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The international investment literature consistently indicates that enterprises, functioning as pivotal components of the economic system, engage in diversified outward foreign investment activities, thereby catalyzing the transition towards a greener and more sustainable economy and society. Based on the overseas investment data of Chinese listed companies from 2009 to 2019, this paper adopts a comprehensive approach comprising the two-way fixed effects model, propensity score matching technique, and difference-in-differences set up to evaluate the impact of the enterprise's overseas investment quantity and decision-making of host countries on green development. The findings explore that an increase in outward investment quantity facilitates the enterprise's green transition, which withstands robustness testing, including the decomposition of the green transition index, adjustments to the sample timeframe, and exclusion of corporate samples from top-tier cities. Such promoting effects are more pronounced among listed companies investing in low- and middle-income countries, as well as those located in provinces aligned with the Belt and Road Initiative in China. Further, an enterprise's overseas investment decision-making by the proposal of the BRI has exhibited a substantial and enduring enhancement of green development. This discovery underscores a pragmatic trajectory for the enterprise's green transformation, driven by proactive engagement in high-level openness. [ABSTRACT FROM AUTHOR]