1. Activation of lignin-derived biochar with mixed H2O and CO2: Characterization of reaction intermediates and investigation their potential synergistic effects.
- Author
-
Jiang, Yuchen, Ming, Cong, Zhang, Shu, Gholizadeh, Mortaza, Wang, Yi, Hu, Song, Xiang, Jun, and Hu, Xun
- Subjects
- *
BIOCHAR , *CARBON dioxide , *LIGNINS , *ACTIVATED carbon , *LIGNIN structure , *SURFACE area , *MESOPORES - Abstract
Physical activation of biomass with H 2 O or CO 2 is an important method for producing activated carbon (AC). Activation of biomass with CO 2 or H 2 O follows varied mechanisms and the use of mixed CO 2 /H 2 O might show potential synergistic effects for creating pores. This was investigated by activation of lignin-derived biochar with H 2 O, CO 2 and their mixture. The results demonstrated that H 2 O as an activator was much more effective than CO 2 for generation of pores (804.1 m2g−1 versus 516.1 m2g−1in CO 2), especially mesopores (40% versus 14% in CO 2). This was achieved via enhancing cracking/gasification reactions of the biochar with H 2 O. The synergistic effect of CO 2 and H 2 O for activation of the lignin-derived biochar was insignificant as cracking/gasification reactions were not enhanced, leading to remarkably lower specific surface area of the AC (674.8 m2g−1) than that with H 2 O as an activator alone. Competitive adsorption of CO 2 and H 2 O existed and preferable adsorption of CO 2 hindered deoxygenation of the biochar with H 2 O. The in-situ IR characterization indicated that CO 2 presence suppressed decarbonylation reactions, retaining more oxygen species in form of C O, while it was the opposite in H 2 O. Additionally, activation with H 2 O formed numerous round-shape dents on surface of activated carbon, while the activation with CO 2 formed the characteristic round edges. The AC activated with H 2 O showed superior capability for adsorption of phenol than that activated with CO 2 or mixed H 2 O/CO 2. [Display omitted] • H 2 O is more effective than CO 2 for cracking, forming less activated carbon (AC). • Synergistic effect of CO 2 /H 2 O is insignificant as creating pores are not enhanced via cracking. • Competitive while preferable adsorption of CO 2 hinders activation with H 2 O. • CO 2 is not as active as H 2 O for cracking of C O in intermediates and for creating pores. • AC activated with H 2 O is superior for adsorbing phenol. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF