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This paper introduces a convenient approach for determining iodate in iodized salt by headspace gas chromatography (HS-GC). The analytical technique can measure the generated carbon dioxide from the redox reaction between iodate and sodium oxalate in the presence of strong acid. The formed carbon dioxide from this reaction in a closed vial is measured by GC. It was observed that the redox reaction in the vial was completed in 40 min at 95 °C. The results indicated that this analytical technique is precise (RSD ≤ 2.69%) and accurate (relative errors ≤ 7.21%). The present approach is fast and simple, providing a robust avenue to the routine estimation of iodate in iodized salt in a wide variety of applications from processing to quality monitoring., (Copyright © 2018 Elsevier B.V. All rights reserved.)