Search

Presents a study which performed quantitative x-ray diffraction measurements on a nanocrystalline copper sample made by severe plastic deformation. Experimental results; Discussion and conclusions.

We present a new giant magnetoresistance (GMR) material composed of polyaniline, polystyrene, sulfur, manganese acetylacetonate, lanthanum, and praseodymium chlorides. These compounds were mixed and processed mechanochemically to obtain thin films. External magnetic field of 6000 Oe increases conductivity of films by more than 300%. Analysis of transient current kinetics after application of constant voltage (10 V) to samples showed the existence of three types of charge carriers, which we identified as e-, H+, and Cl-. Contribution of functional groups of polyaniline and elemental sulfur S in the formation of the above charge carriers in this new GMR composite material is discussed. [ABSTRACT FROM AUTHOR]

Coordination polymers exhibiting magnetic properties can be considered as promising materials for magnetic applications. We obtained such materials by means pf mechanochemical incorporation of binuclear metal complexes Mn–O–Mn into polystyrene. Incorporation of binuclear manganese complexes was achieved by using substituted benzoquinones (organic acceptors) as intermediate ligands that react with manganese acetylacetonate and provide new coordination and stabilization of manganese in different valence states. Magnetic transitions in this system are due to reversible disproportionation process Mn3+–O–Mn3+⇔Mn2+–O–Mn4+ in the binuclear complex. The structure of the binuclear complex was obtained using ab initio calculations. [ABSTRACT FROM AUTHOR]

We report on mechanochemical synthesis and magnetic and electric properties of organic polymeric semiconductor that contains paramagnetic and ferromagnetic particles. As starting materials we used polyaniline (emeraldine base), polystyrene, FeCl3, and elemental sulfur. These components were chosen for the purpose of obtaining semiconductor polymer composite containing magnetic iron nanoparticles and having flexible thermomechanical properties. The presence of nanoparticles was evidenced by scanning electron microscopy. The value of conductivity of the Fe-doped polymer composite was increased by several orders of magnitude compared to the initial undoped polyaniline. Temperature dependence of the conductivity shows semiconductor character of the composite material. [ABSTRACT FROM AUTHOR]

By means of mechanochemical synthesis we obtained a coordination polymer containing binuclear manganese complexes with organic catechol/ortho-quinone ligands. The reaction system contained polystyrene, manganese acetylacetonate, and donor-acceptor mixture catechol/ortho-quinone. Electron paramagnetic resonance (EPR) and infrared spectroscopic data show that the binuclear manganese complex is covalently linked to the chain of polystyrene. Theoretical EPR spectrum analysis revealed a triplet state of the complex with two nonequivalent manganese ions coupled to each other by spin exchange. The type of magnetic coupling between manganese ions in this system is similar to the one in manganese based inorganic magnetic materials. [ABSTRACT FROM AUTHOR]

We investigated paramagnetic properties of binuclear niobium complexes Nb-O-Nb with two nonequivalent Nb4+ ions in lithium-niobium phosphate glasses sLNPGd, in the environment of catechol/ortho-quinone ligands and in polyethylene. Experimental electron paramagnetic resonance spectrum analysis revealed nonequivalent distribution of the charge and electron spin density between two Nb atoms. Mechanochemical interaction of LNPG with an organic donor-acceptor mixture catechol/ortho-quinone followed by organic solvent extraction leads to the formation of a new binuclear complex with catechol/ortho-quinone ligands. This complex can be further incorporated into polyethylene matrix to form the complex with properties close to the complex in LNPG. [ABSTRACT FROM AUTHOR]

We report on synthesis of Co, Ni, and Fe nanoparticles by the action of elastic wave pulses on solid phase sandwich type samples containing metal salt, reducing agent, polyethylene, and polyacrylamide. The formation of metal nanoparticles is evidenced by ferromagnetic resonance and scanning electron microscopy. The product yield for the nanoparticles formation has a threshold character with the pressure in the elastic wave pulse. The maximum amount of Co, Ni, and Fe nanoparticles is observed around 20 kbar of pressure in elastic wave pulses. The presence of polyacrylamide in reaction composites increases the stability of metal nanoparticles to oxidation by two orders of magnitude. © 2004 American Institute of Physics. [ABSTRACT FROM AUTHOR]

Chromium complexes, where ortho-quinone ligands are covalently linked to polymeric chains of polyethylene, polystyrene, and copolymer of ethylene and vinylacetate are studied. The results of infrared and electron paramagnetic resonance spectroscopic studies of chromium coordination polymers show that covalent linking of quinone ligands is accompanied by the change in the valence states of chromium Cr(III)↔Cr(IV)↔Cr(V). The ligand field of the triplet Cr4+ ion is close to the one in Cr-doped Y2SiO5, a laser material in the visible and infrared regions. Therefore some useful magnetic and/or optical properties in such transition metal coordination polymers can be expected. © 2004 American Institute of Physics. [ABSTRACT FROM AUTHOR]