross-section, emission cross-section and fluorescence lifetime have been estimated as 25nm, 12.6nm, 0.54×10−20 cm2, 1.47×10−20 cm2 and 1.43ms. The spectral properties of Yb:Lu3ScAl4O12 crystal were compared with those of Yb:Lu3Al5O12 (Yb:LuAG) crystal. The results indicate that Yb:Lu3ScAl4O12 crystal should be a potential candidate used for generating short pulses in mode-locking operation. [Copyright &y& Elsevier]