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1. A convenient synthesis of N - tert -butyl amides by the reaction of di- tert -butyl dicarbonate and nitriles catalyzed by Cu(OTf)2.

Author

Yang, Wanfeng, Feng, Chengliang, Tang, Yuqi, Ji, Min, and Chen, Junqing

Subjects
*AMIDES, *CATALYST synthesis, *CATALYSTS, *CHEMICAL yield, *CARBONATES
Abstract

The utility of Cu(OTf)2 as the catalyst for the synthesis of a series of N - tert -butyl amides in excellent isolated yields via the reaction of nitriles (alkyl, aryl, benzyl, and furyl nitriles) with di- tert -butyl dicarbonate is described. Cu(OTf)2 is a highly stable and efficient catalyst for the present Ritter reaction under solvent-free conditions at room temperature. [ABSTRACT FROM AUTHOR]

Published
2020
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