1. Low-temperature preparation and electrical properties of CaBi2Nb2O9 piezoelectric ceramic by addition of B2O3.
- Author
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Pan, C. B., Zhao, G. C., Li, S. M., Wang, X. L., Wang, J. M. Z., Tao, M., Yin, L. H., Song, W. H., Zhu, X. B., Yang, J., and Sun, Y. P.
- Subjects
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PIEZOELECTRIC ceramics , *CERAMICS , *PIEZOELECTRICITY , *CURIE temperature , *FERROELECTRICITY , *LOW temperatures - Abstract
CaBi2Nb2O9 ceramics were fabricated via the solid-state reaction method by the addition of B2O3 as a sintering aid at lower sintering temperatures than that prepared without B2O3. Ferroelectricity, piezoelectricity, and resistivity can be still greatly enhanced when the sintering temperature is decreased from 1075 °C for CaBi2Nb2O9 to 975 °C for CaBi2Nb2O9–0.25 wt. % B2O3. The high resistivity and weak c-axis texture ensure that the ceramics can be fully polarized in a high enough electric field. The increased spontaneous ferroelectric and remanent polarization result in a significant enhancement in the piezoelectric properties of CaBi2Nb2O9–0.25 wt. % B2O3. The sample sintered at 975 °C possesses a high piezoelectric coefficient d33 of ∼15.0 pC/N and resistivity of 1.4 × 106 Ω cm (at 600 °C) along with a high ferroelectric Curie temperature TC of ∼954 °C. This work is beneficial for the preparation of high-temperature piezoelectric ceramics with excellent electrical properties at a low sintering temperature. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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