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Spontaneous formation of chiral domains such as a helical filament and a bent-broom texture was observed from the mixture of a rod-like liquid crystal octylcyano-biphenyl (8CB) and a tri boomerang-shaped 2,4,6-triphenoxy-1,3,5-triazine (triphenoxy) molecule. Although the constituent molecules were achiral, their mixture showed the chiral domains with the equal fraction of the opposite handedness. No tilt of 8CB molecules in the smectic layer was observed, implying the chirality is not due to the polar packing and tilt of the molecules. In addition, the splay and bend elastic constant of 8CB was decreased after doping triphenoxy. A structural conformation of triphenoxy and an orientational coupling between 8CB and triphenoxy are considered to be related to the chiral domain formation. [ABSTRACT FROM AUTHOR]

We propose methods to obtain multi-domains with different threshold voltages for vertically aligned liquid crystal displays without additional transistors or capacitors. We exposed an ultraviolet light through a photomask and spatially varied the surface anchoring energy by partially decomposing the polyimide or inducing the adsorption of reactive monomers. The threshold voltage was reduced with smaller surface anchoring, and the reduction of the threshold could be qualitatively interpreted using a model describing a weak anchoring condition. [ABSTRACT FROM AUTHOR]

We propose a method to confirm the biaxial phase in thermotropic nematic liquid crystals from measurement of the electro-optic characteristics. The electro-optic transmittance curve shows monotonic decrease to zero in the uniaxial phase but the curve shows a U-shaped behavior (or a monotonic decrease to nonzero transmittance) in the biaxial phase. In a bent-core mesogen 4,4′(1,3,4oxadiazole2,5diyl)dipheptylbenzoate (ODBP-Ph-C7), known to be in the nematic phase at temperatures between 173 and 222 °C, it has been found that its electro-optic curve at 190 °C shows a U-shaped behavior, while the curve at 210 °C shows a monotonic decrease to zero transmittance. We believe that these experimental results confirm the biaxial nature of ODBP-Ph-C7. [ABSTRACT FROM AUTHOR]

We propose a dual mode liquid crystal display (LCD), which can realize dynamic and memory operating LCD modes in a display panel. Horizontal switching and bistable chiral splay nematic LCD modes are used for the dynamic and memory operations, respectively. As the horizontal switching is applied to the dynamic operation, it is possible to use the same LC texture of splay for realizing dark states of both the dynamic and memory operations. Because, for each operation, pixel division is not required in the proposed dual mode LCD, there is no decrease in aperture ratio and resolution. In order to obtain superior display performance for both operations, a wideband half-wave configuration is employed to the proposed dual mode LCD. Due to the wideband configuration, very low light leakages at the dark state and good dispersion characteristics for the entire visible range are obtained. As a result, the proposed dual mode LCD shows a high contrast ratio of over 100:1 for both the dynamic and memory operations. [ABSTRACT FROM AUTHOR]

The authors demonstrate through dark injection space-charge-limited current (DI-SCLC) and trap-free SCLC measurements that an indium tin oxide (ITO)/buckminsterfullerene (C60) electrode can form a quasi-Ohmic contact with N,N′-bis(naphthalen-1-yl)-N,N′-bis(phenyl) benzidine (NPB). The DI-SCLC results show a clear peak current along with a shift of the peak position as the field intensity varies, implying an Ohmic (or quasi-Ohmic) contact. A theoretical simulation of the SCLC also shows that ITO/C60 forms an Ohmic contact with NPB when the electric field intensity is higher than 30 kV/cm. The Ohmic contact makes it possible to estimate the NPB hole mobility through the use of both DI-SCLC and trap-free SCLC analysis. [ABSTRACT FROM AUTHOR]

We propose a vertical alignment liquid crystal cell controlled by double-side in-plane switching with a positive dielectric anisotropy liquid crystal material. In this structure, the pixel electrodes are interdigital electrodes, which are deposited on the bottom and top substrates parallel to each other. In the voltage-off state, the liquid crystal molecules are vertically aligned under the crossed polarizers; hence the cell appears to be dark. When an in-plane field is applied, the liquid crystal molecules tilt down to the left or right along the field direction, which is at 45° with respect to the input polarizer, giving rise to maximum transmission of the incident light. We fabricated the proposed cells, which show higher transmittance and lower driving voltage compared with the conventional vertical alignment configuration with a positive dielectric anisotropy liquid crystal. The improved electro-optical properties are due to the stronger in-plane field compared with the configuration having one-side electrode. In this device, the response time and viewing angle characteristics are almost the same as the conventional structure. [ABSTRACT FROM AUTHOR]

Considering the surface distribution of polyimide chains, the properties of the unidirectional out-of-plane nematic liquid crystal tilt angle are investigated in view of the van der Waals interaction between nematic liquid crystal molecules and two polyimide layers: the anisotropic upper layer and the isotropic lower layer. The dependence of the pretilt angle upon the thickness of the upper polyimide layer oriented by rubbing is estimated from experiment and theory. Another experimental result shows that the relation between the anchoring energy and the thickness of the polyimide layer could be dependent on lower material. This was also explained in view of the nonretarded van der Waals interaction. [ABSTRACT FROM AUTHOR]

When an electric field is applied to a nematic liquid crystal cell with splay alignment layers, which is realized by mechanical parallel rubbing, the system exhibits abnormal reverse tilt domains. Even though the system has pretilt angle due to symmetry breaking by rubbing, existence of singular point in a cell by splay geometry and shift of that by locally asymmetric pretilt angle configurations result in the abnormal reverse tilt domains. On the basis of Oseen-Frank theory, dependence of singular point upon the abnormal reverse tilt domains is theoretically investigated for a splay alignment liquid crystal cell. By using the Dickman’s Q-tensor method [SID Int. Symp. Digest Tech. Papers 24, 638 (1993)], liquid crystal director field is calculated for the splay-aligned liquid crystal cell that an electric field is applied to. We presume a model to explain the abnormal reverse tilt domains, and derive the conditions required for the generation and elimination of these domains. [ABSTRACT FROM AUTHOR]

Properties of nematic liquid crystals aligned on polyimide surfaces exposed to a low-energy Ar ion beam are investigated. The study revealed that there are few ions or radicals induced by broken bonds on polyimide surfaces bombarded with Ar ion beams.

Pretilt angle measurable by using the conventional crystal rotation method is limited to about 0°-20° and 700-90°. We propose a method by which we can measure the pretilt angle by using the crystal rotation method even if the pretilt angle is between 20° and 70°. In this method, the determination of a pretilt angle is achieved by finding the rotation angles where transmittances are maximum and minimum in the periodic transmittance characteristics obtained with the variation of rotation angle. [ABSTRACT FROM AUTHOR]