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Abstract A facile one-step solid-phase synthesis strategy is developed for synthesizing a binder-free molybdenum disulfide/carbon fibers paper (MoS 2 /CFP) anode. The microstructure, composition, morphology and electrochemical performances were investigated. It is found that the thin MoS 2 layers are well anchored on the interlaced carbon fibers to form MoS 2 /CFP, which has mesoporous structure and large specific surface area of ∼18.8 m2g-1. As a result, the obtained MoS 2 /CFP anode exhibits a reversible capacity of 261 mAh·g−1 with 31.2% loading ratio of MoS 2. After subtracting the capacity of CFP, the MoS 2 in the composite anode delivers a reversible capacity of 539 mAh·g−1 and shows better cycle stability than commercial MoS 2 after 100 cycles at 100 mA g−1. The remarkable electrochemical performances could be attributed to the buffer space among carbon fibers for the volume changes of MoS 2 as well as the highly conductive carbon fibers network, suggesting that the MoS 2 /CFP is a promising binder-free anode for lithium-ion batteries. Graphical abstract Image 1 Highlights • A one-step solid-phase synthesis strategy is developed to fabricate MoS 2 /CFP anode. • The MoS 2 and the carbon matrix of MoS 2 /CFP composite were synthesized synchronously. • The MoS 2 /CFP anode exhibits enhanced cycling performance and high-rate capability. • The mechanism of the enhanced electrochemical properties was discussed for MoS 2 /CFP. [ABSTRACT FROM AUTHOR]