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Integrating renewable electricity and green hydrogen with CO 2 utilization to produce chemicals has drawn much attention due to its low carbon emission characteristics. The goal of this paper is to investigate the environmental sustainability of producing a steady hourly output of methanol by utilizing electricity and hydrogen produced via renewable energy resources, and CO 2 captured from a coal-fired power plant located in Inner Mongolia, China. Six renewable energy-based electricity and hydrogen systems are considered based on photovoltaic, wind turbines and combinations thereof, including battery and grid technologies. The environmental impact indicators of these system are compared comprehensively through life cycle assessment approach, including not only global warming potential but also fossil fuel depletion, water & soil & air pollution indices and human health index. The results indicate that the most environmentally friendly system is Case B2 which uses photovoltaic to produce hydrogen and electricity, with battery for energy storage and excess electricity sold back to grid. It shows apparently the best sustainability performance in global warming potential, which is 0.105 kg CO 2 -eq per kg methanol. In general, the proposed six systems outperform conventional methanol production systems in terms of global warming potential and abiotic depletion potential, with reductions ranging from 74% to 92% and 51.1%–73.8% respectively, but they have high levels in other environmental sustainability indicators such as human toxicity, eutrophication potential, and ozone layer depletion potential due to the photovoltaic electricity generation unit. The findings highlight that it is essential to consider a comprehensive range of environmental sustainability indicators when developing renewable energy-based methanol systems on a large scale. [Display omitted] • Component capacity of the integrated system is optimized. • Comprehensive life cycle environmental impact assessment is conducted. • GWP of proposed route is 74 %–92% lower than fossil-based route. • PV manufacturing is critical in most environmental impact indicators. • HTP, ODP and EP indicators of proposed route are much high. [ABSTRACT FROM AUTHOR]